2,3-二氨基萘-1,4-二酮：分子体系合成的多功能前体

IF 1.8 3区化学 Q3 CHEMISTRY, ORGANIC

Synthetic Communications Pub Date : 2024-11-30 DOI:10.1080/00397911.2024.2435467

Sherif M. H. Sanad

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引用次数: 0

摘要

本文研究了2,3-二氨基萘-1,4-二酮在取代和环化1,4-萘醌生产中的反应性。2,3-二氨基萘-1,4-二酮有两个相邻的氨基功能，允许与各种亲电中心反应。它们被认为是一种有效的化学试剂，能够产生广泛的具有生物应用和良好电化学性能的杂环衍生物。本文综述了以2,3-二氨基萘-1,4-二酮与各种亲电试剂反应合成取代1,4-萘醌的文献。这篇综述包括了所有关于2,3-二氨基萘-1,4-二酮环化的报道，得到了带有单环、双环、三环和四环的杂环。这篇综述根据环状系统的类型和每个系统中杂原子的数量分为几个部分。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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2,3-Diaminonaphthalene-1,4-dione: Versatile precursor for the synthesis of molecular systems

The current review investigates the reactivity of 2,3-diaminonaphthalene-1,4-dione in the production of substituted and annulated 1,4-naphthoquinones. 2,3-Diaminonaphthalene-1,4-dione has two adjacent amino functions, allowing for reactions with a variety of electrophilic centers. They are regarded as effective chemical reagents capable of producing a wide range of heterocyclic derivatives with biological applications and favorable electrochemical properties. We reviewed all available papers on the synthesis of substituted 1,4-naphthoquinones via the reactions of 2,3-diaminonaphthalene-1,4-dione with various electrophiles. This review includes all reports in which 2,3-diaminonaphthalene-1,4-dione is annulated, yielding heterocycles with mono-, bi-, tri-, and tetracyclic rings. The review is divided into sections based on the type of annulation system and number of heteroatoms in each system.

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来源期刊

Synthetic Communications 化学-有机化学

CiteScore

4.40

自引率

4.80%

发文量

156

审稿时长

4.3 months

期刊介绍： Synthetic Communications presents communications describing new methods, reagents, and other synthetic work pertaining to organic chemistry with sufficient experimental detail to permit reported reactions to be repeated by a chemist reasonably skilled in the art. In addition, the Journal features short, focused review articles discussing topics within its remit of synthetic organic chemistry.