甲烷的可输送容量:理想的“圣杯”吸附剂所需的材料性能水平。

Chem & Bio Engineering Pub Date : 2024-10-31 eCollection Date: 2025-01-23 DOI:10.1021/cbe.4c00127
Mayank Vashishtha, Srinivas Gadipelli, K Vasanth Kumar
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引用次数: 0

摘要

Langmuir等温线用于确定理论上的“圣杯”吸附剂的性能,该吸附剂可以满足美国能源部提出的0.5 g/g和266 v/v的甲烷储存目标。对于5 ~ 65 bar的储罐,吸附剂要求最大吸附容量为0.8388 g/g,结合亲和力为0.05547 bar-1,物料密度为377 g/L。对于工作在5 - 80 bar之间的储罐,在容量和密度相同的情况下,结合亲和力应为0.05 bar-1。Langmuir等温线也被应用于计算必要的吸附剂性能,包括吸附位点的数量和结合能,以实现基于材料密度的266 v/v的体积存储目标。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Deliverable Capacity of Methane: Required Material Property Levels for the Ideal "Holy Grail" Adsorbent.

The Langmuir isotherm is used to determine the properties of a theoretical "holy grail" adsorbent that can meet the US Department of Energy's methane storage target of 0.5 g/g and 266 v/v. For a storage tank operating between 5 and 65 bar, the adsorbent requires a maximum adsorption capacity of 0.8388 g/g, a binding affinity of 0.05547 bar-1, and a material density of 377 g/L. For a tank operating between 5 and 80 bar, the binding affinity should be 0.05 bar-1, with the same capacity and density. The Langmuir isotherm is also applied to calculate the necessary adsorbent properties, including the number of adsorption sites and binding energies, to achieve the volumetric storage target of 266 v/v based on the material's density.

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