照亮铁类似物：铁（II）六碳蝎酸配合物的激发态动力学

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-02-12 DOI:10.1039/D5DT00139K

Catherine E. Johnson, Mawuli Deegbey, Aleksandra Ilic, Nidhi Kaul, Om Prakash, Kenneth Wärnmark, Elena Jakubikova and Reiner Lomoth

引用次数: 0

摘要

用实验和计算方法对咪唑-2-吡啶给体含三（卡宾）硼酸盐配合物进行了表征。尽管特殊的σ给体明显破坏了金属中心态的稳定性，但[Fe(II)(phtmeimb)2]的高能3MLCT态通过向3MC态的无障碍转化而迅速失活。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Shining light on the ferrous analogue: excited state dynamics of an Fe(ii) hexa-carbene scorpionate complex†

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Shining light on the ferrous analogue: excited state dynamics of an Fe(ii) hexa-carbene scorpionate complex†

A ferrous complex bearing tris(carbene)borate ligands with imidazol-2-ylidene donors has been characterized by experimental and computational methods. Despite the pronounced destabilization of metal centered states by the exceptionally σ-donating ligand, the high-energy ³MLCT state of [Fe(II)(phtmeimb)₂] is rapidly deactivated by the barrierless conversion to the ³MC state.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.