自串联催化剂：含功能配体的水溶性铱配合物在水中通过氧化还原异构化/常压加氢催化从烯丙醇生成仲醇

IF 4.7 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2025-02-13 DOI:10.1021/acs.inorgchem.4c0428310.1021/acs.inorgchem.4c04283

Xiaozhong Chen, Beixuan Dong, Guoqiang Zhao, Jing Xu and Feng Li*,

{"title":"自串联催化剂：含功能配体的水溶性铱配合物在水中通过氧化还原异构化/常压加氢催化从烯丙醇生成仲醇","authors":"Xiaozhong Chen, Beixuan Dong, Guoqiang Zhao, Jing Xu and Feng Li*, ","doi":"10.1021/acs.inorgchem.4c0428310.1021/acs.inorgchem.4c04283","DOIUrl":null,"url":null,"abstract":"A water-soluble iridium complex [Cp*Ir(6,6′-(OH)2-2,2′-bpy)(H2O)][OTf]2 was found to be an efficient autotandem catalyst for the synthesis of secondary alcohols via redox isomerization/atmospheric hydrogenation in water. The OH groups in the bpy ligand are a key factor for the activity of the catalyst. Then, the mechanistic experiments and the practical utilization of the catalytic system were presented.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"64 7","pages":"3203–3212 3203–3212"},"PeriodicalIF":4.7000,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Auto-Tandem Catalyst: From Allylic Alcohols to Secondary Alcohols via Redox Isomerization/Atmospheric Hydrogenation in Water Catalyzed by a Water-Soluble Iridium Complex Bearing a Functional Ligand\",\"authors\":\"Xiaozhong Chen, Beixuan Dong, Guoqiang Zhao, Jing Xu and Feng Li*, \",\"doi\":\"10.1021/acs.inorgchem.4c0428310.1021/acs.inorgchem.4c04283\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A water-soluble iridium complex [Cp*Ir(6,6′-(OH)2-2,2′-bpy)(H2O)][OTf]2 was found to be an efficient autotandem catalyst for the synthesis of secondary alcohols via redox isomerization/atmospheric hydrogenation in water. The OH groups in the bpy ligand are a key factor for the activity of the catalyst. Then, the mechanistic experiments and the practical utilization of the catalytic system were presented.\",\"PeriodicalId\":40,\"journal\":{\"name\":\"Inorganic Chemistry\",\"volume\":\"64 7\",\"pages\":\"3203–3212 3203–3212\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2025-02-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.inorgchem.4c04283\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.inorgchem.4c04283","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

研究了一种水溶性铱配合物[Cp*Ir(6,6′-(OH)2-2,2′-bpy)(H2O)][OTf]2是在水中氧化还原异构化/常压加氢合成仲醇的有效自串接催化剂。bpy配体中的羟基是影响催化剂活性的关键因素。然后介绍了该催化体系的机理实验和实际应用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Auto-Tandem Catalyst: From Allylic Alcohols to Secondary Alcohols via Redox Isomerization/Atmospheric Hydrogenation in Water Catalyzed by a Water-Soluble Iridium Complex Bearing a Functional Ligand

查看原文本刊更多论文

Auto-Tandem Catalyst: From Allylic Alcohols to Secondary Alcohols via Redox Isomerization/Atmospheric Hydrogenation in Water Catalyzed by a Water-Soluble Iridium Complex Bearing a Functional Ligand

A water-soluble iridium complex [Cp*Ir(6,6′-(OH)₂-2,2′-bpy)(H₂O)][OTf]₂ was found to be an efficient autotandem catalyst for the synthesis of secondary alcohols via redox isomerization/atmospheric hydrogenation in water. The OH groups in the bpy ligand are a key factor for the activity of the catalyst. Then, the mechanistic experiments and the practical utilization of the catalytic system were presented.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.