Yujie Chen, Fanlei Qin, Jiawen Wang, Kai Yang*, Yinyan Li and Gongxun Bai*,
{"title":"用Eu3+离子掺杂提高CsPbBr3量子点玻璃的发光和热稳定性","authors":"Yujie Chen, Fanlei Qin, Jiawen Wang, Kai Yang*, Yinyan Li and Gongxun Bai*, ","doi":"10.1021/acsanm.4c0720410.1021/acsanm.4c07204","DOIUrl":null,"url":null,"abstract":"<p >Perovskite quantum dots with halogen elements (Cl, Br, I) have been extensively studied due to their unique optoelectronic properties. However, the spectral properties of luminescent materials continue to present challenges in perovskite quantum dot glasses. Here, Eu<sup>3+</sup>-doped CsPbBr<sub>3</sub> quantum dot glasses were successfully prepared. Meanwhile, optimizing the doping concentration of Eu<sup>3+</sup> significantly improved the formation of quantum dots and enhanced their fluorescence intensity. After a heating–cooling cycle, the CsPbBr<sub>3</sub>:0.5% Eu<sup>3+</sup> glass still retained 95% of its initial value. By coating CsPbBr<sub>3</sub>:0.5% Eu<sup>3+</sup> glass powder with red phosphor on a blue chip, a white LED with a CCT of 5417 K can be prepared. Therefore, Eu<sup>3+</sup>-doped CsPbBr<sub>3</sub> quantum dot glasses demonstrate significant potential as an efficient material for optical lighting applications.</p>","PeriodicalId":6,"journal":{"name":"ACS Applied Nano Materials","volume":"8 7","pages":"3608–3616 3608–3616"},"PeriodicalIF":5.5000,"publicationDate":"2025-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhancing Luminescence and Thermal Stability of CsPbBr3 Quantum Dot Glasses through Doping with Eu3+ Ions\",\"authors\":\"Yujie Chen, Fanlei Qin, Jiawen Wang, Kai Yang*, Yinyan Li and Gongxun Bai*, \",\"doi\":\"10.1021/acsanm.4c0720410.1021/acsanm.4c07204\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Perovskite quantum dots with halogen elements (Cl, Br, I) have been extensively studied due to their unique optoelectronic properties. However, the spectral properties of luminescent materials continue to present challenges in perovskite quantum dot glasses. Here, Eu<sup>3+</sup>-doped CsPbBr<sub>3</sub> quantum dot glasses were successfully prepared. Meanwhile, optimizing the doping concentration of Eu<sup>3+</sup> significantly improved the formation of quantum dots and enhanced their fluorescence intensity. After a heating–cooling cycle, the CsPbBr<sub>3</sub>:0.5% Eu<sup>3+</sup> glass still retained 95% of its initial value. By coating CsPbBr<sub>3</sub>:0.5% Eu<sup>3+</sup> glass powder with red phosphor on a blue chip, a white LED with a CCT of 5417 K can be prepared. Therefore, Eu<sup>3+</sup>-doped CsPbBr<sub>3</sub> quantum dot glasses demonstrate significant potential as an efficient material for optical lighting applications.</p>\",\"PeriodicalId\":6,\"journal\":{\"name\":\"ACS Applied Nano Materials\",\"volume\":\"8 7\",\"pages\":\"3608–3616 3608–3616\"},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2025-02-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Nano Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsanm.4c07204\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Nano Materials","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsanm.4c07204","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Enhancing Luminescence and Thermal Stability of CsPbBr3 Quantum Dot Glasses through Doping with Eu3+ Ions
Perovskite quantum dots with halogen elements (Cl, Br, I) have been extensively studied due to their unique optoelectronic properties. However, the spectral properties of luminescent materials continue to present challenges in perovskite quantum dot glasses. Here, Eu3+-doped CsPbBr3 quantum dot glasses were successfully prepared. Meanwhile, optimizing the doping concentration of Eu3+ significantly improved the formation of quantum dots and enhanced their fluorescence intensity. After a heating–cooling cycle, the CsPbBr3:0.5% Eu3+ glass still retained 95% of its initial value. By coating CsPbBr3:0.5% Eu3+ glass powder with red phosphor on a blue chip, a white LED with a CCT of 5417 K can be prepared. Therefore, Eu3+-doped CsPbBr3 quantum dot glasses demonstrate significant potential as an efficient material for optical lighting applications.
期刊介绍:
ACS Applied Nano Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics and biology relevant to applications of nanomaterials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important applications of nanomaterials.