Changbao Jiang, Chunyao Huang, Jiayao Wu*, Deyong Wang, Baisheng Nie, Aiwen Wang and Yiran Zhu*,
{"title":"离子溶液在高压电脉冲压裂中的优化效果","authors":"Changbao Jiang, Chunyao Huang, Jiayao Wu*, Deyong Wang, Baisheng Nie, Aiwen Wang and Yiran Zhu*, ","doi":"10.1021/acs.energyfuels.4c0607610.1021/acs.energyfuels.4c06076","DOIUrl":null,"url":null,"abstract":"<p >High-voltage electric pulse (HVEP) technology holds significant potential in enhancing the permeability for coalbed methane extraction, and the introduction of ionic solutions greatly amplifies its fracturing effectiveness. To elucidate the optimization effects of different ionic solutions in HVEP technology, this study systematically compared the improvement in coal samples conductivity after treatment with KCl, MgCl<sub>2</sub>, and FeCl<sub>3</sub> solutions. Physical experiments on HVEP-induced coal fracturing were conducted to reveal the evolution of pore and fracture structures in coal and the associated permeability changes. The results demonstrate that: (1) ionic solution soaking significantly improves the conductivity of coal samples, reduces the difficulty of electrical breakdown, and enhances energy utilization efficiency. The improvement effects vary among solutions, with FeCl<sub>3</sub> showing the best performance for XT anthracite and MgCl<sub>2</sub> being more effective for SSP bituminous coal. (2) Compared to distilled water, ionic solution-treated coal samples exhibit significantly increased porosity and average pore size after breakdown, with an enhanced internal fracture network. The number of macropores and mesopores increases, while micropores and nanopores decrease, resulting in improved pore-throat connectivity. (3) In terms of permeability enhancement, the effects of the three ionic solutions surpass those of distilled water. Consistent with the conductivity improvement trend, FeCl<sub>3</sub> and MgCl<sub>2</sub> solutions demonstrated optimal permeability enhancement for XT and SSP coal samples, respectively. Therefore, when combining ionic solution treatment with HVEP technology for coal seam fracturing and permeability enhancement, it is crucial to consider the specific characteristics of the coal to select the most suitable ionic solution and achieve higher efficiency in permeability improvement.</p>","PeriodicalId":35,"journal":{"name":"Energy & Fuels","volume":"39 7","pages":"3528–3539 3528–3539"},"PeriodicalIF":5.3000,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Optimization Effects of Ionic Solutions on Coal Fracturing Using High-Voltage Electric Pulse\",\"authors\":\"Changbao Jiang, Chunyao Huang, Jiayao Wu*, Deyong Wang, Baisheng Nie, Aiwen Wang and Yiran Zhu*, \",\"doi\":\"10.1021/acs.energyfuels.4c0607610.1021/acs.energyfuels.4c06076\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >High-voltage electric pulse (HVEP) technology holds significant potential in enhancing the permeability for coalbed methane extraction, and the introduction of ionic solutions greatly amplifies its fracturing effectiveness. To elucidate the optimization effects of different ionic solutions in HVEP technology, this study systematically compared the improvement in coal samples conductivity after treatment with KCl, MgCl<sub>2</sub>, and FeCl<sub>3</sub> solutions. Physical experiments on HVEP-induced coal fracturing were conducted to reveal the evolution of pore and fracture structures in coal and the associated permeability changes. The results demonstrate that: (1) ionic solution soaking significantly improves the conductivity of coal samples, reduces the difficulty of electrical breakdown, and enhances energy utilization efficiency. The improvement effects vary among solutions, with FeCl<sub>3</sub> showing the best performance for XT anthracite and MgCl<sub>2</sub> being more effective for SSP bituminous coal. (2) Compared to distilled water, ionic solution-treated coal samples exhibit significantly increased porosity and average pore size after breakdown, with an enhanced internal fracture network. The number of macropores and mesopores increases, while micropores and nanopores decrease, resulting in improved pore-throat connectivity. (3) In terms of permeability enhancement, the effects of the three ionic solutions surpass those of distilled water. Consistent with the conductivity improvement trend, FeCl<sub>3</sub> and MgCl<sub>2</sub> solutions demonstrated optimal permeability enhancement for XT and SSP coal samples, respectively. Therefore, when combining ionic solution treatment with HVEP technology for coal seam fracturing and permeability enhancement, it is crucial to consider the specific characteristics of the coal to select the most suitable ionic solution and achieve higher efficiency in permeability improvement.</p>\",\"PeriodicalId\":35,\"journal\":{\"name\":\"Energy & Fuels\",\"volume\":\"39 7\",\"pages\":\"3528–3539 3528–3539\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2025-02-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Energy & Fuels\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.energyfuels.4c06076\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy & Fuels","FirstCategoryId":"5","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.energyfuels.4c06076","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Optimization Effects of Ionic Solutions on Coal Fracturing Using High-Voltage Electric Pulse
High-voltage electric pulse (HVEP) technology holds significant potential in enhancing the permeability for coalbed methane extraction, and the introduction of ionic solutions greatly amplifies its fracturing effectiveness. To elucidate the optimization effects of different ionic solutions in HVEP technology, this study systematically compared the improvement in coal samples conductivity after treatment with KCl, MgCl2, and FeCl3 solutions. Physical experiments on HVEP-induced coal fracturing were conducted to reveal the evolution of pore and fracture structures in coal and the associated permeability changes. The results demonstrate that: (1) ionic solution soaking significantly improves the conductivity of coal samples, reduces the difficulty of electrical breakdown, and enhances energy utilization efficiency. The improvement effects vary among solutions, with FeCl3 showing the best performance for XT anthracite and MgCl2 being more effective for SSP bituminous coal. (2) Compared to distilled water, ionic solution-treated coal samples exhibit significantly increased porosity and average pore size after breakdown, with an enhanced internal fracture network. The number of macropores and mesopores increases, while micropores and nanopores decrease, resulting in improved pore-throat connectivity. (3) In terms of permeability enhancement, the effects of the three ionic solutions surpass those of distilled water. Consistent with the conductivity improvement trend, FeCl3 and MgCl2 solutions demonstrated optimal permeability enhancement for XT and SSP coal samples, respectively. Therefore, when combining ionic solution treatment with HVEP technology for coal seam fracturing and permeability enhancement, it is crucial to consider the specific characteristics of the coal to select the most suitable ionic solution and achieve higher efficiency in permeability improvement.
期刊介绍:
Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.