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IF 3.3 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2025-02-14 DOI:10.1021/acs.joc.4c03015

Yufeng Zhang, Junqing Shi, Lei Ji

引用次数: 0

摘要

在此，我们报告了 B←N Lewis 对官能化过烯烃的两种近规异构体：中心对称 PBNPf1 和镜像对称 PBNPf2。镜像对称官能化能更有效地调整光电子特性。PBNPf1 和 PBNPf2 的 LUMO 能级分别稳定在 -3.00 eV 和 -3.30 eV。此外，PBNPf1 和 PBNPf2 的最大发射波长分别移至 574 纳米和 628 纳米，荧光量子产率分别高达 96% 和 87%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

B←N Lewis Pair-Functionalized Perylenes: Tuning Optoelectronic Properties via Regioisomerization.

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B←N Lewis Pair-Functionalized Perylenes: Tuning Optoelectronic Properties via Regioisomerization.

Herein, we report two peri-regioisomers of B←N Lewis pair-functionalized perylenes: the centrosymmetric PBNPf1 and the mirror-symmetric PBNPf2. Mirror-symmetric functionalization more effectively tunes the photoelectronic properties. The LUMO energy levels of PBNPf1 and PBNPf2 are stabilized to -3.00 eV and -3.30 eV. Additionally, the emission maxima of PBNPf1 and PBNPf2 are shifted to 574 and 628 nm, with fluorescence quantum yields of up to 96% and 87%, respectively.

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.