前言：硼烷修饰铁配合物的CO2还原：二级配位球策略

IF 16.9 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Angewandte Chemie International Edition Pub Date : 2025-02-24 DOI:10.1002/anie.202580961

Connor S. Durfy, Joseph A. Zurakowski, Dr. Marcus W. Drover

{"title":"前言：硼烷修饰铁配合物的CO2还原：二级配位球策略","authors":"Connor S. Durfy, Joseph A. Zurakowski, Dr. Marcus W. Drover","doi":"10.1002/anie.202580961","DOIUrl":null,"url":null,"abstract":"<p>Bifunctional complex design can enable selective activation of the strong C=O bonds in CO2. Much like a fiddler crab, the {Fe-H/Cp*-BCy2} complex employed by Marcus W. Drover and co-workers in their Research Article (e202421599), features two distinct ”claws“ This study highlights that cooperativity between the iron hydride and pendant Lewis acidic borane is integral to facilitate the reduction of CO2 to a C1 product.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":125,"journal":{"name":"Angewandte Chemie International Edition","volume":"64 9","pages":""},"PeriodicalIF":16.9000,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202580961","citationCount":"0","resultStr":"{\"title\":\"Frontispiece: CO2 Reduction at a Borane-Modified Iron Complex: A Secondary Coordination Sphere Strategy\",\"authors\":\"Connor S. Durfy, Joseph A. Zurakowski, Dr. Marcus W. Drover\",\"doi\":\"10.1002/anie.202580961\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Bifunctional complex design can enable selective activation of the strong C=O bonds in CO2. Much like a fiddler crab, the {Fe-H/Cp*-BCy2} complex employed by Marcus W. Drover and co-workers in their Research Article (e202421599), features two distinct ”claws“ This study highlights that cooperativity between the iron hydride and pendant Lewis acidic borane is integral to facilitate the reduction of CO2 to a C1 product.\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure>\\n </p>\",\"PeriodicalId\":125,\"journal\":{\"name\":\"Angewandte Chemie International Edition\",\"volume\":\"64 9\",\"pages\":\"\"},\"PeriodicalIF\":16.9000,\"publicationDate\":\"2025-02-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202580961\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Chemie International Edition\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/anie.202580961\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie International Edition","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/anie.202580961","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

双功能复合物设计可以选择性激活CO2中的强C=O键。Marcus W. Drover及其同事在他们的研究文章（e202421599）中使用的{Fe-H/Cp*-BCy2}配合物就像招蟹一样，具有两个不同的“爪子”。这项研究强调了铁氢化物和悬坠Lewis酸性硼烷之间的协同作用对于促进二氧化碳还原为C1产物是不可或缺的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Frontispiece: CO2 Reduction at a Borane-Modified Iron Complex: A Secondary Coordination Sphere Strategy

查看原文本刊更多论文

Frontispiece: CO2 Reduction at a Borane-Modified Iron Complex: A Secondary Coordination Sphere Strategy

Bifunctional complex design can enable selective activation of the strong C=O bonds in CO2. Much like a fiddler crab, the {Fe-H/Cp*-BCy2} complex employed by Marcus W. Drover and co-workers in their Research Article (e202421599), features two distinct ”claws“ This study highlights that cooperativity between the iron hydride and pendant Lewis acidic borane is integral to facilitate the reduction of CO2 to a C1 product.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Angewandte Chemie International Edition 化学-化学综合

CiteScore

26.60

自引率

6.60%

发文量

3549

审稿时长

1.5 months

期刊介绍： Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.