流动形态对固体氧化物电解槽性能和热应力影响的评价

IF 4.6 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Hongwei Zhang , Yong Zeng , Ruyu Shi , Dong Yan , Lichao Jia , Wenying Zhang
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引用次数: 0

摘要

流场是影响固体氧化物电解槽(SOEC)电解性能的重要因素之一。本文建立了一个完整的三维SOEC单电池模型,并对其阴极流动形态进行了数值计算。与平行流场、交叉流场和蛇形流场的电解行为相比,旋转l型流场表现出更好的性能。它具有良好的气体分布能力,增强了传质,从而提高了电解性能,同时速度和温度分布更加均匀。另外,旋转l型流场中阴极、电解液和阳极的平均第一主应力分别最小,平行流场中阴极、电解液和阳极的最大第一主应力分别最小。应力的大小和分布不仅受温度梯度的影响,还与流动形态有关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Evaluating the effect of flow configuration on the performance and thermal stress of solid oxide electrolysis cell
The flow field is one of the important factors affecting the electrolytic performance of solid oxide electrolysis cell (SOEC). In this paper, a comprehensive three-dimensional SOEC single cell model is established, and its cathode flow configuration is evaluated numerically. Comparing with the electrolytic behavior of parallel flow field, cross flow field, and serpentine flow field, the rotary L-type flow field shows better performance. It has good gas distribution ability, enhances mass transfer, and thus improves electrolytic performance, while achieves a more uniform velocity and temperature distribution. In addition, the average first principal stress of the cathode, electrolyte and anode in the rotary L-type flow field is the smallest respectively, but the maximum first principal stress of the cathode, electrolyte and anode in the parallel flow field is the smallest respectively. The value and distribution of stress is not only affected by temperature gradient, but also related to the flow configurations.
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来源期刊
Materials Science and Engineering: B
Materials Science and Engineering: B 工程技术-材料科学:综合
CiteScore
5.60
自引率
2.80%
发文量
481
审稿时长
3.5 months
期刊介绍: The journal provides an international medium for the publication of theoretical and experimental studies and reviews related to the electronic, electrochemical, ionic, magnetic, optical, and biosensing properties of solid state materials in bulk, thin film and particulate forms. Papers dealing with synthesis, processing, characterization, structure, physical properties and computational aspects of nano-crystalline, crystalline, amorphous and glassy forms of ceramics, semiconductors, layered insertion compounds, low-dimensional compounds and systems, fast-ion conductors, polymers and dielectrics are viewed as suitable for publication. Articles focused on nano-structured aspects of these advanced solid-state materials will also be considered suitable.
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