Rb3CoCl4NO3晶体的结构、光谱特性和相变

IF 0.6 4区材料科学 Q4 CRYSTALLOGRAPHY

Crystallography Reports Pub Date : 2025-02-16 DOI:10.1134/S1063774524602089

A. V. Gudymenko, V. A. Komornikov, N. I. Sorokina, T. A. Sorokin, I. S. Timakov, D. S. Matveeva, A. E. Voloshin

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引用次数: 0

摘要

首次获得了适用于光谱特性研究的Rb3CoCl4NO3样品，并在λ = 200-800 nm波长范围内进行了研究。透明窗口位于紫外可见和可见-红外边界。差示扫描量热/热重分析表明，Rb3CoCl4NO3晶体热稳定，熔体不分解，经历了两次可逆相变。在293 ~ 625 K的温度范围内，用x射线衍射研究了Rb3CoCl4NO3单晶的结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Structure, Spectral Characteristics, and Phase Transitions in the Rb3CoCl4NO3 Crystal

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Structure, Spectral Characteristics, and Phase Transitions in the Rb3CoCl4NO3 Crystal

Rb₃CoCl₄NO₃ samples applicable for studying spectral characteristics have been obtained for the first time and investigated in the wavelength range λ = 200–800 nm. Transparency windows are found at the UV–visible and visible–IR boundaries. Differential-scanning calorimetry/thermogravimetry analysis revealed that the Rb₃CoCl₄NO₃ crystal is thermally stable, melts without decomposition, and undergoes two reversible phase transitions. The structure of Rb₃CoCl₄NO₃ single crystals was studied by X-ray diffraction in the temperature range of 293–625 K.

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来源期刊

Crystallography Reports 化学-晶体学

CiteScore

1.10

自引率

28.60%

发文量

审稿时长

4-8 weeks

期刊介绍： Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.