Bi4Ti3O12在40Bi2O3-40B2O3-20TiO2玻璃基体中结晶,用于光-压电催化染料降解

IF 3.2 4区 化学 Q2 CHEMISTRY, ANALYTICAL
Luminescence Pub Date : 2025-02-19 DOI:10.1002/bio.70124
Ashis Kumar Moharana, Akshay Gaur, Rahul Vaish
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引用次数: 0

摘要

光催化和压电催化的耦合已经引起了研究人员的极大兴趣。在这项研究中,我们展示了钛酸铋(Bi4Ti3O12)微晶玻璃(BTO-GC)的光-压催化活性。采用熔融淬火技术,在40Bi2O3-40B2O3-20TiO2 (mol %)玻璃体系中制备了BTO-GC样品。采用x射线衍射(XRD)技术和拉曼光谱对催化剂进行了结构和物相分析。利用扫描电镜(SEM)和x射线光电子能谱(XPS)对其表面形貌和化学成分进行了分析。对BTO-GC在光催化、压电催化和光压电催化过程中的催化性能进行了评价。采用紫外可见分光光度计对亚甲基蓝(MB)染料的降解进行了研究。在太阳能光催化过程中,最大降解率达到~86%。本研究强调了微晶玻璃的协同光压电催化性能,并促进了对其潜在机制的理解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Bi4Ti3O12 Crystallized in 40Bi2O3-40B2O3-20TiO2 Glass Matrix for Photo-Piezocatalytic Dye Degradation

The coupling of photocatalysis and piezocatalysis has gained significant interest among researchers. In this study, we present the photo-piezocatalytic activity exhibited by bismuth titanate (Bi4Ti3O12) glass-ceramics (BTO-GC). BTO-GC samples were prepared in a glass system of 40Bi2O3-40B2O3-20TiO2 (in mol %) by using the melt-quench technique. The catalyst was characterized by the X-ray diffraction (XRD) technique and Raman spectroscopy for its structure and phase analysis. Surface morphology and chemical composition were analyzed by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), respectively. The catalytic performance of BTO-GC was evaluated in photocatalysis, piezocatalysis, and photo-piezocatalysis processes. Methylene blue (MB) dye degradation was evaluated by using a UV–Vis spectrophotometer. A maximum degradation performance of ~86% was achieved in the solar light photocatalysis process. This study highlights the synergistic photo-piezocatalytic performance in glass-ceramics and advances the understanding of its underlying mechanism.

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来源期刊
Luminescence
Luminescence 生物-生化与分子生物学
CiteScore
5.10
自引率
13.80%
发文量
248
审稿时长
3.5 months
期刊介绍: Luminescence provides a forum for the publication of original scientific papers, short communications, technical notes and reviews on fundamental and applied aspects of all forms of luminescence, including bioluminescence, chemiluminescence, electrochemiluminescence, sonoluminescence, triboluminescence, fluorescence, time-resolved fluorescence and phosphorescence. Luminescence publishes papers on assays and analytical methods, instrumentation, mechanistic and synthetic studies, basic biology and chemistry. Luminescence also publishes details of forthcoming meetings, information on new products, and book reviews. A special feature of the Journal is surveys of the recent literature on selected topics in luminescence.
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