重15族（P, As, Sb, Bi）自由基化学的最新进展-框架，小分子反应性和催化

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-02-25 DOI:10.1039/D4DT03582H

Deana L. G. Symes and Jason D. Masuda

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引用次数: 0

摘要

几十年来，基团自由基化学一直是一个有针对性的研究领域。随着磷自由基的例子越来越多，砷、锑和铋等较重的氧原自由基也成为重要的目标。在21世纪，已经报道了15组自由基的不同框架，本文将对此进行介绍。讨论了所选自由基的反应性和应用，并展望了该领域的发展方向。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Recent advances in heavier group 15 (P, As, Sb, Bi) radical chemistry – frameworks, small molecule reactivity, and catalysis

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Recent advances in heavier group 15 (P, As, Sb, Bi) radical chemistry – frameworks, small molecule reactivity, and catalysis

Main group radical chemistry has been a targeted research area for several decades. With growing examples of phosphorus radicals, even heavier pnictogen radicals including arsenic, antimony, and bismuth have also become important targets. A diverse framework of group 15 radicals has been reported in the 21st century and is covered herein. Reactivity and applications of selected radicals and future directions for this field are discussed.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.