YFeO3-Y3Fe5O12非均相结构磁性纳米材料的合成及共沉淀法制备纳米纤维

IF 4.7 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR
Jia-Li Wang, Xue Xi*, Ke-Di Cai*, Zhi-Han Chang, Jian-Fang Chi and Xiao-Shi Lang, 
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引用次数: 0

摘要

氧化铁钇基磁性纳米材料的设计与制造在微电子相关领域有着不可缺少的作用。瓶颈仍然存在,包括有限的再现性和无法控制所得到的材料的尺寸。本研究首次采用直接共沉淀法制备了以(NH4)2CO3为沉淀剂的非均相YFeO3-Y3Fe5O12复合材料。在优化条件下,制备的YFeO3-Y3Fe5O12纳米颗粒在室温下具有较高的结晶度和铁磁性,其饱和磁化强度(Ms)达到11.927 emu·g-1。同时,颗粒尺寸可达到约14.7 nm。氧化钇铁组分之间紧密的异质结形成了明显的铁磁性。随后,以YFeO3-Y3Fe5O12纳米颗粒为原料,采用静电纺丝技术制备柔性[(YFeO3-Y3Fe5O12)/PVP]纳米纤维。通过改变纳米纤维中磁性粒子的比例,可以调节纳米纤维的磁性强度。实现了磁性与纳米纤维膜制备的有机结合。磁性微粒被包裹在纳米纤维中,不仅避免了团聚,而且避免了与杂质的直接接触,提高了实用性和回收寿命。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis of YFeO3–Y3Fe5O12 Heterogeneous Structure Magnetic Nanomaterials and Preparation of Nanofibers by Coprecipitation Method

Synthesis of YFeO3–Y3Fe5O12 Heterogeneous Structure Magnetic Nanomaterials and Preparation of Nanofibers by Coprecipitation Method

The design and fabrication of yttrium iron oxide-based magnetic nanomaterials play an indispensable role in microelectronic-related fields. The bottleneck still remains, including limited reproducibility and the inability to control the size of the resulting material. In this study, a straightforward coprecipitation method was firstly used for the production of heterogeneous YFeO3–Y3Fe5O12 composite with (NH4)2CO3 as the precipitant. Under optimized conditions, the obtained YFeO3–Y3Fe5O12 nanoparticles exhibit high crystallinity and ferromagnetic properties at room temperature, and its saturation magnetization strength (Ms) reached 11.927 emu·g–1. Meanwhile, the particle size can be achieved at approximately 14.7 nm. The compact heterojunction between the yttrium iron oxide components gives rise to the obvious ferromagnetic property. Subsequently, YFeO3–Y3Fe5O12 nanoparticles were taken as the raw material for preparing flexible [(YFeO3–Y3Fe5O12)/PVP] nanofibers by electrospinning technology. By changing the proportion of magnetic particles in the nanofibers, the magnetic strength can be regulated. The integration between magnetism and the preparation of nanofiber membranes is realized. The encapsulation of magnetic particles in the nanofibers avoids not only aggregation but also the direct contact with the impurity, which promotes practicability and recycle life.

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来源期刊
Inorganic Chemistry
Inorganic Chemistry 化学-无机化学与核化学
CiteScore
7.60
自引率
13.00%
发文量
1960
审稿时长
1.9 months
期刊介绍: Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.
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