压电材料氧化还原催化伯胺机械氧化还原异硫氰化

IF 3.6 2区 化学 Q1 CHEMISTRY, ORGANIC
Miao Wang*, Hui-Ying Ren, Shan Jiang, Xiao-Yu Pu, Xiao-Lu Zhang, He-Ying Zhu, Jia-Chen Xiang* and Bang-Tun Zhao*, 
{"title":"压电材料氧化还原催化伯胺机械氧化还原异硫氰化","authors":"Miao Wang*,&nbsp;Hui-Ying Ren,&nbsp;Shan Jiang,&nbsp;Xiao-Yu Pu,&nbsp;Xiao-Lu Zhang,&nbsp;He-Ying Zhu,&nbsp;Jia-Chen Xiang* and Bang-Tun Zhao*,&nbsp;","doi":"10.1021/acs.joc.4c0252610.1021/acs.joc.4c02526","DOIUrl":null,"url":null,"abstract":"<p >A novel mechanoredox-enabled synthesis of aromatic and aliphatic isothiocyanates from primary amines and carbon disulfide under ball milling conditions using a piezoelectric material (BaTiO<sub>3</sub>) as the redox catalyst has been developed. This method displays several features, such as short reaction time, operational simplicity, room temperature and air conditions, minimal solvent, broad substrate scope, and recyclable cheap catalyst. Preliminary mechanistic studies revealed that highly polarized piezoelectric material acted as a single-electron transfer (SET) oxidation reagent for the key desulfurization process.</p>","PeriodicalId":57,"journal":{"name":"Journal of Organic Chemistry","volume":"90 7","pages":"2816–2821 2816–2821"},"PeriodicalIF":3.6000,"publicationDate":"2025-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mechanoredox-Enabled Isothiocyanation of Primary Amines Using Piezoelectric Material as the Redox Catalyst\",\"authors\":\"Miao Wang*,&nbsp;Hui-Ying Ren,&nbsp;Shan Jiang,&nbsp;Xiao-Yu Pu,&nbsp;Xiao-Lu Zhang,&nbsp;He-Ying Zhu,&nbsp;Jia-Chen Xiang* and Bang-Tun Zhao*,&nbsp;\",\"doi\":\"10.1021/acs.joc.4c0252610.1021/acs.joc.4c02526\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >A novel mechanoredox-enabled synthesis of aromatic and aliphatic isothiocyanates from primary amines and carbon disulfide under ball milling conditions using a piezoelectric material (BaTiO<sub>3</sub>) as the redox catalyst has been developed. This method displays several features, such as short reaction time, operational simplicity, room temperature and air conditions, minimal solvent, broad substrate scope, and recyclable cheap catalyst. Preliminary mechanistic studies revealed that highly polarized piezoelectric material acted as a single-electron transfer (SET) oxidation reagent for the key desulfurization process.</p>\",\"PeriodicalId\":57,\"journal\":{\"name\":\"Journal of Organic Chemistry\",\"volume\":\"90 7\",\"pages\":\"2816–2821 2816–2821\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-02-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Organic Chemistry\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.joc.4c02526\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Organic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.joc.4c02526","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0

摘要

采用压电材料(BaTiO3)作为氧化还原催化剂,在球磨条件下,以伯胺和二硫化碳为原料,机械氧化还原合成了芳香和脂肪族异硫氰酸酯。该方法具有反应时间短、操作简单、室温和空气条件好、溶剂用量少、底物适用范围广、催化剂可回收等特点。初步的机理研究表明,高极化压电材料在关键脱硫过程中充当单电子转移(SET)氧化试剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Mechanoredox-Enabled Isothiocyanation of Primary Amines Using Piezoelectric Material as the Redox Catalyst

Mechanoredox-Enabled Isothiocyanation of Primary Amines Using Piezoelectric Material as the Redox Catalyst

A novel mechanoredox-enabled synthesis of aromatic and aliphatic isothiocyanates from primary amines and carbon disulfide under ball milling conditions using a piezoelectric material (BaTiO3) as the redox catalyst has been developed. This method displays several features, such as short reaction time, operational simplicity, room temperature and air conditions, minimal solvent, broad substrate scope, and recyclable cheap catalyst. Preliminary mechanistic studies revealed that highly polarized piezoelectric material acted as a single-electron transfer (SET) oxidation reagent for the key desulfurization process.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Organic Chemistry
Journal of Organic Chemistry 化学-有机化学
CiteScore
6.20
自引率
11.10%
发文量
1467
审稿时长
2 months
期刊介绍: Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信