{"title":"不同极性溶剂中1-[4-(4-戊基环己基)苯基]-3-(喹啉-8-氨基)丙-2-烯-1- 1分子的合成及结构鉴定","authors":"M. Yu. Volkov, A. R. Sharipova, O. A. Turanova","doi":"10.1007/s00723-024-01726-z","DOIUrl":null,"url":null,"abstract":"<div><p>β-Enaminone 1-[4-(4-pentylcyclohexyl)-phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one was first synthesized and studied by NMR and UV spectroscopy. It was established that the molecules of this substance exist in the ketone form of the <i>cis-</i>isomer in both polar acetone and weakly polar chloroform. Exposing the solutions of this enaminone daylight at room temperature leads to the formation of small amounts of trans-isomer in them. 365 nm UV irradiation of the solution in chloroform leads to reversible <i>cis–trans</i> isomerization of the dissolved molecules of 1-[4-(4-pentylcyclohexyl)phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"56 3","pages":"297 - 312"},"PeriodicalIF":1.1000,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Structure Identification of 1-[4-(4-pentylcyclohexyl)-phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one Molecules in Solvents of Different Polarities\",\"authors\":\"M. Yu. Volkov, A. R. Sharipova, O. A. Turanova\",\"doi\":\"10.1007/s00723-024-01726-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>β-Enaminone 1-[4-(4-pentylcyclohexyl)-phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one was first synthesized and studied by NMR and UV spectroscopy. It was established that the molecules of this substance exist in the ketone form of the <i>cis-</i>isomer in both polar acetone and weakly polar chloroform. Exposing the solutions of this enaminone daylight at room temperature leads to the formation of small amounts of trans-isomer in them. 365 nm UV irradiation of the solution in chloroform leads to reversible <i>cis–trans</i> isomerization of the dissolved molecules of 1-[4-(4-pentylcyclohexyl)phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one.</p></div>\",\"PeriodicalId\":469,\"journal\":{\"name\":\"Applied Magnetic Resonance\",\"volume\":\"56 3\",\"pages\":\"297 - 312\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-11-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Magnetic Resonance\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00723-024-01726-z\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Magnetic Resonance","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1007/s00723-024-01726-z","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
Synthesis and Structure Identification of 1-[4-(4-pentylcyclohexyl)-phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one Molecules in Solvents of Different Polarities
β-Enaminone 1-[4-(4-pentylcyclohexyl)-phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one was first synthesized and studied by NMR and UV spectroscopy. It was established that the molecules of this substance exist in the ketone form of the cis-isomer in both polar acetone and weakly polar chloroform. Exposing the solutions of this enaminone daylight at room temperature leads to the formation of small amounts of trans-isomer in them. 365 nm UV irradiation of the solution in chloroform leads to reversible cis–trans isomerization of the dissolved molecules of 1-[4-(4-pentylcyclohexyl)phenyl]-3-(quinolin-8-ylamino)prop-2-en-1-one.
期刊介绍:
Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields.
The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.