Yanwei Sun, Jiahui Yan, Mingming Wu, Jie Jiang, Yi Liu
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NH2-MIL-125 Nanosheets Prepared via Crystallization Kinetics Modulation for Ultrathin Membrane Fabrication.
Regulating both crystallographic orientation and thickness of titanium metal-organic framework (Ti-MOF) membranes remains a significant challenge. In this study, we pioneered the fabrication of uniform 29 nm thick NH2-MIL-125 nanosheet seeds by employing crystallization kinetics modulation approach. Through innovating confined counter-diffusion-assisted epitaxial growth under single-mode microwave heating, a highly c-oriented 80 nm thick NH2-MIL-125 membrane was prepared. Significant reduction in thickness endowed the membrane with unprecedented H2 permeance (1350 GPU) along with considerable H2/CO2 selectivity (19.1), exceeding the performance benchmarks of state-of-the-art NH2-MIL-125 membranes.
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