Jia-Li Wang, Xue Xi*, Ke-Di Cai*, Zhi-Han Chang, Jian-Fang Chi and Xiao-Shi Lang,
{"title":"YFeO3-Y3Fe5O12非均相结构磁性纳米材料的合成及共沉淀法制备纳米纤维","authors":"Jia-Li Wang, Xue Xi*, Ke-Di Cai*, Zhi-Han Chang, Jian-Fang Chi and Xiao-Shi Lang, ","doi":"10.1021/acs.inorgchem.4c0502010.1021/acs.inorgchem.4c05020","DOIUrl":null,"url":null,"abstract":"<p >The design and fabrication of yttrium iron oxide-based magnetic nanomaterials play an indispensable role in microelectronic-related fields. The bottleneck still remains, including limited reproducibility and the inability to control the size of the resulting material. In this study, a straightforward coprecipitation method was firstly used for the production of heterogeneous YFeO<sub>3</sub>–Y<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub> composite with (NH<sub>4</sub>)<sub>2</sub>CO<sub>3</sub> as the precipitant. Under optimized conditions, the obtained YFeO<sub>3</sub>–Y<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub> nanoparticles exhibit high crystallinity and ferromagnetic properties at room temperature, and its saturation magnetization strength (Ms) reached 11.927 emu·g<sup>–1</sup>. Meanwhile, the particle size can be achieved at approximately 14.7 nm. The compact heterojunction between the yttrium iron oxide components gives rise to the obvious ferromagnetic property. Subsequently, YFeO<sub>3</sub>–Y<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub> nanoparticles were taken as the raw material for preparing flexible [(YFeO<sub>3</sub>–Y<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub>)/PVP] nanofibers by electrospinning technology. By changing the proportion of magnetic particles in the nanofibers, the magnetic strength can be regulated. The integration between magnetism and the preparation of nanofiber membranes is realized. The encapsulation of magnetic particles in the nanofibers avoids not only aggregation but also the direct contact with the impurity, which promotes practicability and recycle life.</p>","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"64 7","pages":"3454–3462 3454–3462"},"PeriodicalIF":4.7000,"publicationDate":"2025-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of YFeO3–Y3Fe5O12 Heterogeneous Structure Magnetic Nanomaterials and Preparation of Nanofibers by Coprecipitation Method\",\"authors\":\"Jia-Li Wang, Xue Xi*, Ke-Di Cai*, Zhi-Han Chang, Jian-Fang Chi and Xiao-Shi Lang, \",\"doi\":\"10.1021/acs.inorgchem.4c0502010.1021/acs.inorgchem.4c05020\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The design and fabrication of yttrium iron oxide-based magnetic nanomaterials play an indispensable role in microelectronic-related fields. The bottleneck still remains, including limited reproducibility and the inability to control the size of the resulting material. In this study, a straightforward coprecipitation method was firstly used for the production of heterogeneous YFeO<sub>3</sub>–Y<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub> composite with (NH<sub>4</sub>)<sub>2</sub>CO<sub>3</sub> as the precipitant. Under optimized conditions, the obtained YFeO<sub>3</sub>–Y<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub> nanoparticles exhibit high crystallinity and ferromagnetic properties at room temperature, and its saturation magnetization strength (Ms) reached 11.927 emu·g<sup>–1</sup>. Meanwhile, the particle size can be achieved at approximately 14.7 nm. The compact heterojunction between the yttrium iron oxide components gives rise to the obvious ferromagnetic property. Subsequently, YFeO<sub>3</sub>–Y<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub> nanoparticles were taken as the raw material for preparing flexible [(YFeO<sub>3</sub>–Y<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub>)/PVP] nanofibers by electrospinning technology. By changing the proportion of magnetic particles in the nanofibers, the magnetic strength can be regulated. The integration between magnetism and the preparation of nanofiber membranes is realized. The encapsulation of magnetic particles in the nanofibers avoids not only aggregation but also the direct contact with the impurity, which promotes practicability and recycle life.</p>\",\"PeriodicalId\":40,\"journal\":{\"name\":\"Inorganic Chemistry\",\"volume\":\"64 7\",\"pages\":\"3454–3462 3454–3462\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2025-02-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.inorgchem.4c05020\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.inorgchem.4c05020","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis of YFeO3–Y3Fe5O12 Heterogeneous Structure Magnetic Nanomaterials and Preparation of Nanofibers by Coprecipitation Method
The design and fabrication of yttrium iron oxide-based magnetic nanomaterials play an indispensable role in microelectronic-related fields. The bottleneck still remains, including limited reproducibility and the inability to control the size of the resulting material. In this study, a straightforward coprecipitation method was firstly used for the production of heterogeneous YFeO3–Y3Fe5O12 composite with (NH4)2CO3 as the precipitant. Under optimized conditions, the obtained YFeO3–Y3Fe5O12 nanoparticles exhibit high crystallinity and ferromagnetic properties at room temperature, and its saturation magnetization strength (Ms) reached 11.927 emu·g–1. Meanwhile, the particle size can be achieved at approximately 14.7 nm. The compact heterojunction between the yttrium iron oxide components gives rise to the obvious ferromagnetic property. Subsequently, YFeO3–Y3Fe5O12 nanoparticles were taken as the raw material for preparing flexible [(YFeO3–Y3Fe5O12)/PVP] nanofibers by electrospinning technology. By changing the proportion of magnetic particles in the nanofibers, the magnetic strength can be regulated. The integration between magnetism and the preparation of nanofiber membranes is realized. The encapsulation of magnetic particles in the nanofibers avoids not only aggregation but also the direct contact with the impurity, which promotes practicability and recycle life.
期刊介绍:
Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.