{"title":"工程仿生亚纳米结构离子选择性纳滤膜对Li+/Co2+的优异分离","authors":"Yanrui Wang, Haochun Wang, Yating Hu, Meng Zhang, Zixin Ma, Shu Jiang, Jinlong Wang, Heng Liang, Xiaobin Tang","doi":"10.1002/eem2.12845","DOIUrl":null,"url":null,"abstract":"<p>Nanofiltration (NF) membranes with exceptional ion selectivity and permeability are needed for the recovery of lithium from waste lithium-ion batteries. Herein, inspired by the homogeneous microchannels in the skeletal structure of glass sponges, an innovative biomimetic sponge-like sub-nanostructured NF membrane was designed using an alkali-induced MXene (AMXene)-ethyl formate (EF)-induced bulk/interfacial diffusion decoupling strategy to simultaneously improve Li<sup>+</sup>/Co<sup>2+</sup> selectivity and membrane permeability. The Li<sup>+</sup>/Co<sup>2+</sup> separation factor (S<sub>Li,Co</sub> = 24) of the engineered membrane was improved by an order of magnitude compared to that of an NF270 membrane (S<sub>Li,Co</sub> = 2). The selectivity of Mg<sup>2+</sup>/Na<sup>+</sup> (<span></span><math>\n <msub>\n <mi>B</mi>\n <mtext>NaCl</mtext>\n </msub>\n <mo>/</mo>\n <msub>\n <mi>B</mi>\n <msub>\n <mtext>MgCl</mtext>\n <mn>2</mn>\n </msub>\n </msub></math> = 286) and <span></span><math>\n <mrow>\n <msubsup>\n <mi>SO</mi>\n <mn>4</mn>\n <mrow>\n <mn>2</mn>\n <mo>−</mo>\n </mrow>\n </msubsup>\n </mrow></math>/Cl<sup>−</sup> (<span></span><math>\n <msub>\n <mi>B</mi>\n <mtext>NaCl</mtext>\n </msub>\n <mo>/</mo>\n <msub>\n <mi>B</mi>\n <msub>\n <mtext>NaSO</mtext>\n <mn>4</mn>\n </msub>\n </msub></math> = 941) increased by 3 ~ 12 times, and the permeability (25.8 L m<sup>−2</sup> h<sup>−1</sup> bar<sup>−1</sup>) remained at a desirable level, beyond the current upper bound of the other cutting-edge membranes. The superior performance was attributed to the limited release of amine in bulk phase and the boosted interfacial diffusion by reducing interfacial energy barrier during the interfacial polymerization reaction, which were realized via the synergetic effects of AMXene and EF. This approach yielded a biomimetic sponge-like sub-nanostructured NF membrane with controlled homogeneous pore radii (0.202 nm) and a thickness as small as 16.08 nm, which led to high ion selectivity and permeability. The engineered membrane was capable of efficient separation and recovery of Li<sup>+</sup>/metal ions.</p>","PeriodicalId":11554,"journal":{"name":"Energy & Environmental Materials","volume":"8 2","pages":""},"PeriodicalIF":13.0000,"publicationDate":"2024-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.12845","citationCount":"0","resultStr":"{\"title\":\"Engineering Biomimetic Sub-Nanostructured Ion-Selective Nanofiltration Membrane for Excellent Separation of Li+/Co2+\",\"authors\":\"Yanrui Wang, Haochun Wang, Yating Hu, Meng Zhang, Zixin Ma, Shu Jiang, Jinlong Wang, Heng Liang, Xiaobin Tang\",\"doi\":\"10.1002/eem2.12845\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Nanofiltration (NF) membranes with exceptional ion selectivity and permeability are needed for the recovery of lithium from waste lithium-ion batteries. Herein, inspired by the homogeneous microchannels in the skeletal structure of glass sponges, an innovative biomimetic sponge-like sub-nanostructured NF membrane was designed using an alkali-induced MXene (AMXene)-ethyl formate (EF)-induced bulk/interfacial diffusion decoupling strategy to simultaneously improve Li<sup>+</sup>/Co<sup>2+</sup> selectivity and membrane permeability. The Li<sup>+</sup>/Co<sup>2+</sup> separation factor (S<sub>Li,Co</sub> = 24) of the engineered membrane was improved by an order of magnitude compared to that of an NF270 membrane (S<sub>Li,Co</sub> = 2). The selectivity of Mg<sup>2+</sup>/Na<sup>+</sup> (<span></span><math>\\n <msub>\\n <mi>B</mi>\\n <mtext>NaCl</mtext>\\n </msub>\\n <mo>/</mo>\\n <msub>\\n <mi>B</mi>\\n <msub>\\n <mtext>MgCl</mtext>\\n <mn>2</mn>\\n </msub>\\n </msub></math> = 286) and <span></span><math>\\n <mrow>\\n <msubsup>\\n <mi>SO</mi>\\n <mn>4</mn>\\n <mrow>\\n <mn>2</mn>\\n <mo>−</mo>\\n </mrow>\\n </msubsup>\\n </mrow></math>/Cl<sup>−</sup> (<span></span><math>\\n <msub>\\n <mi>B</mi>\\n <mtext>NaCl</mtext>\\n </msub>\\n <mo>/</mo>\\n <msub>\\n <mi>B</mi>\\n <msub>\\n <mtext>NaSO</mtext>\\n <mn>4</mn>\\n </msub>\\n </msub></math> = 941) increased by 3 ~ 12 times, and the permeability (25.8 L m<sup>−2</sup> h<sup>−1</sup> bar<sup>−1</sup>) remained at a desirable level, beyond the current upper bound of the other cutting-edge membranes. The superior performance was attributed to the limited release of amine in bulk phase and the boosted interfacial diffusion by reducing interfacial energy barrier during the interfacial polymerization reaction, which were realized via the synergetic effects of AMXene and EF. This approach yielded a biomimetic sponge-like sub-nanostructured NF membrane with controlled homogeneous pore radii (0.202 nm) and a thickness as small as 16.08 nm, which led to high ion selectivity and permeability. The engineered membrane was capable of efficient separation and recovery of Li<sup>+</sup>/metal ions.</p>\",\"PeriodicalId\":11554,\"journal\":{\"name\":\"Energy & Environmental Materials\",\"volume\":\"8 2\",\"pages\":\"\"},\"PeriodicalIF\":13.0000,\"publicationDate\":\"2024-11-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eem2.12845\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Energy & Environmental Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/eem2.12845\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy & Environmental Materials","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/eem2.12845","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
从废锂离子电池中回收锂需要具有优异离子选择性和渗透性的纳滤膜。在此,受玻璃海绵骨架结构中均匀微通道的启发,采用碱诱导MXene (AMXene)-甲酸乙酯(EF)诱导体/界面扩散解耦策略,设计了一种创新的仿生海绵状亚纳米纳滤膜,同时提高了Li+/Co2+的选择性和膜的通透性。与NF270膜(SLi,Co = 2)相比,工程膜的Li+/Co2+分离系数(SLi,Co = 24)提高了一个数量级。Mg2+/Na+ (B NaCl / B MgCl 2 = 286)和so4 2−/Cl−(B NaCl / B NaSO 4 = 941)提高了3 ~ 12倍,渗透率(25.8 L m−2 h−1 bar−1)保持在理想水平,超过了目前其他前沿膜的上限。这种优异的性能是由于AMXene和EF的协同作用,在界面聚合反应中,抑制了胺在体相中的释放,降低了界面能垒,促进了界面扩散。该方法制备了一种仿生海绵状亚纳米结构的纳滤膜,具有可控的均匀孔半径(0.202 nm),厚度小至16.08 nm,具有高离子选择性和高渗透性。该工程膜能够有效地分离和回收Li+/金属离子。
Engineering Biomimetic Sub-Nanostructured Ion-Selective Nanofiltration Membrane for Excellent Separation of Li+/Co2+
Nanofiltration (NF) membranes with exceptional ion selectivity and permeability are needed for the recovery of lithium from waste lithium-ion batteries. Herein, inspired by the homogeneous microchannels in the skeletal structure of glass sponges, an innovative biomimetic sponge-like sub-nanostructured NF membrane was designed using an alkali-induced MXene (AMXene)-ethyl formate (EF)-induced bulk/interfacial diffusion decoupling strategy to simultaneously improve Li+/Co2+ selectivity and membrane permeability. The Li+/Co2+ separation factor (SLi,Co = 24) of the engineered membrane was improved by an order of magnitude compared to that of an NF270 membrane (SLi,Co = 2). The selectivity of Mg2+/Na+ ( = 286) and /Cl− ( = 941) increased by 3 ~ 12 times, and the permeability (25.8 L m−2 h−1 bar−1) remained at a desirable level, beyond the current upper bound of the other cutting-edge membranes. The superior performance was attributed to the limited release of amine in bulk phase and the boosted interfacial diffusion by reducing interfacial energy barrier during the interfacial polymerization reaction, which were realized via the synergetic effects of AMXene and EF. This approach yielded a biomimetic sponge-like sub-nanostructured NF membrane with controlled homogeneous pore radii (0.202 nm) and a thickness as small as 16.08 nm, which led to high ion selectivity and permeability. The engineered membrane was capable of efficient separation and recovery of Li+/metal ions.
期刊介绍:
Energy & Environmental Materials (EEM) is an international journal published by Zhengzhou University in collaboration with John Wiley & Sons, Inc. The journal aims to publish high quality research related to materials for energy harvesting, conversion, storage, and transport, as well as for creating a cleaner environment. EEM welcomes research work of significant general interest that has a high impact on society-relevant technological advances. The scope of the journal is intentionally broad, recognizing the complexity of issues and challenges related to energy and environmental materials. Therefore, interdisciplinary work across basic science and engineering disciplines is particularly encouraged. The areas covered by the journal include, but are not limited to, materials and composites for photovoltaics and photoelectrochemistry, bioprocessing, batteries, fuel cells, supercapacitors, clean air, and devices with multifunctionality. The readership of the journal includes chemical, physical, biological, materials, and environmental scientists and engineers from academia, industry, and policy-making.