{"title":"单核Pt（II）配合物和[Pt- ag -Pt]簇：可控合成、结构跃迁和发光调制","authors":"Xin-Tong Lv, Jian-Gong Huang, Deng-Ke Cao","doi":"10.1002/ejic.202400714","DOIUrl":null,"url":null,"abstract":"<p>Complexes [Pt(moppy)(PPh<sub>2</sub>Py)Cl] (<b>1</b>), [Pt(moppy)(PPh<sub>2</sub>Py)]PF<sub>6</sub> (<b>2</b>) and [Pt<sub>2</sub>(moppy)<sub>2</sub>(CH<sub>3</sub>CN)<sub>2</sub>Ag(<i>μ</i>-PPh<sub>2</sub>Py)<sub>2</sub>](PF<sub>6</sub>)<sub>3</sub> (<b>3</b>) have been synthesized through choosing suitable experimental condition to modulate the coordination mode of PPh<sub>2</sub>Py. Crystal structures indicate that <b>1</b> and <b>2</b> show distinct mononuclear structures, and complex <b>3</b> is a [Pt−Ag-Pt] cluster. In a CH<sub>2</sub>Cl<sub>2</sub>–H<sub>2</sub>O mixed solvent, complexes <b>1</b> and <b>2</b> can be interconverted upon alternately adding AgPF<sub>6</sub> and NaCl. Complex <b>3</b> can dissociate into complex <b>2</b> in solution. These complexes reveal different luminescence. In deaerated acetone, complex <b>1</b> is non-luminescent, while <b>2</b> show green luminescence with main emission bands at 511 and 534 nm. Complexes <b>1</b> and <b>2</b> in solid state show similar green luminescence, but significant differences in quantum yield, <i>Φ</i>=7.4 % for <b>1</b>, and <i>Φ</i>=17.6 % for <b>2</b>. Compared to <b>1</b> and <b>2</b>, complex <b>3</b>⋅CH<sub>3</sub>COCH<sub>3</sub> exhibits yellow solid-state luminescecne (<i>Φ</i>=14.1 %). In this paper, we discuss structural transitions among complexes <b>1</b>–<b>3</b> and luminescence modulation.</p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 5","pages":""},"PeriodicalIF":2.2000,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mononuclear Pt(II) Complexes and [Pt-Ag-Pt] Cluster: Controllable Syntheses, Structural Transition and Luminescence Modulation\",\"authors\":\"Xin-Tong Lv, Jian-Gong Huang, Deng-Ke Cao\",\"doi\":\"10.1002/ejic.202400714\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Complexes [Pt(moppy)(PPh<sub>2</sub>Py)Cl] (<b>1</b>), [Pt(moppy)(PPh<sub>2</sub>Py)]PF<sub>6</sub> (<b>2</b>) and [Pt<sub>2</sub>(moppy)<sub>2</sub>(CH<sub>3</sub>CN)<sub>2</sub>Ag(<i>μ</i>-PPh<sub>2</sub>Py)<sub>2</sub>](PF<sub>6</sub>)<sub>3</sub> (<b>3</b>) have been synthesized through choosing suitable experimental condition to modulate the coordination mode of PPh<sub>2</sub>Py. Crystal structures indicate that <b>1</b> and <b>2</b> show distinct mononuclear structures, and complex <b>3</b> is a [Pt−Ag-Pt] cluster. In a CH<sub>2</sub>Cl<sub>2</sub>–H<sub>2</sub>O mixed solvent, complexes <b>1</b> and <b>2</b> can be interconverted upon alternately adding AgPF<sub>6</sub> and NaCl. Complex <b>3</b> can dissociate into complex <b>2</b> in solution. These complexes reveal different luminescence. In deaerated acetone, complex <b>1</b> is non-luminescent, while <b>2</b> show green luminescence with main emission bands at 511 and 534 nm. Complexes <b>1</b> and <b>2</b> in solid state show similar green luminescence, but significant differences in quantum yield, <i>Φ</i>=7.4 % for <b>1</b>, and <i>Φ</i>=17.6 % for <b>2</b>. Compared to <b>1</b> and <b>2</b>, complex <b>3</b>⋅CH<sub>3</sub>COCH<sub>3</sub> exhibits yellow solid-state luminescecne (<i>Φ</i>=14.1 %). In this paper, we discuss structural transitions among complexes <b>1</b>–<b>3</b> and luminescence modulation.</p>\",\"PeriodicalId\":38,\"journal\":{\"name\":\"European Journal of Inorganic Chemistry\",\"volume\":\"28 5\",\"pages\":\"\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2025-01-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202400714\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Inorganic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202400714","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Mononuclear Pt(II) Complexes and [Pt-Ag-Pt] Cluster: Controllable Syntheses, Structural Transition and Luminescence Modulation
Complexes [Pt(moppy)(PPh2Py)Cl] (1), [Pt(moppy)(PPh2Py)]PF6 (2) and [Pt2(moppy)2(CH3CN)2Ag(μ-PPh2Py)2](PF6)3 (3) have been synthesized through choosing suitable experimental condition to modulate the coordination mode of PPh2Py. Crystal structures indicate that 1 and 2 show distinct mononuclear structures, and complex 3 is a [Pt−Ag-Pt] cluster. In a CH2Cl2–H2O mixed solvent, complexes 1 and 2 can be interconverted upon alternately adding AgPF6 and NaCl. Complex 3 can dissociate into complex 2 in solution. These complexes reveal different luminescence. In deaerated acetone, complex 1 is non-luminescent, while 2 show green luminescence with main emission bands at 511 and 534 nm. Complexes 1 and 2 in solid state show similar green luminescence, but significant differences in quantum yield, Φ=7.4 % for 1, and Φ=17.6 % for 2. Compared to 1 and 2, complex 3⋅CH3COCH3 exhibits yellow solid-state luminescecne (Φ=14.1 %). In this paper, we discuss structural transitions among complexes 1–3 and luminescence modulation.
期刊介绍：
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
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