构建弱Ru- mo金属键抑制Ru过氧化，实现持久的酸性水氧化。

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-02-25 DOI:10.1039/d5cc00186b

Yongduo Liu , Runxu Deng , Yang Song , Weiling Tan , Xiongxin Tao , Shijian Luo , Daojun Long , Siguo Chen , Zidong Wei

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引用次数: 0

摘要

虽然降低Ru- o共价抑制了晶格氧的损失，但它也削弱了Ru- obri - mo构型的电子转移，导致Ru过度氧化。在RuO2中掺杂Mo，削弱了Ru- o的共价，形成了弱的Ru-Mo金属键，以补偿Ru的电子密度，其中Mo0.125Ru0.875O2催化剂在300 mA cm-2下500 h表现出稳定的PEM性能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Constructing weak Ru–Mo metallic bonds to suppress Ru overoxidation for durable acidic water oxidation†

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Constructing weak Ru–Mo metallic bonds to suppress Ru overoxidation for durable acidic water oxidation†

Although reducing the Ru–O covalency suppresses the loss of lattice oxygen, it also weakens the electron transfer of the Ru–O_bri–Mo configuration, leading to Ru overoxidation. Herein, doping Mo into RuO₂ weakens the Ru–O covalency and forms weak Ru–Mo metallic bonds to compensate for the electron density of Ru, where the Mo_0.125Ru_0.875O₂ catalyst exhibits stable PEM performance at 300 mA cm⁻² for 500 h.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.