{"title":"可持续建筑解决方案:糖厂石灰废料-活性矿渣在高性能混凝土中的作用","authors":"Hadi Bahmani, Davood Mostofinejad","doi":"10.1016/j.asej.2025.103315","DOIUrl":null,"url":null,"abstract":"<div><div>This pioneering research aims to develop high-performance concrete (HPC) using waste lime from sugar factories to activate slag. The study explores the transformative effects of high-temperature treatment on sugar factory lime waste and its potential to enhance slag activation, representing a novel approach in sustainable construction materials. The newly formulated HPC was rigorously compared with traditional counterparts made from calcium oxide-activated slag and calcined dolomite. A comprehensive series of tests were conducted at 28 days, assessing critical performance metrics, including compressive strength, four-point bending strength, tensile strength, and water absorption. Microstructural analysis was performed using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDAX), and Fourier Transform Infrared Spectroscopy (FTIR). The results revealed that samples activated with 10 % sugar factory lime waste achieved a compressive strength of approximately 80 MPa, rivaling samples activated with 10 % calcium oxide. These lime-activated samples also demonstrated outstanding tensile and bending strengths of 5.6 MPa and 6.6 MPa, respectively—the highest recorded in this study. The microstructural analysis indicated a dense microstructure with an elevated Si/Al ratio and significant geopolymerization. The low water absorption rate of 2.1 % highlighted the reduced porosity of this innovative geopolymeric matrix. This research is the first to investigate the high-temperature treatment of sugar factory lime waste for slag activation in HPC. The findings suggest that incorporating 10 % waste lime significantly lowers the climate change impact index to 397.6 kg CO<sub>2</sub> eq—12 % less than samples with 30 % calcium oxide and 7 % lower than those with 30 % dolomite. Using sugar factory waste lime enhances mechanical properties and promotes environmental sustainability, presenting a compelling alternative that excels in both performance and ecological benefits.</div></div>","PeriodicalId":48648,"journal":{"name":"Ain Shams Engineering Journal","volume":"16 3","pages":"Article 103315"},"PeriodicalIF":6.0000,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sustainable construction solutions: The role of sugar factory lime waste-activated slag in high-performance concrete\",\"authors\":\"Hadi Bahmani, Davood Mostofinejad\",\"doi\":\"10.1016/j.asej.2025.103315\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This pioneering research aims to develop high-performance concrete (HPC) using waste lime from sugar factories to activate slag. The study explores the transformative effects of high-temperature treatment on sugar factory lime waste and its potential to enhance slag activation, representing a novel approach in sustainable construction materials. The newly formulated HPC was rigorously compared with traditional counterparts made from calcium oxide-activated slag and calcined dolomite. A comprehensive series of tests were conducted at 28 days, assessing critical performance metrics, including compressive strength, four-point bending strength, tensile strength, and water absorption. Microstructural analysis was performed using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDAX), and Fourier Transform Infrared Spectroscopy (FTIR). The results revealed that samples activated with 10 % sugar factory lime waste achieved a compressive strength of approximately 80 MPa, rivaling samples activated with 10 % calcium oxide. These lime-activated samples also demonstrated outstanding tensile and bending strengths of 5.6 MPa and 6.6 MPa, respectively—the highest recorded in this study. The microstructural analysis indicated a dense microstructure with an elevated Si/Al ratio and significant geopolymerization. The low water absorption rate of 2.1 % highlighted the reduced porosity of this innovative geopolymeric matrix. This research is the first to investigate the high-temperature treatment of sugar factory lime waste for slag activation in HPC. The findings suggest that incorporating 10 % waste lime significantly lowers the climate change impact index to 397.6 kg CO<sub>2</sub> eq—12 % less than samples with 30 % calcium oxide and 7 % lower than those with 30 % dolomite. Using sugar factory waste lime enhances mechanical properties and promotes environmental sustainability, presenting a compelling alternative that excels in both performance and ecological benefits.</div></div>\",\"PeriodicalId\":48648,\"journal\":{\"name\":\"Ain Shams Engineering Journal\",\"volume\":\"16 3\",\"pages\":\"Article 103315\"},\"PeriodicalIF\":6.0000,\"publicationDate\":\"2025-02-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ain Shams Engineering Journal\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2090447925000565\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ain Shams Engineering Journal","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2090447925000565","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
这项开创性的研究旨在开发高性能混凝土(HPC),利用制糖厂的废石灰来激活矿渣。该研究探讨了高温处理对糖厂石灰废物的转化作用及其增强炉渣活化的潜力,代表了可持续建筑材料的一种新方法。将新配方的高性能混凝土与传统的氧化钙活化渣和煅烧白云石制成的高性能混凝土进行了严格比较。在28天内进行了一系列全面的测试,评估关键性能指标,包括抗压强度、四点弯曲强度、拉伸强度和吸水率。显微结构分析采用扫描电镜(SEM)、能量色散x射线光谱(EDAX)和傅里叶变换红外光谱(FTIR)进行。结果表明,10%糖厂石灰废物活化的样品达到了约80 MPa的抗压强度,与10%氧化钙活化的样品相媲美。这些石灰活化的样品也表现出出色的拉伸和弯曲强度,分别为5.6 MPa和6.6 MPa,这是本研究中记录的最高强度。显微结构分析表明,其微观结构致密,硅铝比升高,地聚合作用显著。低吸水率为2.1%,突出表明这种创新的地聚合物基质降低了孔隙率。本研究首次研究了高温处理制糖厂石灰废渣的高效液相色谱法炉渣活化。研究结果表明,添加10%的废石灰可显著降低气候变化影响指数至397.6 kg CO2当量,比添加30%氧化钙的样品低12%,比添加30%白云石的样品低7%。利用糖厂废石灰提高机械性能,促进环境可持续性,在性能和生态效益方面都表现出令人信服的替代方案。
Sustainable construction solutions: The role of sugar factory lime waste-activated slag in high-performance concrete
This pioneering research aims to develop high-performance concrete (HPC) using waste lime from sugar factories to activate slag. The study explores the transformative effects of high-temperature treatment on sugar factory lime waste and its potential to enhance slag activation, representing a novel approach in sustainable construction materials. The newly formulated HPC was rigorously compared with traditional counterparts made from calcium oxide-activated slag and calcined dolomite. A comprehensive series of tests were conducted at 28 days, assessing critical performance metrics, including compressive strength, four-point bending strength, tensile strength, and water absorption. Microstructural analysis was performed using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDAX), and Fourier Transform Infrared Spectroscopy (FTIR). The results revealed that samples activated with 10 % sugar factory lime waste achieved a compressive strength of approximately 80 MPa, rivaling samples activated with 10 % calcium oxide. These lime-activated samples also demonstrated outstanding tensile and bending strengths of 5.6 MPa and 6.6 MPa, respectively—the highest recorded in this study. The microstructural analysis indicated a dense microstructure with an elevated Si/Al ratio and significant geopolymerization. The low water absorption rate of 2.1 % highlighted the reduced porosity of this innovative geopolymeric matrix. This research is the first to investigate the high-temperature treatment of sugar factory lime waste for slag activation in HPC. The findings suggest that incorporating 10 % waste lime significantly lowers the climate change impact index to 397.6 kg CO2 eq—12 % less than samples with 30 % calcium oxide and 7 % lower than those with 30 % dolomite. Using sugar factory waste lime enhances mechanical properties and promotes environmental sustainability, presenting a compelling alternative that excels in both performance and ecological benefits.
期刊介绍:
in Shams Engineering Journal is an international journal devoted to publication of peer reviewed original high-quality research papers and review papers in both traditional topics and those of emerging science and technology. Areas of both theoretical and fundamental interest as well as those concerning industrial applications, emerging instrumental techniques and those which have some practical application to an aspect of human endeavor, such as the preservation of the environment, health, waste disposal are welcome. The overall focus is on original and rigorous scientific research results which have generic significance.
Ain Shams Engineering Journal focuses upon aspects of mechanical engineering, electrical engineering, civil engineering, chemical engineering, petroleum engineering, environmental engineering, architectural and urban planning engineering. Papers in which knowledge from other disciplines is integrated with engineering are especially welcome like nanotechnology, material sciences, and computational methods as well as applied basic sciences: engineering mathematics, physics and chemistry.