一种新型Mn@MOF-303催化剂用于苯基硫醇与CO2的高效s -甲酰化反应

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-02-28 DOI:10.1039/d5cc00195a

Ya-Shuai Liu , Zhi-Qiang Wang , Yong-Po Zhang , Wei-Yu Mu , Wen-Min Wang , Jin-Zhong Zhao

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引用次数: 0

摘要

在室温下，以Mn@MOF-303为催化剂，实现了一种新的、高效的苯甲酰基硫醇与CO2的s -甲酰化反应。Mn@MOF-303作为一种多相催化剂，具有高效的催化活性和优良的循环性能。通过DFT计算进一步分析了反应机理。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A novel Mn@MOF-303 as a catalyst for the highly efficient S-formylation of benzyl thiols with CO2†

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A novel Mn@MOF-303 as a catalyst for the highly efficient S-formylation of benzyl thiols with CO2†

A novel and efficient chemical approach for the S-formylation of benzylthiols with CO₂ has been achieved in the presence of Mn@MOF-303 as the catalyst at room temperature. As a heterogeneous catalyst, Mn@MOF-303 exhibited efficient catalytic activity and excellent cycling performance. Furthermore, the reaction mechanism was further analyzed by DFT calculations.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.