过期药物衍生的神奇清除剂,去除有害染料,无危险足迹

IF 3 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES
Soumen Dey, Gayatri Kumari Sethi, Priyanka Priyadarsini Samal, Saismruti Das, Bidisha Bharadwaj, Himanshu Barik, Jashminirani Swain, Ankita Panda, Md. Atif Qaiyum, Banashree Dey
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引用次数: 0

摘要

水中过多的染料污染加剧了生物的健康困境。此外,过期药品由于管理不善,在环境中随意处置,会产生二次危害。为了解决这两个问题,我们将一种过期药物“Oflofrenz-OZ”转化为活性炭(OAC),然后从水中超高速清除顽固的溴百里酚蓝(BTB)和crocein橙(CO)。利用粉末XRD、FESEM-EDX、pHZPC和BET表面积对材料进行了表征。FESEM表现出高度多孔的形态,均匀装饰,从而提供了一个有利的染料承载平台。对BTB和CO (362.318 mg/g和1008.089 mg/g)的超快吸附性能符合Langmuir单层模型(R2 = 0.999)。温和的碱辅助再生使材料再生高达50%,实现三循环再利用。OAC在管井、水龙头和反渗透系统的模拟废水中表现良好,具有协同的现场适用性。通过将染料负载的废材料转化为第二代碳基吸附剂,收率达到80%,解决了长期困扰的处理问题。与类似材料相比,由于其非凡的吸附效果,经济可行性和零足迹,目前的材料是一个明显的赢家。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Expired Medicine-Derived Wonder Scavenger for The Removal of Harmful Dyes With No Hazardous Footprint

Exorbitant dye contamination in water augments health quandaries in living beings. Besides, expired medicines induce secondary hazards owing to mismanaged, rampant disposal in environments. To quench the dual problem, the waste-to-best protocol was exercised maneuvering the conversion of an expired medicine ‘Oflofrenz-OZ’ to activated carbon (OAC) followed by extraordinary ultrafast scavenging of recalcitrant bromothymol blue (BTB), and crocein orange (CO) from water. The material is well characterized using powder XRD, FESEM-EDX, pHZPC, and BET surface area. FESEM exhibits a highly porous morphology, evenly decorated, thereby offering a favorable dye-hosting platform. Outstanding adsorption capacities for BTB and CO (362.318 and 1008.089 mg/g) are powered by ultrafast kinetics, obeying the Langmuir monolayer model (R2 = 0.999). Mild alkali-assisted regeneration revives the material by up to 50%, enabling three-cycle reuse. OAC performs well with simulated wastewater from tube-well, tap, and reverse osmosis systems, which synergistically advocates field applicability. The long-hankered disposal problem of dye-loaded spent material has been addressed by converting it to a second-generation carbon-based adsorbent with an 80% yield. Compared with analogous materials, the present material is a clear winner, thanks to its extraordinary adsorption efficacy, economic viability, and zero footprints.

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来源期刊
Water, Air, & Soil Pollution
Water, Air, & Soil Pollution 环境科学-环境科学
CiteScore
4.50
自引率
6.90%
发文量
448
审稿时长
2.6 months
期刊介绍: Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments. Articles should not be submitted that are of local interest only and do not advance international knowledge in environmental pollution and solutions to pollution. Articles that simply replicate known knowledge or techniques while researching a local pollution problem will normally be rejected without review. Submitted articles must have up-to-date references, employ the correct experimental replication and statistical analysis, where needed and contain a significant contribution to new knowledge. The publishing and editorial team sincerely appreciate your cooperation. Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.
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