葫芦bbbb_uril包封能完全保护弱酸中的活性亚胺。

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2025-01-28 DOI:10.1039/d4ob01879f

Kejia Shi , Bradley D. Smith

引用次数: 0

摘要

由4-（N，N-二甲胺）苯甲醛和伯胺衍生的亚胺在弱酸中水解非常快，然而，它可以被封装在葫芦[7]uril （CB7）中，从而得到一个完全保护不稳定亚胺键的主/客体复合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cucurbit[7]uril encapsulation completely protects reactive imine in weak acid†

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Cucurbit[7]uril encapsulation completely protects reactive imine in weak acid†

An imine derived from 4-(N,N-dimethylamino)benzaldehyde and a primary amine undergoes very rapid hydrolysis in weak acid, however, it can be encapsulated within cucurbit[7]uril () to give a host/guest complex that completely protects the labile imine bond.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.