有机硼酸与二恶唑酮和异氰酸酯的无金属和无碱选择性酰胺化

IF 2.5 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

New Journal of Chemistry Pub Date : 2025-02-04 DOI:10.1039/D5NJ00163C

Hui Sun, Shuguang Chen and Hui Wang

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引用次数: 0

摘要

在此，我们描述了硼酸与二恶唑酮和异氰酸酯的无金属和无碱交叉偶联反应，以选择性地合成各种酰胺。这些反应发生在1,2-和1,3-迁移过程中，分别形成C-N和C-C键，在温和的条件下获得满意的良好产率。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Metal- and base-free selective amidations of organoboronic acids with dioxazolones and isocyanates†

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Metal- and base-free selective amidations of organoboronic acids with dioxazolones and isocyanates†

Herein, we describe metal- and base-free cross-coupling reactions of boronic acids with dioxazolones and isocyanates to selectively synthesize various amides. These reactions occurred with processes of 1,2- and 1,3-migrations to construct C–N and C–C bonds to provide the corresponding amides in satisfactory to good yields under mild conditions, respectively.

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