硫酸肼的多态改性：液相结晶及一些性能

IF 0.6 4区材料科学 Q4 CRYSTALLOGRAPHY

Crystallography Reports Pub Date : 2025-02-16 DOI:10.1134/S1063774524602119

M. V. Kudryashov, P. D. Drozhilkin, N. V. Somov

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引用次数: 0

摘要

研究了硫酸肼在5 ~ 35℃水溶液中形成正交和单斜多晶改性。得到了硫酸肼在5 ~ 25℃范围内的水溶解度曲线。结果表明，随着生长温度的降低，沉淀的单斜硫酸肼晶体的质量分数增加。当冷却到液氮的沸腾温度时，检测到可能的温度诱导从正交型到单斜型的转变。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Hydrazine Sulfate Polymorphic Modifications: Liquid Phase Crystallization and Some Properties

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Hydrazine Sulfate Polymorphic Modifications: Liquid Phase Crystallization and Some Properties

The formation of orthorhombic and monoclinic polymorphic modifications of hydrazine sulfate from an aqueous solution in the temperature range from 5 to 35°C was studied. A curve of the hydrazine sulfate solubility in water in the range of 5–25°C was obtained. It is shown that, with a decrease in the growth temperature, the mass fraction of precipitated monoclinic hydrazine sulfate crystals increases. A possible temperature-induced transition from the orthorhombic to the monoclinic modification was detected when cooling to the boiling temperature of liquid nitrogen.

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来源期刊

Crystallography Reports 化学-晶体学

CiteScore

1.10

自引率

28.60%

发文量

审稿时长

4-8 weeks

期刊介绍： Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.