取代基对锑（III）配体中心电催化析氢的影响

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-02-11 DOI:10.1039/D4DT03178D

Qing-Hua Yu, Yu-Fei Li, Xu-You Cao, Liang-Hong Liu, Jun-Ying Chen, Li-Ping Si and Hai-Yang Liu

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引用次数: 0

摘要

合成了一系列含有不同数量中五氟苯基取代基的三芳基锑，并对其作为电催化析氢催化剂进行了评价。在corrole大环中引入吸电子的五氟苯基导致有机和水介质中电催化析氢反应（HER）活性的显著提高，突出了这些配合物对增强催化活性的可调性

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Substituent effect on the ligand-centred electrocatalytic hydrogen evolution of antimony(iii) corroles†

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Substituent effect on the ligand-centred electrocatalytic hydrogen evolution of antimony(iii) corroles†

A series of antimony(III) triaryl corroles bearing different numbers of meso-pentafluorophenyl substituents was synthesized and evaluated as catalysts for electrocatalytic hydrogen evolution. Introduction of the electron-withdrawing pentafluorophenyl group to the corrole macrocycle led to a significant boost in electro-catalytic hydrogen evolution reaction (HER) activity in organic and aqueous media, highlighting the tunability of these complexes for enhanced catalytic activity.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.