{"title":"两步固溶处理Al-Si-Cu-Mg铸造合金组织演变及热处理工艺研究","authors":"Hao Song, Yaqiang Tian, Keli Liu, Xiaoping Zheng, Yingli Wei, Zhenyu Liu, Runze Zhang, Junsheng Wang, Liansheng Chen, Mingshan Zhang","doi":"10.1007/s11837-025-07156-x","DOIUrl":null,"url":null,"abstract":"<div><p>The heat treatment process plays a decisive role in the microstructure and mechanical properties of alloys. However, it is difficult to optimize the heat treatment process of Al-Si-Cu-Mg cast alloys because of the different solubilities of Al<sub>2</sub>Cu and Q-Al<sub>5</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>6</sub>. In this study, the parameters of the heat treatment process were optimized by using thermal simulation and experimental, and the microstructure evolution during the solid solution process was studied. The results show that the dissolution temperatures of low melting point eutectic phase Al<sub>2</sub>Cu and Q-Al<sub>5</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>6</sub> are 502°C and 539°C by using DSC. Spherical Al<sub>2</sub>Cu phase is easily dissolved, and irregular Al<sub>2</sub>Cu phase and Q-Al<sub>5</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>6</sub> phase are not easily dissolved under the one-step solution treatment. However, the two-step solution treatment makes the Q-Al<sub>5</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>6</sub> phase dissolve, which improves the solid solution degree of the alloy. The spheroidization degree of eutectic Si is the highest under the optimum one- and two-step solution process. The microhardness was the highest (76.4 ± 1.2 HV, 95.6 ± 2.0 HV). The optimal heat treatment processes are 500°C + 9 h + 170°C + 3 h and 500°C + 9 h + 535°C + 7 h + 170°C + 3 h, and the peak aging hardness is 132.9 ± 1.9 HV and 139.9 ± 2.1 HV, respectively.</p></div>","PeriodicalId":605,"journal":{"name":"JOM","volume":"77 3","pages":"1252 - 1266"},"PeriodicalIF":2.1000,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on Microstructure Evolution and Heat Treatment Process of Al-Si-Cu-Mg Cast Alloys Under Two-Step Solution Treatment\",\"authors\":\"Hao Song, Yaqiang Tian, Keli Liu, Xiaoping Zheng, Yingli Wei, Zhenyu Liu, Runze Zhang, Junsheng Wang, Liansheng Chen, Mingshan Zhang\",\"doi\":\"10.1007/s11837-025-07156-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The heat treatment process plays a decisive role in the microstructure and mechanical properties of alloys. However, it is difficult to optimize the heat treatment process of Al-Si-Cu-Mg cast alloys because of the different solubilities of Al<sub>2</sub>Cu and Q-Al<sub>5</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>6</sub>. In this study, the parameters of the heat treatment process were optimized by using thermal simulation and experimental, and the microstructure evolution during the solid solution process was studied. The results show that the dissolution temperatures of low melting point eutectic phase Al<sub>2</sub>Cu and Q-Al<sub>5</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>6</sub> are 502°C and 539°C by using DSC. Spherical Al<sub>2</sub>Cu phase is easily dissolved, and irregular Al<sub>2</sub>Cu phase and Q-Al<sub>5</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>6</sub> phase are not easily dissolved under the one-step solution treatment. However, the two-step solution treatment makes the Q-Al<sub>5</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>6</sub> phase dissolve, which improves the solid solution degree of the alloy. The spheroidization degree of eutectic Si is the highest under the optimum one- and two-step solution process. The microhardness was the highest (76.4 ± 1.2 HV, 95.6 ± 2.0 HV). The optimal heat treatment processes are 500°C + 9 h + 170°C + 3 h and 500°C + 9 h + 535°C + 7 h + 170°C + 3 h, and the peak aging hardness is 132.9 ± 1.9 HV and 139.9 ± 2.1 HV, respectively.</p></div>\",\"PeriodicalId\":605,\"journal\":{\"name\":\"JOM\",\"volume\":\"77 3\",\"pages\":\"1252 - 1266\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2025-02-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"JOM\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11837-025-07156-x\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"JOM","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11837-025-07156-x","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
热处理工艺对合金的显微组织和力学性能起着决定性的作用。然而,由于Al2Cu和Q-Al5Cu2Mg8Si6的溶解度不同,使得Al-Si-Cu-Mg铸造合金的热处理工艺难以优化。本研究采用热模拟和实验相结合的方法对热处理工艺参数进行了优化,并对固溶过程中的组织演变进行了研究。结果表明:低熔点共晶相Al2Cu和Q-Al5Cu2Mg8Si6的溶解温度分别为502℃和539℃;一步固溶处理下,球形Al2Cu相易溶,不规则Al2Cu相和Q-Al5Cu2Mg8Si6相不易溶。两步固溶处理使Q-Al5Cu2Mg8Si6相溶解,提高了合金的固溶度。在最佳的一步和两步固溶工艺下,共晶Si的球化程度最高。显微硬度最高(76.4±1.2 HV, 95.6±2.0 HV)。最佳热处理工艺为500℃+ 9 h + 170℃+ 3 h和500℃+ 9 h + 535℃+ 7 h + 170℃+ 3 h,峰值时效硬度分别为132.9±1.9 HV和139.9±2.1 HV。
Study on Microstructure Evolution and Heat Treatment Process of Al-Si-Cu-Mg Cast Alloys Under Two-Step Solution Treatment
The heat treatment process plays a decisive role in the microstructure and mechanical properties of alloys. However, it is difficult to optimize the heat treatment process of Al-Si-Cu-Mg cast alloys because of the different solubilities of Al2Cu and Q-Al5Cu2Mg8Si6. In this study, the parameters of the heat treatment process were optimized by using thermal simulation and experimental, and the microstructure evolution during the solid solution process was studied. The results show that the dissolution temperatures of low melting point eutectic phase Al2Cu and Q-Al5Cu2Mg8Si6 are 502°C and 539°C by using DSC. Spherical Al2Cu phase is easily dissolved, and irregular Al2Cu phase and Q-Al5Cu2Mg8Si6 phase are not easily dissolved under the one-step solution treatment. However, the two-step solution treatment makes the Q-Al5Cu2Mg8Si6 phase dissolve, which improves the solid solution degree of the alloy. The spheroidization degree of eutectic Si is the highest under the optimum one- and two-step solution process. The microhardness was the highest (76.4 ± 1.2 HV, 95.6 ± 2.0 HV). The optimal heat treatment processes are 500°C + 9 h + 170°C + 3 h and 500°C + 9 h + 535°C + 7 h + 170°C + 3 h, and the peak aging hardness is 132.9 ± 1.9 HV and 139.9 ± 2.1 HV, respectively.
期刊介绍:
JOM is a technical journal devoted to exploring the many aspects of materials science and engineering. JOM reports scholarly work that explores the state-of-the-art processing, fabrication, design, and application of metals, ceramics, plastics, composites, and other materials. In pursuing this goal, JOM strives to balance the interests of the laboratory and the marketplace by reporting academic, industrial, and government-sponsored work from around the world.