不同极性溶剂中1-[4-(4-戊基环己基)苯基]-3-(喹啉-8-氨基)丙-2-烯-1- 1分子的合成及结构鉴定

IF 1.1 4区 物理与天体物理 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
M. Yu. Volkov, A. R. Sharipova, O. A. Turanova
{"title":"不同极性溶剂中1-[4-(4-戊基环己基)苯基]-3-(喹啉-8-氨基)丙-2-烯-1- 1分子的合成及结构鉴定","authors":"M. Yu. Volkov,&nbsp;A. R. Sharipova,&nbsp;O. A. Turanova","doi":"10.1007/s00723-024-01726-z","DOIUrl":null,"url":null,"abstract":"<div><p>β-Enaminone 1-[4-(4-pentylcyclohexyl)-phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one was first synthesized and studied by NMR and UV spectroscopy. It was established that the molecules of this substance exist in the ketone form of the <i>cis-</i>isomer in both polar acetone and weakly polar chloroform. Exposing the solutions of this enaminone daylight at room temperature leads to the formation of small amounts of trans-isomer in them. 365 nm UV irradiation of the solution in chloroform leads to reversible <i>cis–trans</i> isomerization of the dissolved molecules of 1-[4-(4-pentylcyclohexyl)phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"56 3","pages":"297 - 312"},"PeriodicalIF":1.1000,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Structure Identification of 1-[4-(4-pentylcyclohexyl)-phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one Molecules in Solvents of Different Polarities\",\"authors\":\"M. Yu. Volkov,&nbsp;A. R. Sharipova,&nbsp;O. A. Turanova\",\"doi\":\"10.1007/s00723-024-01726-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>β-Enaminone 1-[4-(4-pentylcyclohexyl)-phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one was first synthesized and studied by NMR and UV spectroscopy. It was established that the molecules of this substance exist in the ketone form of the <i>cis-</i>isomer in both polar acetone and weakly polar chloroform. Exposing the solutions of this enaminone daylight at room temperature leads to the formation of small amounts of trans-isomer in them. 365 nm UV irradiation of the solution in chloroform leads to reversible <i>cis–trans</i> isomerization of the dissolved molecules of 1-[4-(4-pentylcyclohexyl)phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one.</p></div>\",\"PeriodicalId\":469,\"journal\":{\"name\":\"Applied Magnetic Resonance\",\"volume\":\"56 3\",\"pages\":\"297 - 312\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-11-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Magnetic Resonance\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00723-024-01726-z\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Magnetic Resonance","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1007/s00723-024-01726-z","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
引用次数: 0

摘要

首次合成了β-Enaminone 1-[4-(4-戊基环己基)苯基]-3-(喹啉-8-氨基)prop-2-en-1-one,并用NMR和UV光谱对其进行了研究。确定了该物质的分子在极性丙酮和弱极性氯仿中均以顺式异构体的酮形式存在。在室温下暴露这种胺酮溶液会导致其中形成少量的反式异构体。在氯仿中365 nm的紫外照射下,溶解的1-[4-(4-戊基环己基)苯基]-3-(喹啉-8-氨基)丙-2-烯-1- 1的分子发生可逆的顺-反异构化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis and Structure Identification of 1-[4-(4-pentylcyclohexyl)-phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one Molecules in Solvents of Different Polarities

Synthesis and Structure Identification of 1-[4-(4-pentylcyclohexyl)-phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one Molecules in Solvents of Different Polarities

β-Enaminone 1-[4-(4-pentylcyclohexyl)-phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one was first synthesized and studied by NMR and UV spectroscopy. It was established that the molecules of this substance exist in the ketone form of the cis-isomer in both polar acetone and weakly polar chloroform. Exposing the solutions of this enaminone daylight at room temperature leads to the formation of small amounts of trans-isomer in them. 365 nm UV irradiation of the solution in chloroform leads to reversible cis–trans isomerization of the dissolved molecules of 1-[4-(4-pentylcyclohexyl)phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Applied Magnetic Resonance
Applied Magnetic Resonance 物理-光谱学
CiteScore
1.90
自引率
10.00%
发文量
59
审稿时长
2.3 months
期刊介绍: Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields. The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信