{"title":"硅烷β-选择性自由基C(sp3) -H功能化方法","authors":"","doi":"10.1038/s44160-024-00675-6","DOIUrl":null,"url":null,"abstract":"Site-selective C–H bond functionalization of silanes is challenging because of the presence of multiple C–H bonds. Now, a photocatalytic method for the radical β-C(sp3)–H functionalization of silanes using the β-silicon effect is developed, enabling the aminoalkylation, alkylation and arylation of simple silanes to prepare more complex organosilicon compounds.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"4 2","pages":"152-153"},"PeriodicalIF":0.0000,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Method for the β-selective radical C(sp3)–H functionalization of silanes\",\"authors\":\"\",\"doi\":\"10.1038/s44160-024-00675-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Site-selective C–H bond functionalization of silanes is challenging because of the presence of multiple C–H bonds. Now, a photocatalytic method for the radical β-C(sp3)–H functionalization of silanes using the β-silicon effect is developed, enabling the aminoalkylation, alkylation and arylation of simple silanes to prepare more complex organosilicon compounds.\",\"PeriodicalId\":74251,\"journal\":{\"name\":\"Nature synthesis\",\"volume\":\"4 2\",\"pages\":\"152-153\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-10-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nature synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.nature.com/articles/s44160-024-00675-6\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"0\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature synthesis","FirstCategoryId":"1085","ListUrlMain":"https://www.nature.com/articles/s44160-024-00675-6","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"0","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Method for the β-selective radical C(sp3)–H functionalization of silanes
Site-selective C–H bond functionalization of silanes is challenging because of the presence of multiple C–H bonds. Now, a photocatalytic method for the radical β-C(sp3)–H functionalization of silanes using the β-silicon effect is developed, enabling the aminoalkylation, alkylation and arylation of simple silanes to prepare more complex organosilicon compounds.
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