锡基催化剂在电化学CO2还原中的不同活性转移：单原子与多原子结构的ph依赖行为

IF 16.9 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Angewandte Chemie International Edition Pub Date : 2025-02-17 DOI:10.1002/anie.202580861

Yuhang Wang, Di Zhang, Bin Sun, Xue Jia, Linda Zhang, Hefeng Cheng, Jun Fan, Hao Li

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引用次数: 0

摘要

在他们的通讯（e202418228）中，李浩和同事揭示了一个令人兴奋的对比：*OCHO在Sn- n4 - c和多原子Sn上的结合强度的电场响应表现出相反的行为。这种反应导致了Sn- n4 - c和多原子Sn的一个迷人的，相反的ph依赖火山演化。最重要的是，我们提出了使用单原子和多原子金属催化剂设计催化剂的不同策略。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Frontispiece: Divergent Activity Shifts of Tin-Based Catalysts for Electrochemical CO2 Reduction: pH-Dependent Behavior of Single-Atom Versus Polyatomic Structures

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Frontispiece: Divergent Activity Shifts of Tin-Based Catalysts for Electrochemical CO2 Reduction: pH-Dependent Behavior of Single-Atom Versus Polyatomic Structures

In their Communication (e202418228), Hao Li and co-workers reveal an exciting contrast: the electric field response of the binding strength of *OCHO on Sn-N4-C and polyatomic Sn displays opposite behaviors. This response results in a fascinating, opposite pH-dependent volcano evolution for Sn-N4-C and polyatomic Sn. Most importantly, we propose that distinct strategies are necessary for designing catalysts using single-atom versus polyatomic metal catalysts.

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来源期刊

Angewandte Chemie International Edition 化学-化学综合

CiteScore

26.60

自引率

6.60%

发文量

3549

审稿时长

1.5 months

期刊介绍： Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.