用于先进微波吸收应用的氮化硼-环氧-硅烷功能化腰果酚纳米复合材料的工程可扩展和成本效益制造

IF 3.9 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Sathish Kumar M, Mandhakini Mohandas, Santhosh Jeferson and Ramasamy Jayavel*, 
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引用次数: 0

摘要

电子设备和5G技术的日益普及加剧了电磁波(EMW)污染,需要有效的对策。微波吸收材料(MAM)为解决这一问题提供了有希望的解决方案。氮化硼(BN)由于其优异的介电性能、低密度、导热性和化学稳定性,是开发MAM的合适候选材料。本文研究了纳米复合材料对氮化硼微波吸收性能的优化。通过将BN加入到硅烷功能化腰果酚改性的环氧树脂基体中,该复合材料具有增强的极化和改善的界面相互作用。所得材料表现出优异的表面粗糙度和疏水性。优化后的复合材料具有优异的微波吸收性能,在12.4 GHz时的反射损耗为−23 dB,厚度仅为10 mm。此外,复合材料表现出增强的机械阻尼值0.85。这些结果表明,复合材料结构内部的阻抗匹配和多极化损耗机制的协同作用是其优异的微波吸收性能的重要原因。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Engineering Scalable and Cost-Effective Fabrication of Architecturally Tailored Boron Nitride-Epoxy-Silane-Functionalized Cardanol Nanocomposites for Advanced Microwave Absorption Applications

Engineering Scalable and Cost-Effective Fabrication of Architecturally Tailored Boron Nitride-Epoxy-Silane-Functionalized Cardanol Nanocomposites for Advanced Microwave Absorption Applications

The increasing prevalence of electronic devices and 5G technology has exacerbated electromagnetic wave (EMW) pollution, necessitating effective countermeasures. Microwave-absorbing materials (MAM) offer promising solutions to address this issue. Owing to its exceptional dielectric properties, low density, thermal conductivity, and chemical stability, boron nitride (BN) is a suitable candidate for MAM development. This study investigates the optimization of the BN microwave absorption performance through nanocomposite fabrication. The composite has been engineered with enhanced polarization and improved interfacial interactions by incorporating BN into an epoxy resin matrix modified with silane-functionalized cardanol. The resulting material exhibited superior surface roughness and hydrophobicity. The optimal composite formulation demonstrated outstanding microwave absorption properties, achieving a reflection loss of −23 dB at 12.4 GHz with a thickness of only 10 mm. Furthermore, the composite displayed an enhanced mechanical damping value of 0.85. These results suggest that the synergistic effect of impedance matching and multiple polarization loss mechanisms within the composite structure contributes to its superior microwave absorption performance.

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来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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