苯并唑型O2NO-I（III）化合物在苯酚和苯胺硝化中的应用

IF 3.6 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2025-01-31 DOI:10.1021/acs.joc.4c0273810.1021/acs.joc.4c02738

Yuli Sun, Haofeng Shi, Jiaxin He, Kaiyue Yang, Dongxue Yin, Dan Xiao and Yunfei Du*,

{"title":"苯并唑型O2NO-I（III）化合物在苯酚和苯胺硝化中的应用","authors":"Yuli Sun, Haofeng Shi, Jiaxin He, Kaiyue Yang, Dongxue Yin, Dan Xiao and Yunfei Du*, ","doi":"10.1021/acs.joc.4c0273810.1021/acs.joc.4c02738","DOIUrl":null,"url":null,"abstract":"A benziodazole-type O2NO-I(III) compound was used as a nitrating reagent to react with a series of electron-rich arenes including substituted phenols and anilines, affording the corresponding nitration products under mild conditions. Mechanistically, O2NO-I(III) compound generates the reactive nitrogen dioxide (NO2) species, which enables the nitration of phenols and anilines.","PeriodicalId":57,"journal":{"name":"Journal of Organic Chemistry","volume":"90 6","pages":"2328–2340 2328–2340"},"PeriodicalIF":3.6000,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Application of Benziodazole-Type O2NO-I(III) Compound as a Nitrating Reagent for Nitration of Phenols and Anilines\",\"authors\":\"Yuli Sun, Haofeng Shi, Jiaxin He, Kaiyue Yang, Dongxue Yin, Dan Xiao and Yunfei Du*, \",\"doi\":\"10.1021/acs.joc.4c0273810.1021/acs.joc.4c02738\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A benziodazole-type O2NO-I(III) compound was used as a nitrating reagent to react with a series of electron-rich arenes including substituted phenols and anilines, affording the corresponding nitration products under mild conditions. Mechanistically, O2NO-I(III) compound generates the reactive nitrogen dioxide (NO2) species, which enables the nitration of phenols and anilines.\",\"PeriodicalId\":57,\"journal\":{\"name\":\"Journal of Organic Chemistry\",\"volume\":\"90 6\",\"pages\":\"2328–2340 2328–2340\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-01-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Organic Chemistry\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.joc.4c02738\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Organic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.joc.4c02738","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}

引用次数: 0

摘要

以一种苯并唑型O2NO-I（III）化合物为硝化试剂，与取代酚类、苯胺类等一系列富电子芳烃反应，在温和条件下生成相应的硝化产物。从机理上讲，O2NO-I（III）化合物产生活性二氧化氮（NO2），使苯酚和苯胺的硝化作用成为可能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

The Application of Benziodazole-Type O2NO-I(III) Compound as a Nitrating Reagent for Nitration of Phenols and Anilines

查看原文本刊更多论文

The Application of Benziodazole-Type O2NO-I(III) Compound as a Nitrating Reagent for Nitration of Phenols and Anilines

A benziodazole-type O₂NO-I(III) compound was used as a nitrating reagent to react with a series of electron-rich arenes including substituted phenols and anilines, affording the corresponding nitration products under mild conditions. Mechanistically, O₂NO-I(III) compound generates the reactive nitrogen dioxide (NO₂) species, which enables the nitration of phenols and anilines.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.