Menestreau Paul, Alejandro Grimm, Glaydson Simões Dos Reis, Gopinathan Manavalan, Sruthy E S, Mikael Thyrel, Shaikshavali Petnikota
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引用次数: 0
摘要
由于其可持续的方法,生物质是许多研究的主题,集中在多功能材料的合成,包括电池电极和超级电容器。在这项工作中,桦木原木加工过程中的锯末被用来生产一种高多孔碳材料(CBW),该材料用于铝电池(ABs)和超级电容器(SCs)的电极结构。大量的表征表明,CBW是由高度无序的无定形碳和极高的比表面积(3029 m2 g−1)组成的,以微孔特征为主。生化武器的化学分析表明存在大量的氧官能团。作为AB的阴极,CBW在0.1、1.0、2.0、3.0、4.0、5.0和10.0 a g−1电流下的放电容量分别为115、74、54、50、47、43和29 mAh g−1。同样,具有CBW对称电极的SC在电流速率为0.1、0.5、1.0、2.0、3.0、4.0、5.0和10.0 A g−1时的电容分别为143、94、87、79、74、69、65和51 F g−1。电化学表征表明,CBW对ABs和SCs具有良好的应用前景,控制其孔隙类型可以进一步提高其性能。
Activated Carbon from Birch Wood as an Electrode Material for Aluminum Batteries and Supercapacitors
Due to its sustainable approach, biomass is the subject of much research focused on the synthesis of multifunctional materials including electrodes for batteries and supercapacitors. In this work, sawdust from the processing of birch logs was used to produce a highly porous carbon material (CBW) that is employed for the construction of electrodes for aluminum batteries (ABs) and supercapacitors (SCs). A multitude of characterizations indicated that CBW is built in with highly disordered amorphous carbons and an extremely high specific surface area of 3029 m2 g−1 which is predominant with microporous features. The chemical analysis of CBW indicated the presence of a significant amount of oxygen functionalities. As a cathode of AB, CBW achieved discharge capacities 115, 74, 54, 50, 47, 43, and 29 mAh g−1 at current rates 0.1, 1.0, 2.0, 3.0, 4.0, 5.0, and 10.0 A g−1, respectively. Similarly, SC with CBW symmetric electrodes exhibited capacitances 143, 94, 87, 79, 74, 69, 65, and 51 F g−1 at current rates 0.1, 0.5, 1.0, 2.0, 3.0, 4.0, 5.0, and 10.0 A g−1, respectively. The electrochemical characterization revealed that CBW is promising for ABs and SCs, and controlling the porosity type could further enhance the performance.
期刊介绍:
ChemElectroChem is aimed to become a top-ranking electrochemistry journal for primary research papers and critical secondary information from authors across the world. The journal covers the entire scope of pure and applied electrochemistry, the latter encompassing (among others) energy applications, electrochemistry at interfaces (including surfaces), photoelectrochemistry and bioelectrochemistry.