C. Thirupathi, J. Bosco Franklin, J. Mohemed Ali, M. Mercy Jenifer, M. Sangamithirai, S. John Sundaram, Mir Waqas Alam, Pitcheri Rosaiah
{"title":"探索ZnO/CuO/g-C3N4纳米复合材料的优异储能性能","authors":"C. Thirupathi, J. Bosco Franklin, J. Mohemed Ali, M. Mercy Jenifer, M. Sangamithirai, S. John Sundaram, Mir Waqas Alam, Pitcheri Rosaiah","doi":"10.1007/s10971-025-06671-2","DOIUrl":null,"url":null,"abstract":"<div><p>In this study, the synthesis and electrochemical performance of a zinc oxide/copper oxide/graphitic carbon nitride ZnO/CuO/g-C₃N₄ composite for energy storage applications were investigated. The synthesis was carried out using a multi-step process, where ZnO/CuO was prepared via co-precipitation, and g-C₃N₄ was synthesized through thermal polymerization. Fourier-transform infrared spectroscopy (FTIR) revealed the presence of metal-oxide bonds and carbon-nitrogen functional groups, verifying the successful integration of g-C₃N₄ into the ZnO/CuO system. UV-visible absorption studies exhibited a red shift and a broader absorption band in the ZnO/CuO/g-C₃N₄ composite, indicating enhanced optical properties, which are favorable for energy storage applications. Furthermore, cyclic voltammetry (CV) measurements demonstrated superior capacitance and excellent rate capability, achieving a specific capacitance of 253 F/g at a scan rate of 10 mV/s. The combined structural, optical, and electrochemical properties of the ZnO/CuO/g-C₃N₄ composite underscore its potential as an advanced material for energy storage applications.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":"113 3","pages":"885 - 895"},"PeriodicalIF":2.3000,"publicationDate":"2025-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Exploring the ZnO/CuO/g-C3N4 nanocomposite for superior energy storage capabilities\",\"authors\":\"C. Thirupathi, J. Bosco Franklin, J. Mohemed Ali, M. Mercy Jenifer, M. Sangamithirai, S. John Sundaram, Mir Waqas Alam, Pitcheri Rosaiah\",\"doi\":\"10.1007/s10971-025-06671-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this study, the synthesis and electrochemical performance of a zinc oxide/copper oxide/graphitic carbon nitride ZnO/CuO/g-C₃N₄ composite for energy storage applications were investigated. The synthesis was carried out using a multi-step process, where ZnO/CuO was prepared via co-precipitation, and g-C₃N₄ was synthesized through thermal polymerization. Fourier-transform infrared spectroscopy (FTIR) revealed the presence of metal-oxide bonds and carbon-nitrogen functional groups, verifying the successful integration of g-C₃N₄ into the ZnO/CuO system. UV-visible absorption studies exhibited a red shift and a broader absorption band in the ZnO/CuO/g-C₃N₄ composite, indicating enhanced optical properties, which are favorable for energy storage applications. Furthermore, cyclic voltammetry (CV) measurements demonstrated superior capacitance and excellent rate capability, achieving a specific capacitance of 253 F/g at a scan rate of 10 mV/s. The combined structural, optical, and electrochemical properties of the ZnO/CuO/g-C₃N₄ composite underscore its potential as an advanced material for energy storage applications.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":664,\"journal\":{\"name\":\"Journal of Sol-Gel Science and Technology\",\"volume\":\"113 3\",\"pages\":\"885 - 895\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2025-01-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Sol-Gel Science and Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10971-025-06671-2\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Sol-Gel Science and Technology","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10971-025-06671-2","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Exploring the ZnO/CuO/g-C3N4 nanocomposite for superior energy storage capabilities
In this study, the synthesis and electrochemical performance of a zinc oxide/copper oxide/graphitic carbon nitride ZnO/CuO/g-C₃N₄ composite for energy storage applications were investigated. The synthesis was carried out using a multi-step process, where ZnO/CuO was prepared via co-precipitation, and g-C₃N₄ was synthesized through thermal polymerization. Fourier-transform infrared spectroscopy (FTIR) revealed the presence of metal-oxide bonds and carbon-nitrogen functional groups, verifying the successful integration of g-C₃N₄ into the ZnO/CuO system. UV-visible absorption studies exhibited a red shift and a broader absorption band in the ZnO/CuO/g-C₃N₄ composite, indicating enhanced optical properties, which are favorable for energy storage applications. Furthermore, cyclic voltammetry (CV) measurements demonstrated superior capacitance and excellent rate capability, achieving a specific capacitance of 253 F/g at a scan rate of 10 mV/s. The combined structural, optical, and electrochemical properties of the ZnO/CuO/g-C₃N₄ composite underscore its potential as an advanced material for energy storage applications.
期刊介绍:
The primary objective of the Journal of Sol-Gel Science and Technology (JSST), the official journal of the International Sol-Gel Society, is to provide an international forum for the dissemination of scientific, technological, and general knowledge about materials processed by chemical nanotechnologies known as the "sol-gel" process. The materials of interest include gels, gel-derived glasses, ceramics in form of nano- and micro-powders, bulk, fibres, thin films and coatings as well as more recent materials such as hybrid organic-inorganic materials and composites. Such materials exhibit a wide range of optical, electronic, magnetic, chemical, environmental, and biomedical properties and functionalities. Methods for producing sol-gel-derived materials and the industrial uses of these materials are also of great interest.