防止CO2注水井盐沉淀和堵塞风险的策略:孔隙尺度实验见解

IF 5.3 3区 工程技术 Q2 ENERGY & FUELS
Di He*, Mincheng Zhang, Zhe Wang, Shuixuan Chen and Heping Yuan, 
{"title":"防止CO2注水井盐沉淀和堵塞风险的策略:孔隙尺度实验见解","authors":"Di He*,&nbsp;Mincheng Zhang,&nbsp;Zhe Wang,&nbsp;Shuixuan Chen and Heping Yuan,&nbsp;","doi":"10.1021/acs.energyfuels.4c0540410.1021/acs.energyfuels.4c05404","DOIUrl":null,"url":null,"abstract":"<p >In the CO<sub>2</sub> geological sequestration in saline aquifers, salt precipitation can lead to a decrease in reservoir permeability and porosity, severely impacting sequestration projects. While significant research has been conducted on the mechanisms of salt precipitation and remedial strategies of postprecipitation, there has been little focus on preventive strategies before salt precipitation occurs. This study designs pore-scale experiments to investigate the impact of preventive strategies on injectivity and proposes two prevention schemes: preinjection of water and CO<sub>2</sub> presaturated with water. The study found that preinjecting fresh water into the reservoir before injecting dry CO<sub>2</sub> can effectively dilute the in situ formation water and significantly reduce salt precipitation, thus maintaining good injectivity, particularly when there is almost no boundary solution in the reservoir. However, in conditions with an infinite boundary solution, as the replenishing solution continues to flow back to the inlet, the preinjection of water cannot prevent the formation of a wet salt barrier at the inlet, significantly damaging injectivity. For the CO<sub>2</sub> presaturated with water scheme, the study found that when low-temperature humidified CO<sub>2</sub> enters a high-temperature reservoir, the higher temperature increases the solubility of water vapor in CO<sub>2</sub>, causing the formation water to evaporate and precipitate salt. Thus, it cannot prevent the formation of a wet salt barrier in the inlet. However, when high-temperature humidified CO<sub>2</sub> enters a low-temperature reservoir, the temperature drop causes the water vapor in the CO<sub>2</sub> to become supersaturated and periodically condense into fresh water, continuously flushing and diluting the formation water. Consequently, no salt precipitates in the porous structure, and good injectivity is maintained. Therefore, under specific conditions, both the preinjection of fresh water into the reservoir and the CO<sub>2</sub> presaturated with water schemes can effectively prevent salt precipitation, significantly mitigating the adverse effects of salt precipitation on sequestration projects.</p>","PeriodicalId":35,"journal":{"name":"Energy & Fuels","volume":"39 6","pages":"3176–3187 3176–3187"},"PeriodicalIF":5.3000,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Strategies for Preventing Salt Precipitation and Blockage Risks in CO2 Injection Wells: Pore-Scale Experimental Insights\",\"authors\":\"Di He*,&nbsp;Mincheng Zhang,&nbsp;Zhe Wang,&nbsp;Shuixuan Chen and Heping Yuan,&nbsp;\",\"doi\":\"10.1021/acs.energyfuels.4c0540410.1021/acs.energyfuels.4c05404\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >In the CO<sub>2</sub> geological sequestration in saline aquifers, salt precipitation can lead to a decrease in reservoir permeability and porosity, severely impacting sequestration projects. While significant research has been conducted on the mechanisms of salt precipitation and remedial strategies of postprecipitation, there has been little focus on preventive strategies before salt precipitation occurs. This study designs pore-scale experiments to investigate the impact of preventive strategies on injectivity and proposes two prevention schemes: preinjection of water and CO<sub>2</sub> presaturated with water. The study found that preinjecting fresh water into the reservoir before injecting dry CO<sub>2</sub> can effectively dilute the in situ formation water and significantly reduce salt precipitation, thus maintaining good injectivity, particularly when there is almost no boundary solution in the reservoir. However, in conditions with an infinite boundary solution, as the replenishing solution continues to flow back to the inlet, the preinjection of water cannot prevent the formation of a wet salt barrier at the inlet, significantly damaging injectivity. For the CO<sub>2</sub> presaturated with water scheme, the study found that when low-temperature humidified CO<sub>2</sub> enters a high-temperature reservoir, the higher temperature increases the solubility of water vapor in CO<sub>2</sub>, causing the formation water to evaporate and precipitate salt. Thus, it cannot prevent the formation of a wet salt barrier in the inlet. However, when high-temperature humidified CO<sub>2</sub> enters a low-temperature reservoir, the temperature drop causes the water vapor in the CO<sub>2</sub> to become supersaturated and periodically condense into fresh water, continuously flushing and diluting the formation water. Consequently, no salt precipitates in the porous structure, and good injectivity is maintained. Therefore, under specific conditions, both the preinjection of fresh water into the reservoir and the CO<sub>2</sub> presaturated with water schemes can effectively prevent salt precipitation, significantly mitigating the adverse effects of salt precipitation on sequestration projects.</p>\",\"PeriodicalId\":35,\"journal\":{\"name\":\"Energy & Fuels\",\"volume\":\"39 6\",\"pages\":\"3176–3187 3176–3187\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2025-01-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Energy & Fuels\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.energyfuels.4c05404\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy & Fuels","FirstCategoryId":"5","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.energyfuels.4c05404","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0

摘要

在含盐含水层CO2地质封存中,盐降水会导致储层渗透率和孔隙度降低,严重影响封存工程。虽然对盐沉淀的机理和盐沉淀后的补救策略进行了大量的研究,但很少关注盐沉淀发生前的预防策略。本研究设计了孔隙尺度的实验来研究预防策略对注入能力的影响,并提出了两种预防方案:预注水和水饱和CO2。研究发现,在注入干CO2之前先向储层预注入淡水,可以有效稀释原位地层水,显著减少盐沉淀,保持良好的注入能力,特别是在储层几乎没有边界溶液的情况下。然而,在边界解为无穷大的情况下,随着补充溶液继续流回进口,预注水不能阻止进口处湿盐屏障的形成,严重损害了注入能力。对于CO2带水预饱和方案,研究发现,当低温加湿CO2进入高温储层时,较高的温度增加了水蒸气在CO2中的溶解度,导致地层水蒸发并析出盐。因此,它不能阻止入口形成湿盐屏障。然而,当高温加湿的CO2进入低温储层时,温度下降导致CO2中的水蒸气过饱和,周期性地凝结成淡水,不断冲刷和稀释地层水。因此,在多孔结构中没有盐沉淀,并保持了良好的注入性。因此,在特定条件下,水库预注淡水和CO2水预饱和方案均可有效防止盐沉淀,显著减轻盐沉淀对封存工程的不利影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Strategies for Preventing Salt Precipitation and Blockage Risks in CO2 Injection Wells: Pore-Scale Experimental Insights

Strategies for Preventing Salt Precipitation and Blockage Risks in CO2 Injection Wells: Pore-Scale Experimental Insights

In the CO2 geological sequestration in saline aquifers, salt precipitation can lead to a decrease in reservoir permeability and porosity, severely impacting sequestration projects. While significant research has been conducted on the mechanisms of salt precipitation and remedial strategies of postprecipitation, there has been little focus on preventive strategies before salt precipitation occurs. This study designs pore-scale experiments to investigate the impact of preventive strategies on injectivity and proposes two prevention schemes: preinjection of water and CO2 presaturated with water. The study found that preinjecting fresh water into the reservoir before injecting dry CO2 can effectively dilute the in situ formation water and significantly reduce salt precipitation, thus maintaining good injectivity, particularly when there is almost no boundary solution in the reservoir. However, in conditions with an infinite boundary solution, as the replenishing solution continues to flow back to the inlet, the preinjection of water cannot prevent the formation of a wet salt barrier at the inlet, significantly damaging injectivity. For the CO2 presaturated with water scheme, the study found that when low-temperature humidified CO2 enters a high-temperature reservoir, the higher temperature increases the solubility of water vapor in CO2, causing the formation water to evaporate and precipitate salt. Thus, it cannot prevent the formation of a wet salt barrier in the inlet. However, when high-temperature humidified CO2 enters a low-temperature reservoir, the temperature drop causes the water vapor in the CO2 to become supersaturated and periodically condense into fresh water, continuously flushing and diluting the formation water. Consequently, no salt precipitates in the porous structure, and good injectivity is maintained. Therefore, under specific conditions, both the preinjection of fresh water into the reservoir and the CO2 presaturated with water schemes can effectively prevent salt precipitation, significantly mitigating the adverse effects of salt precipitation on sequestration projects.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信