国际碳捕集与利用会议(ICCCU-24):实现可持续性和净零目标的平台

IF 18.2 1区 材料科学 Q1 CHEMISTRY, PHYSICAL
Sebastian C. Peter
{"title":"国际碳捕集与利用会议(ICCCU-24):实现可持续性和净零目标的平台","authors":"Sebastian C. Peter","doi":"10.1021/acsenergylett.5c00245","DOIUrl":null,"url":null,"abstract":"The International Conference on Carbon Capture and Utilization (ICCCU-24; https://www.icccu24.com), held from December 9–13, 2024, at the Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bengaluru, emerged as a pivotal platform for addressing CO<sub>2</sub> mitigation and advancing solutions toward sustainability. (1) This conference was organized by the National Centre for Carbon Capture and Utilization (NCCCU) at JNCASR, one of the first Centres of Excellence (CoE) on Carbon Capture and Utilization (CCU) in India with a generous support of Department of Science and Technology (DST). This conference was planned with an intend to expedite shifting to a low-carbon economy by exchanging best practices, emerging technologies, and successful case studies emphasizing pragmatic solutions and interdisciplinary collaboration. This conference aims to unite scientists, engineers, innovators, policymakers, stakeholders in CCU, and leaders in a cooperative effort to address the issues of CO<sub>2</sub> emissions and climate change, promoting practical solutions for a sustainable future. By fostering collaboration among academia, industry, and policymakers, the conference underscored the critical role of CCU in achieving India’s ambitious net-zero emissions target by 2070. The major themes of the conference were Carbon Capture and Carbon Utilization (Figure 1). The ICCCU-24 convenor, Sebastian C Peter (JNCASR), pointed out in the opening session that “<i>CCU is an important research activity as it can help reduce emissions and contribute to global decarbonization efforts. The cross-disciplinary training through the ICCCU-2024 will develop a deep understanding and problem-oriented approach in next-generation researchers working in different dimensions of CCU</i>”. Figure 1. Overall themes of ICCCU-24. The first approach focused on theoretical studies, providing a fundamental background for CCU chemistry. Biswarup Pathak (IIT Indore), Ali Haider (IIT Delhi), and Vidya Avasare (Ashoka University) extensively discussed their computational explorations of CO<sub>2</sub> behavior through various pathways. (2,3) Soujanya Yarasi (CSIR-IICT) highlighted how quantum mechanical (QM) methods integrated with AI/ML techniques can predict the adsorption and interaction behaviors of amine solvents and solid adsorbent materials, enabling the optimization of CO<sub>2</sub> capture processes. (4) Vikram Vishal (IIT Bombay) and Rajnish Kumar (IIT Madras) discussed strategies for mitigating risks in CO<sub>2</sub>-enhanced petroleum recovery and gas hydrates for capture and sequestration, respectively. (5,6) K. V. Agrawal (EPFL) explored membrane-based CO<sub>2</sub> capture, focusing on unit-cell-thick MOF membranes precisely tuned with Å-scale pore sizes. (7) These membranes enable a highly scalable and uniform CO<sub>2</sub> capture process. Raju Kumar Gupta (IIT Kanpur) emphasized the importance of solid sorbents, particularly nanostructured solid adsorbents for CO<sub>2</sub> capture. (8) His research aims to develop low-cost, low-temperature adsorbents, reducing energy and cost requirements. Additionally, he highlighted CO<sub>2</sub> conversion using Bismuth oxyhalide (BiOX) materials. Ranga Rao (IIT Madras) presented an innovative approach to CO<sub>2</sub> capture using waste biomass materials, such as coco-peat and chitosan, as sustainable sources for synthesizing activated porous carbons. (9) Coco-peat-derived carbon demonstrated CO<sub>2</sub> adsorption of up to 4.8 mmol g<sup>–1</sup> at 25 °C and 1 bar. He also discussed ultramicroporous carbons derived from chitosan hydrogels, which enable effective CO<sub>2</sub> capture and catalytic conversion using materials like Cu<sub>2</sub>O films, mixed phases of BaTiO<sub>3</sub>/BaTi<sub>5</sub>O<sub>11</sub>, and POM-based systems. (10) C.M. Nagaraja (IIT Ropar) highlighted the strategic design, synthesis, and catalytic performance of CO<sub>2</sub>-philic framework materials. These materials integrate catalytic sites for efficient carbon capture and conversion directly from the air. (11) By facilitating simultaneous CO<sub>2</sub> fixation into high-value chemicals under mild conditions, these smart materials offer sustainable and practical solutions for carbon management and utilization. Carbon utilization was classified into three categories: electrochemical, thermochemical and photochemical. A more sustainable electro-synthetic route for graphitic carbon nitride quantum dots (g-C<sub>3</sub>N<sub>4</sub> QDs) with size-tuned properties for enhanced electrochemical activity was proposed by Vijayamohanan K. Pillai (IISER Tirupati). (12) Addressing cathodic flooding, a major issue in electrochemical CO<sub>2</sub> reduction (eCO<sub>2</sub>RR), Brian Seger (Technical University of Denmark) introduced a unique approach to study this phenomenon using synchrotron-based small-angle and wide-angle X-ray scattering and X-ray fluorescence techniques. He also highlighted the advantages of CO electroreduction for enhanced stability and the use of Ni anodes, which avoid anodic corrosion of IrO<sub>2</sub> anodes and their deposition on the cathode, ultimately boosting hydrogen generation. (13,14) Peter Strasser (TU Berlin) discussed the challenges of direct air or flue gas CO<sub>2</sub> capture, emphasizing its necessity for atmospheric CO<sub>2</sub> reduction. He presented the electrochemically mediated amine regeneration (EMAR) technique to capture CO<sub>2</sub> via complexation and release it with proper mechanistic insights gained through operando mass spectrometry. (15) Prashanth W. Menezes (TU Berlin and Helmholtz-Zentrum Berlin) elaborated on the efficient design of catalysts and the tailored development of (pre)catalysts that dictate the formation of active catalysts under reaction conditions. He also explored strategies to reduce the overall full-cell potential of eCO<sub>2</sub>RR, replacing the oxygen evolution reaction (OER) at the anode with organic oxidation reactions (OOR). (16) Abhishek Dey (IACS) addressed the challenges posed by proton and oxygen reductions leading to hydrogen evolution reaction (HER) and oxygen reduction reaction (ORR), which significantly diminish eCO<sub>2</sub>RR. He presented exploratory research on iron porphyrin bioinspired artificial mimics for highly selective eCO<sub>2</sub>RR, explaining how spin states, hydrogen bonding, and heterogenization influence the rate and selectivity of CO<sub>2</sub>RR products such as CO, HCOOH, CH<sub>3</sub>OH, CH<sub>4</sub>, or C<sub>2</sub>H<sub>4</sub>. (17) Praveen Kumar (IACS) proposed an innovative approach to reduce HER and enhance CO<sub>2</sub> availability near the electrode surface by coating Bi 2D flakes with organic polyaniline (PANI). The amine groups in PANI attract acidic CO<sub>2</sub> molecules, reducing overpotential and improving the faradaic efficiency for formate production. (18) Chinmoy Ranjan (IISc Bangalore) introduced the use of solid oxide electrodes in eCO<sub>2</sub>RR, elucidating their science through in situ Raman spectroscopy and in situ mass spectrometry techniques. (19) Pravin P. Ingole (IIT Delhi) discussed the exclusive design of nanocatalysts for efficient CO<sub>2</sub> capture and electro-reduction, along with probing the photoelectrochemical photocurrent polarity switching effect by tuning electrochemical interfaces. (20) These groundbreaking contributions highlight the multidisciplinary efforts to tackle challenges in CO<sub>2</sub> capture and utilization through advanced theoretical, experimental, and material design approaches. The photoconversion of CO<sub>2</sub> is a promising green approach for CO<sub>2</sub> mitigation. However, challenges related to efficiency and the limited availability of suitable materials were key topics addressed during the conference. Arnab Dutta (IIT Bombay) discussed an Mn-based molecular photocatalyst, [Mn(apap)<sub>2</sub>Br<sub>2</sub>], designed with a bulky multifunctional ligand to achieve efficient and selective CO<sub>2</sub> reduction under visible light. (21) Tapas Kumar Maji (JNCASR) highlighted MOF-based systems with tuned electronic and optical properties for delivering C2 products. (22) Ujjal Gautam and Tokeer Ahmed (Jamia Millia Islamia) presented strategies for designing advanced catalytic systems for decarbonization and CO<sub>2</sub> conversion, including MBenes, TMPs, MOFs, POPs, particularly COFs, and oxide-based heterostructured nanocatalysts. (23,24) Prashant V. Kamat (University of Notre Dame) addressed the unresolved chemistry and challenges of photochemical and electrochemical methods. He discussed the next-generation fabrication of photoelectrodes for designing more efficient photoelectrochemical devices, offering promising advancements in CO<sub>2</sub> photoconversion technologies. (25,26) Thermocatalytic CO<sub>2</sub> utilization is one of the most explored approaches; however, it is hindered by high energy demands due to the need for elevated temperatures and pressures, as well as the requirement for hydrogen. Kamal Kishore Pant (IIT Roorkee) presented his extensive research on thermochemical CO<sub>2</sub> hydrogenation to produce syngas, sustainable aviation fuel (SAF), and bio-oil, including methodologies designed for low-temperature and ambient conditions. (27) Majd Al-Naji (BasCat, TU Berlin) introduced biorefinery processes utilizing the cellulosic fraction and lignin. (28) Sudhanshu Sharma (IIT Gandhinagar) discussed methane production from CO<sub>2</sub> using geopolymer-supported Ru nanoparticles. (29) Subarna Maiti (CSIR-CSMCRI) highlighted the successful utilization of toxic agro-residues from cotton farming, unsuitable as fodder, for CO<sub>2</sub> applications. (30) Manirul Islam (Kalyani University) showcased nearly 99% selectivity in forming cyclic carbonates via cycloaddition of CO<sub>2</sub> with epoxides. (31,32) Joyanta Choudhury (IISER Bhopal) explored the hydride-transfer mechanism for CO<sub>2</sub> hydrogenation to fuels in depth, (33) while Abhijit Shrotri (Hokkaido University) emphasized the role of O-vacancy dynamics in oxides for CO<sub>2</sub> activation and selective methanol production. (34) Komal Tripathi (IIT Roorkee) provided insights into the challenges of CO<sub>2</sub> reduction to value-added products using experimental and theoretical (AI/ML) tools. Addressing the issue of metal dependency in catalysis, Swadhin Mandal (IISER Kolkata) presented affordable metal-free catalysts to achieve exceptional S-formylation of thiols using CO<sub>2</sub>. (35) The adoption of CCU technologies in any country is intrinsically tied to public and governmental policies. The conference emphasized this critical aspect by including discussions from experts on policy frameworks and strategic implementations. Ajay Phatak (Ecological Society and Terre Policy Centre) provided a comprehensive overview of CCU in the context of industrial decarbonization, highlighting policy-driven opportunities and the nexus between renewable energy, hydrogen, and CCU. Swaminathan Sivaram (INSA Senior Scientist, IISER Pune) stressed the urgency of CCUS for India to achieve net-zero emissions by 2070. He underscored the need for low-carbon strategies, energy-efficient CO<sub>2</sub> mitigation methods, and innovative life-cycle assessments. R. R. Sonde (Professor Emeritus, BITS Group of Institutions) advocated for prioritizing renewable energy and energy efficiency in technological advancements. He projected that India would need Carbon Capture, Utilization and Storage (CCUS) technologies capable of handling 1500 million tons of CO<sub>2</sub> annually by 2030 and removing approximately 80000 million tons of CO<sub>2</sub> from the atmosphere by 2070 for carbon dioxide removal (CDR). Sukumar Devotta (Anna University) emphasized integrating green hydrogen from water electrolysis with CO<sub>2</sub> hydrogenation for enhanced sustainability. (36) Neelima Alam (CEST, DST) highlighted her extensive involvement in fostering global best practices through bilateral and multilateral collaborations, leveraging platforms such as Mission Innovation (MI) 1.0, Accelerating CCUS Technologies (ACT), CDR Mission MI 2.0, and the Clean Energy Transition Partnership (CETP). These insights underscore the importance of robust policy frameworks and international collaboration in advancing CCU technologies to combat climate change effectively. The event featured a panel discussion on CCU, moderated by Kannan Srinivasan (Director, CSIR-Central Salt and Marine Research Institute, Bhavnagar), which brought together experts to assess the current status, challenges, and future potential of CCU technologies in India. This engaging dialogue underscored CCU as a cornerstone of India’s climate strategy, emphasizing its pivotal role in reducing emissions and fostering sustainability. The conference also served as a platform for technology transfer and collaboration. V. K. Saraswat (Member, NITI Aayog) inaugurated the commissioning of a 500 kg/day CO<sub>2</sub>-to-methanol plant at the Singareni Thermal Power Plant in Telangana, funded by CMPDI/CIL. This groundbreaking technology, developed by JNCASR and commissioned by Breathe, a JNCASR spin-off, represents a significant milestone in CCU innovation. Two collaborative projects were also inaugurated: CO<sub>2</sub>-to-ethanol and ethylene, developed jointly by JNCASR and HPCL. CO<sub>2</sub>-to-syngas, a collaboration between JNCASR and Tata Steel. Further, a memorandum of understanding was signed between Breathe, Mitocn, and Sadguru Sugars for the development of a 20 TPD CO<sub>2</sub>-to-methanol plant. V. K. Saraswat emphasized the importance of raising awareness about CCU technologies and fostering robust partnerships between academic institutions and industries. By accelerating innovation and collaboration, he highlighted the transformative potential of CCU in addressing climate challenges effectively and advancing India’s sustainability goals. ICCCU-24 showcased the power of collective action in addressing one of the most urgent global challenges─climate change. It highlighted how international cooperation, fueled by shared objectives, can drive meaningful advancements. The conference not only propelled CCU technologies forward but also reinforced the global commitment to combating climate change through innovation, collaboration, and shared responsibility. As the world strives for a sustainable future, ICCCU-24 stands as a beacon of how academic and industrial engagements can inspire real-world solutions, paving the way for a greener planet. The event successfully bridged the gap between seasoned experts and emerging researchers, fostering a dynamic ecosystem for advancing sustainability goals. During the closing session, it was announced that ICCCU-25 will be held from December 7–12, 2025, at the same location. The upcoming event aims to attract an even larger global audience from academia and industry, building on the success of its predecessor. ICCCU-25 will continue to strengthen international networks in CCU research and applications, focusing on driving sustainability and achieving Net Zero objectives. Financial support from the Department of Science and Technology (DST) (Grant Number: DST/TMDEWO/CCUS/CoE/2020/JNCASR(C)), is acknowledged. S.C.P. thanks DST for the Swarna Jayanti Fellowship (Grant DST/SJF/CSA-02/2017-18) Sheikh Saud Laboratory for Career Fellowship. The organizers of the event thank various sponsors including DST, Anusandhan National Research Foundation (ANRF), Tata Steel, Trilok Corporation, Partek, Texol Engineering, American Chemical Society, Royal Society of Chemistry, Breathe Applied Sciences, Spirare Energy, Mitcon, AdiChem technology and Smart Labtek. This article references 36 other publications. This article has not yet been cited by other publications.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"21 1","pages":""},"PeriodicalIF":18.2000,"publicationDate":"2025-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"International Conference on Carbon Capture and Utilization (ICCCU-24): A Platform to Sustainability and Net-Zero Goals\",\"authors\":\"Sebastian C. Peter\",\"doi\":\"10.1021/acsenergylett.5c00245\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The International Conference on Carbon Capture and Utilization (ICCCU-24; https://www.icccu24.com), held from December 9–13, 2024, at the Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bengaluru, emerged as a pivotal platform for addressing CO<sub>2</sub> mitigation and advancing solutions toward sustainability. (1) This conference was organized by the National Centre for Carbon Capture and Utilization (NCCCU) at JNCASR, one of the first Centres of Excellence (CoE) on Carbon Capture and Utilization (CCU) in India with a generous support of Department of Science and Technology (DST). This conference was planned with an intend to expedite shifting to a low-carbon economy by exchanging best practices, emerging technologies, and successful case studies emphasizing pragmatic solutions and interdisciplinary collaboration. This conference aims to unite scientists, engineers, innovators, policymakers, stakeholders in CCU, and leaders in a cooperative effort to address the issues of CO<sub>2</sub> emissions and climate change, promoting practical solutions for a sustainable future. By fostering collaboration among academia, industry, and policymakers, the conference underscored the critical role of CCU in achieving India’s ambitious net-zero emissions target by 2070. The major themes of the conference were Carbon Capture and Carbon Utilization (Figure 1). The ICCCU-24 convenor, Sebastian C Peter (JNCASR), pointed out in the opening session that “<i>CCU is an important research activity as it can help reduce emissions and contribute to global decarbonization efforts. The cross-disciplinary training through the ICCCU-2024 will develop a deep understanding and problem-oriented approach in next-generation researchers working in different dimensions of CCU</i>”. Figure 1. Overall themes of ICCCU-24. The first approach focused on theoretical studies, providing a fundamental background for CCU chemistry. Biswarup Pathak (IIT Indore), Ali Haider (IIT Delhi), and Vidya Avasare (Ashoka University) extensively discussed their computational explorations of CO<sub>2</sub> behavior through various pathways. (2,3) Soujanya Yarasi (CSIR-IICT) highlighted how quantum mechanical (QM) methods integrated with AI/ML techniques can predict the adsorption and interaction behaviors of amine solvents and solid adsorbent materials, enabling the optimization of CO<sub>2</sub> capture processes. (4) Vikram Vishal (IIT Bombay) and Rajnish Kumar (IIT Madras) discussed strategies for mitigating risks in CO<sub>2</sub>-enhanced petroleum recovery and gas hydrates for capture and sequestration, respectively. (5,6) K. V. Agrawal (EPFL) explored membrane-based CO<sub>2</sub> capture, focusing on unit-cell-thick MOF membranes precisely tuned with Å-scale pore sizes. (7) These membranes enable a highly scalable and uniform CO<sub>2</sub> capture process. Raju Kumar Gupta (IIT Kanpur) emphasized the importance of solid sorbents, particularly nanostructured solid adsorbents for CO<sub>2</sub> capture. (8) His research aims to develop low-cost, low-temperature adsorbents, reducing energy and cost requirements. Additionally, he highlighted CO<sub>2</sub> conversion using Bismuth oxyhalide (BiOX) materials. Ranga Rao (IIT Madras) presented an innovative approach to CO<sub>2</sub> capture using waste biomass materials, such as coco-peat and chitosan, as sustainable sources for synthesizing activated porous carbons. (9) Coco-peat-derived carbon demonstrated CO<sub>2</sub> adsorption of up to 4.8 mmol g<sup>–1</sup> at 25 °C and 1 bar. He also discussed ultramicroporous carbons derived from chitosan hydrogels, which enable effective CO<sub>2</sub> capture and catalytic conversion using materials like Cu<sub>2</sub>O films, mixed phases of BaTiO<sub>3</sub>/BaTi<sub>5</sub>O<sub>11</sub>, and POM-based systems. (10) C.M. Nagaraja (IIT Ropar) highlighted the strategic design, synthesis, and catalytic performance of CO<sub>2</sub>-philic framework materials. These materials integrate catalytic sites for efficient carbon capture and conversion directly from the air. (11) By facilitating simultaneous CO<sub>2</sub> fixation into high-value chemicals under mild conditions, these smart materials offer sustainable and practical solutions for carbon management and utilization. Carbon utilization was classified into three categories: electrochemical, thermochemical and photochemical. A more sustainable electro-synthetic route for graphitic carbon nitride quantum dots (g-C<sub>3</sub>N<sub>4</sub> QDs) with size-tuned properties for enhanced electrochemical activity was proposed by Vijayamohanan K. Pillai (IISER Tirupati). (12) Addressing cathodic flooding, a major issue in electrochemical CO<sub>2</sub> reduction (eCO<sub>2</sub>RR), Brian Seger (Technical University of Denmark) introduced a unique approach to study this phenomenon using synchrotron-based small-angle and wide-angle X-ray scattering and X-ray fluorescence techniques. He also highlighted the advantages of CO electroreduction for enhanced stability and the use of Ni anodes, which avoid anodic corrosion of IrO<sub>2</sub> anodes and their deposition on the cathode, ultimately boosting hydrogen generation. (13,14) Peter Strasser (TU Berlin) discussed the challenges of direct air or flue gas CO<sub>2</sub> capture, emphasizing its necessity for atmospheric CO<sub>2</sub> reduction. He presented the electrochemically mediated amine regeneration (EMAR) technique to capture CO<sub>2</sub> via complexation and release it with proper mechanistic insights gained through operando mass spectrometry. (15) Prashanth W. Menezes (TU Berlin and Helmholtz-Zentrum Berlin) elaborated on the efficient design of catalysts and the tailored development of (pre)catalysts that dictate the formation of active catalysts under reaction conditions. He also explored strategies to reduce the overall full-cell potential of eCO<sub>2</sub>RR, replacing the oxygen evolution reaction (OER) at the anode with organic oxidation reactions (OOR). (16) Abhishek Dey (IACS) addressed the challenges posed by proton and oxygen reductions leading to hydrogen evolution reaction (HER) and oxygen reduction reaction (ORR), which significantly diminish eCO<sub>2</sub>RR. He presented exploratory research on iron porphyrin bioinspired artificial mimics for highly selective eCO<sub>2</sub>RR, explaining how spin states, hydrogen bonding, and heterogenization influence the rate and selectivity of CO<sub>2</sub>RR products such as CO, HCOOH, CH<sub>3</sub>OH, CH<sub>4</sub>, or C<sub>2</sub>H<sub>4</sub>. (17) Praveen Kumar (IACS) proposed an innovative approach to reduce HER and enhance CO<sub>2</sub> availability near the electrode surface by coating Bi 2D flakes with organic polyaniline (PANI). The amine groups in PANI attract acidic CO<sub>2</sub> molecules, reducing overpotential and improving the faradaic efficiency for formate production. (18) Chinmoy Ranjan (IISc Bangalore) introduced the use of solid oxide electrodes in eCO<sub>2</sub>RR, elucidating their science through in situ Raman spectroscopy and in situ mass spectrometry techniques. (19) Pravin P. Ingole (IIT Delhi) discussed the exclusive design of nanocatalysts for efficient CO<sub>2</sub> capture and electro-reduction, along with probing the photoelectrochemical photocurrent polarity switching effect by tuning electrochemical interfaces. (20) These groundbreaking contributions highlight the multidisciplinary efforts to tackle challenges in CO<sub>2</sub> capture and utilization through advanced theoretical, experimental, and material design approaches. The photoconversion of CO<sub>2</sub> is a promising green approach for CO<sub>2</sub> mitigation. However, challenges related to efficiency and the limited availability of suitable materials were key topics addressed during the conference. Arnab Dutta (IIT Bombay) discussed an Mn-based molecular photocatalyst, [Mn(apap)<sub>2</sub>Br<sub>2</sub>], designed with a bulky multifunctional ligand to achieve efficient and selective CO<sub>2</sub> reduction under visible light. (21) Tapas Kumar Maji (JNCASR) highlighted MOF-based systems with tuned electronic and optical properties for delivering C2 products. (22) Ujjal Gautam and Tokeer Ahmed (Jamia Millia Islamia) presented strategies for designing advanced catalytic systems for decarbonization and CO<sub>2</sub> conversion, including MBenes, TMPs, MOFs, POPs, particularly COFs, and oxide-based heterostructured nanocatalysts. (23,24) Prashant V. Kamat (University of Notre Dame) addressed the unresolved chemistry and challenges of photochemical and electrochemical methods. He discussed the next-generation fabrication of photoelectrodes for designing more efficient photoelectrochemical devices, offering promising advancements in CO<sub>2</sub> photoconversion technologies. (25,26) Thermocatalytic CO<sub>2</sub> utilization is one of the most explored approaches; however, it is hindered by high energy demands due to the need for elevated temperatures and pressures, as well as the requirement for hydrogen. Kamal Kishore Pant (IIT Roorkee) presented his extensive research on thermochemical CO<sub>2</sub> hydrogenation to produce syngas, sustainable aviation fuel (SAF), and bio-oil, including methodologies designed for low-temperature and ambient conditions. (27) Majd Al-Naji (BasCat, TU Berlin) introduced biorefinery processes utilizing the cellulosic fraction and lignin. (28) Sudhanshu Sharma (IIT Gandhinagar) discussed methane production from CO<sub>2</sub> using geopolymer-supported Ru nanoparticles. (29) Subarna Maiti (CSIR-CSMCRI) highlighted the successful utilization of toxic agro-residues from cotton farming, unsuitable as fodder, for CO<sub>2</sub> applications. (30) Manirul Islam (Kalyani University) showcased nearly 99% selectivity in forming cyclic carbonates via cycloaddition of CO<sub>2</sub> with epoxides. (31,32) Joyanta Choudhury (IISER Bhopal) explored the hydride-transfer mechanism for CO<sub>2</sub> hydrogenation to fuels in depth, (33) while Abhijit Shrotri (Hokkaido University) emphasized the role of O-vacancy dynamics in oxides for CO<sub>2</sub> activation and selective methanol production. (34) Komal Tripathi (IIT Roorkee) provided insights into the challenges of CO<sub>2</sub> reduction to value-added products using experimental and theoretical (AI/ML) tools. Addressing the issue of metal dependency in catalysis, Swadhin Mandal (IISER Kolkata) presented affordable metal-free catalysts to achieve exceptional S-formylation of thiols using CO<sub>2</sub>. (35) The adoption of CCU technologies in any country is intrinsically tied to public and governmental policies. The conference emphasized this critical aspect by including discussions from experts on policy frameworks and strategic implementations. Ajay Phatak (Ecological Society and Terre Policy Centre) provided a comprehensive overview of CCU in the context of industrial decarbonization, highlighting policy-driven opportunities and the nexus between renewable energy, hydrogen, and CCU. Swaminathan Sivaram (INSA Senior Scientist, IISER Pune) stressed the urgency of CCUS for India to achieve net-zero emissions by 2070. He underscored the need for low-carbon strategies, energy-efficient CO<sub>2</sub> mitigation methods, and innovative life-cycle assessments. R. R. Sonde (Professor Emeritus, BITS Group of Institutions) advocated for prioritizing renewable energy and energy efficiency in technological advancements. He projected that India would need Carbon Capture, Utilization and Storage (CCUS) technologies capable of handling 1500 million tons of CO<sub>2</sub> annually by 2030 and removing approximately 80000 million tons of CO<sub>2</sub> from the atmosphere by 2070 for carbon dioxide removal (CDR). Sukumar Devotta (Anna University) emphasized integrating green hydrogen from water electrolysis with CO<sub>2</sub> hydrogenation for enhanced sustainability. (36) Neelima Alam (CEST, DST) highlighted her extensive involvement in fostering global best practices through bilateral and multilateral collaborations, leveraging platforms such as Mission Innovation (MI) 1.0, Accelerating CCUS Technologies (ACT), CDR Mission MI 2.0, and the Clean Energy Transition Partnership (CETP). These insights underscore the importance of robust policy frameworks and international collaboration in advancing CCU technologies to combat climate change effectively. The event featured a panel discussion on CCU, moderated by Kannan Srinivasan (Director, CSIR-Central Salt and Marine Research Institute, Bhavnagar), which brought together experts to assess the current status, challenges, and future potential of CCU technologies in India. This engaging dialogue underscored CCU as a cornerstone of India’s climate strategy, emphasizing its pivotal role in reducing emissions and fostering sustainability. The conference also served as a platform for technology transfer and collaboration. V. K. Saraswat (Member, NITI Aayog) inaugurated the commissioning of a 500 kg/day CO<sub>2</sub>-to-methanol plant at the Singareni Thermal Power Plant in Telangana, funded by CMPDI/CIL. This groundbreaking technology, developed by JNCASR and commissioned by Breathe, a JNCASR spin-off, represents a significant milestone in CCU innovation. Two collaborative projects were also inaugurated: CO<sub>2</sub>-to-ethanol and ethylene, developed jointly by JNCASR and HPCL. CO<sub>2</sub>-to-syngas, a collaboration between JNCASR and Tata Steel. Further, a memorandum of understanding was signed between Breathe, Mitocn, and Sadguru Sugars for the development of a 20 TPD CO<sub>2</sub>-to-methanol plant. V. K. Saraswat emphasized the importance of raising awareness about CCU technologies and fostering robust partnerships between academic institutions and industries. By accelerating innovation and collaboration, he highlighted the transformative potential of CCU in addressing climate challenges effectively and advancing India’s sustainability goals. ICCCU-24 showcased the power of collective action in addressing one of the most urgent global challenges─climate change. It highlighted how international cooperation, fueled by shared objectives, can drive meaningful advancements. The conference not only propelled CCU technologies forward but also reinforced the global commitment to combating climate change through innovation, collaboration, and shared responsibility. As the world strives for a sustainable future, ICCCU-24 stands as a beacon of how academic and industrial engagements can inspire real-world solutions, paving the way for a greener planet. The event successfully bridged the gap between seasoned experts and emerging researchers, fostering a dynamic ecosystem for advancing sustainability goals. During the closing session, it was announced that ICCCU-25 will be held from December 7–12, 2025, at the same location. The upcoming event aims to attract an even larger global audience from academia and industry, building on the success of its predecessor. ICCCU-25 will continue to strengthen international networks in CCU research and applications, focusing on driving sustainability and achieving Net Zero objectives. Financial support from the Department of Science and Technology (DST) (Grant Number: DST/TMDEWO/CCUS/CoE/2020/JNCASR(C)), is acknowledged. S.C.P. thanks DST for the Swarna Jayanti Fellowship (Grant DST/SJF/CSA-02/2017-18) Sheikh Saud Laboratory for Career Fellowship. The organizers of the event thank various sponsors including DST, Anusandhan National Research Foundation (ANRF), Tata Steel, Trilok Corporation, Partek, Texol Engineering, American Chemical Society, Royal Society of Chemistry, Breathe Applied Sciences, Spirare Energy, Mitcon, AdiChem technology and Smart Labtek. This article references 36 other publications. 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摘要

国际碳捕获和利用会议(ICCCU-24);https://www.icccu24.com),于2024年12月9日至13日在班加罗尔贾瓦哈拉尔·尼赫鲁高级科学研究中心(JNCASR)举行,成为解决二氧化碳减排和推进可持续发展解决方案的关键平台。(1)本次会议由JNCASR的国家碳捕集与利用中心(NCCCU)组织,该中心是印度首批碳捕集与利用卓越中心(CoE)之一,得到了科技部(DST)的慷慨支持。本次会议旨在通过交流最佳实践、新兴技术和强调务实解决方案和跨学科合作的成功案例,加快向低碳经济转型。本次会议旨在联合科学家、工程师、创新者、政策制定者、CCU的利益相关者和领导者,共同努力解决二氧化碳排放和气候变化问题,为可持续发展的未来提供切实可行的解决方案。通过促进学术界、工业界和政策制定者之间的合作,会议强调了CCU在实现印度2070年雄心勃勃的净零排放目标方面的关键作用。会议的主要主题是碳捕获和碳利用(图1)。ICCCU-24召集人Sebastian C Peter (JNCASR)在开幕式上指出:“CCU是一项重要的研究活动,因为它可以帮助减少排放并为全球脱碳工作做出贡献。通过ICCCU-2024进行的跨学科培训将为下一代研究人员在CCU的不同维度上工作提供深刻的理解和问题导向的方法”。图1所示。第24届工委会会议的总主题。第一种方法侧重于理论研究,为CCU化学提供基础背景。Biswarup Pathak(印度理工学院)、Ali Haider(印度理工学院德里分校)和Vidya Avasare(阿肖卡大学)广泛讨论了他们通过各种途径对二氧化碳行为的计算探索。(2,3) Soujanya Yarasi (CSIR-IICT)强调了量子力学(QM)方法与AI/ML技术的结合如何预测胺类溶剂和固体吸附材料的吸附和相互作用行为,从而优化CO2捕获过程。(4) Vikram Vishal(印度理工学院孟买分校)和Rajnish Kumar(印度理工学院马德拉斯分校)分别讨论了降低二氧化碳增强石油采收率和天然气水合物捕获和封存风险的策略。(5,6) K. V. Agrawal (EPFL)研究了基于膜的二氧化碳捕获,重点是单位细胞厚度的MOF膜,通过Å-scale孔径精确调节。这些膜实现了高度可扩展和均匀的二氧化碳捕获过程。Raju Kumar Gupta(印度理工学院坎普尔)强调了固体吸附剂,特别是纳米结构固体吸附剂对二氧化碳捕获的重要性。他的研究目标是开发低成本、低温吸附剂,降低能源和成本要求。此外,他还强调了使用氧化卤化铋(BiOX)材料进行二氧化碳转化。Ranga Rao(印度理工学院马德拉斯分校)提出了一种利用废弃生物质材料(如可可豆和壳聚糖)作为合成活性多孔碳的可持续来源来捕获二氧化碳的创新方法。(9)在25°C和1 bar条件下,可可泥炭衍生碳对CO2的吸附量高达4.8 mmol g-1。他还讨论了从壳聚糖水凝胶中提取的超微孔碳,它可以有效地捕获二氧化碳,并使用Cu2O薄膜、BaTiO3/BaTi5O11混合相和pom基系统等材料进行催化转化。(10) C.M. Nagaraja (IIT Ropar)强调了亲二氧化碳框架材料的战略设计、合成和催化性能。这些材料整合了催化位点,可以直接从空气中有效地捕获和转化碳。(11)通过在温和条件下促进二氧化碳同时固定为高价值化学品,这些智能材料为碳管理和利用提供了可持续和实用的解决方案。碳的利用分为电化学、热化学和光化学三大类。Vijayamohanan K. Pillai (IISER Tirupati)提出了一种更具可持续性的电合成路线,用于具有尺寸调谐特性的石墨氮化碳量子点(g-C3N4 QDs),以增强电化学活性。(12)为了解决电化学CO2还原(eCO2RR)中的主要问题阴极泛洪,Brian Seger(丹麦技术大学)介绍了一种独特的方法,使用基于同步加速器的小角度和广角x射线散射和x射线荧光技术来研究这一现象。他还强调了CO电还原在提高稳定性和使用Ni阳极方面的优势,这避免了IrO2阳极的阳极腐蚀及其在阴极上的沉积,最终促进了氢气的生成。 (13,14) Peter Strasser(柏林工业大学)讨论了直接空气或烟气CO2捕集的挑战,强调了其减少大气CO2的必要性。他介绍了电化学介导的胺再生(EMAR)技术,该技术通过络合作用捕获二氧化碳,并通过operando质谱法获得适当的机制见解。(15) Prashanth W. Menezes(柏林工业大学和Helmholtz-Zentrum Berlin)详细阐述了催化剂的有效设计和(预)催化剂的定制开发,这些催化剂决定了在反应条件下活性催化剂的形成。他还探索了降低eCO2RR整体全细胞电位的策略,用有机氧化反应(OOR)取代阳极的析氧反应(OER)。(16) Abhishek Dey (IACS)解决了质子和氧还原导致的析氢反应(HER)和氧还原反应(ORR)所带来的挑战,这些反应会显著降低eCO2RR。他介绍了高选择性eCO2RR的铁卟啉生物仿生人工模拟物的探索性研究,解释了自旋态、氢键和异质化如何影响CO、HCOOH、CH3OH、CH4或C2H4等CO2RR产物的速率和选择性。(17) Praveen Kumar (IACS)提出了一种创新的方法,通过在bi2d薄片上涂覆有机聚苯胺(PANI)来降低HER并提高电极表面附近的CO2可用性。聚苯胺中的胺基吸引酸性CO2分子,降低过电位,提高甲酸酯生产的法拉第效率。(18) Chinmoy Ranjan (IISc Bangalore)介绍了eCO2RR中固体氧化物电极的使用,并通过原位拉曼光谱和原位质谱技术阐明了它们的科学原理。(19) Pravin P. Ingole(印度理工学院德里分校)讨论了纳米催化剂的独家设计,用于有效的二氧化碳捕获和电还原,以及通过调整电化学界面来探测光电电流极性开关效应。(20)这些突破性的贡献突出了通过先进的理论、实验和材料设计方法解决二氧化碳捕获和利用挑战的多学科努力。二氧化碳的光转化是一种很有前途的减少二氧化碳排放的绿色方法。然而,与效率有关的挑战和适当材料的有限供应是会议期间讨论的关键议题。Arnab Dutta(印度理工学院孟买分校)讨论了一种锰基分子光催化剂[Mn(apap)2Br2],该催化剂设计了一个体积庞大的多功能配体,可以在可见光下实现高效和选择性的二氧化碳还原。(21) Tapas Kumar Maji (JNCASR)强调了基于mof的系统,该系统具有可调谐的电子和光学特性,可用于交付C2产品。(22) Ujjal Gautam和Tokeer Ahmed (Jamia Millia Islamia)提出了设计用于脱碳和二氧化碳转化的先进催化系统的策略,包括MBenes, tps, mof, POPs,特别是COFs和基于氧化物的异质结构纳米催化剂。(23,24) Prashant V. Kamat(圣母大学)阐述了光化学和电化学方法尚未解决的化学和挑战。他讨论了下一代光电极的制造,以设计更高效的光电化学器件,为CO2光转换技术提供了有前途的进展。(25,26)热催化CO2利用是探索最多的方法之一;然而,由于需要升高的温度和压力以及对氢气的需求,它受到高能量需求的阻碍。Kamal Kishore Pant (IIT Roorkee)介绍了他在热化学CO2加氢生产合成气、可持续航空燃料(SAF)和生物油方面的广泛研究,包括为低温和环境条件设计的方法。(27) Majd Al-Naji (BasCat, TU Berlin)介绍了利用纤维素馏分和木质素的生物炼制工艺。(28) Sudhanshu Sharma(印度理工学院甘地纳加尔分校)讨论了利用地聚合物负载的Ru纳米颗粒从二氧化碳中产生甲烷。(29) Subarna Maiti (CSIR-CSMCRI)强调成功利用棉花种植中不适合作为饲料的有毒农业残留物用于二氧化碳应用。(30) Kalyani大学的Manirul Islam展示了CO2与环氧化物环加成生成环状碳酸盐的选择性接近99%。(31,32) Joyanta Choudhury (IISER Bhopal)深入探索了二氧化碳加氢到燃料的氢化物转移机制,(33)而Abhijit Shrotri(北海道大学)强调了o空位动力学在二氧化碳活化和选择性甲醇生产中的作用。(34) Komal Tripathi (IIT Roorkee)利用实验和理论(AI/ML)工具,对二氧化碳减排对增值产品的挑战提出了见解。 为了解决催化中金属依赖性的问题,Swadhin Mandal (IISER Kolkata)提出了价格合理的无金属催化剂,可以使用二氧化碳实现硫醇的s -甲酰化。(35)在任何国家采用CCU技术都与公共和政府政策有着内在的联系。会议通过邀请专家就政策框架和战略实施进行讨论,强调了这一关键方面。Ajay Phatak(生态学会和土地政策中心)在工业脱碳的背景下提供了CCU的全面概述,强调了政策驱动的机会以及可再生能源,氢气和CCU之间的联系。Swaminathan Sivaram(印度国家科学研究院高级科学家,IISER Pune)强调了CCUS对印度到2070年实现净零排放的紧迫性。他强调需要低碳战略、节能的二氧化碳缓解方法和创新的生命周期评估。R. R. Sonde (BITS集团机构荣誉教授)主张在技术进步中优先考虑可再生能源和能源效率。他预计,到2030年,印度将需要能够每年处理15亿吨二氧化碳的碳捕集、利用和封存(CCUS)技术,到2070年,从大气中去除大约80亿吨二氧化碳,用于二氧化碳去除(CDR)。安娜大学的Sukumar Devotta强调将水电解产生的绿色氢与二氧化碳加氢相结合,以增强可持续性。(36) Neelima Alam (CEST, DST)强调了她通过双边和多边合作,利用诸如创新使命(MI) 1.0、加速CCUS技术(ACT)、CDR使命MI 2.0和清洁能源转型伙伴关系(CETP)等平台,广泛参与促进全球最佳实践。这些见解强调了强有力的政策框架和国际合作在推进CCU技术以有效应对气候变化方面的重要性。该活动的特色是由Kannan Srinivasan (csir - Bhavnagar中央盐和海洋研究所所长)主持的CCU小组讨论,专家们齐聚一堂,评估了CCU技术在印度的现状、挑战和未来潜力。这一引人入胜的对话强调了CCU作为印度气候战略的基石,强调了其在减少排放和促进可持续发展方面的关键作用。会议还为技术转让和合作提供了一个平台。V. K. Saraswat (NITI Aayog成员)在由CMPDI/CIL资助的泰伦加纳邦Singareni热电厂启动了500公斤/天的二氧化碳制甲醇工厂。这项突破性技术由JNCASR开发,并由JNCASR的衍生公司Breathe委托,是CCU创新的一个重要里程碑。两个合作项目也启动了:由JNCASR和HPCL联合开发的二氧化碳制乙醇和乙烯。二氧化碳制合成气是JNCASR和塔塔钢铁公司的合作项目。此外,Breathe、Mitocn和Sadguru Sugars还签署了一份谅解备忘录,以开发一个20 TPD的二氧化碳制甲醇工厂。V. K. Saraswat强调了提高对CCU技术的认识以及在学术机构和行业之间培养强有力的伙伴关系的重要性。通过加速创新和合作,他强调了CCU在有效应对气候挑战和推进印度可持续发展目标方面的变革潜力。ICCCU-24展示了集体行动在应对最紧迫的全球挑战之一──气候变化──方面的力量。它强调了在共同目标的推动下,国际合作如何能够推动有意义的进展。会议不仅推动了CCU技术的发展,而且加强了通过创新,合作和分担责任来应对气候变化的全球承诺。随着世界为可持续发展的未来而奋斗,ICCCU-24成为学术和工业合作如何激发现实世界解决方案的灯塔,为更绿色的地球铺平道路。该活动成功地弥合了经验丰富的专家和新兴研究人员之间的差距,为推进可持续发展目标培育了一个充满活力的生态系统。在闭幕会议期间,宣布将于2025年12月7日至12日在同一地点举行第25届工商联会议。即将到来的活动旨在吸引来自学术界和工业界的更多全球观众,以上届的成功为基础。ICCCU-25将继续加强CCU研究和应用的国际网络,重点是推动可持续性和实现净零目标。感谢科技部(DST)的财政支持(资助号:DST/TMDEWO/CCUS/CoE/2020/JNCASR(C))。S.C.P. 感谢DST提供Swarna Jayanti奖学金(授予DST/SJF/CSA-02/2017-18)谢赫沙特实验室职业奖学金。此次活动的组织者感谢各种赞助商,包括DST、Anusandhan国家研究基金会(ANRF)、塔塔钢铁、Trilok公司、Partek、Texol工程、美国化学学会、皇家化学学会、Breathe应用科学、Spirare能源、Mitcon、AdiChem技术和Smart Labtek。本文引用了36个其他出版物。这篇文章尚未被其他出版物引用。
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International Conference on Carbon Capture and Utilization (ICCCU-24): A Platform to Sustainability and Net-Zero Goals

International Conference on Carbon Capture and Utilization (ICCCU-24): A Platform to Sustainability and Net-Zero Goals
The International Conference on Carbon Capture and Utilization (ICCCU-24; https://www.icccu24.com), held from December 9–13, 2024, at the Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bengaluru, emerged as a pivotal platform for addressing CO2 mitigation and advancing solutions toward sustainability. (1) This conference was organized by the National Centre for Carbon Capture and Utilization (NCCCU) at JNCASR, one of the first Centres of Excellence (CoE) on Carbon Capture and Utilization (CCU) in India with a generous support of Department of Science and Technology (DST). This conference was planned with an intend to expedite shifting to a low-carbon economy by exchanging best practices, emerging technologies, and successful case studies emphasizing pragmatic solutions and interdisciplinary collaboration. This conference aims to unite scientists, engineers, innovators, policymakers, stakeholders in CCU, and leaders in a cooperative effort to address the issues of CO2 emissions and climate change, promoting practical solutions for a sustainable future. By fostering collaboration among academia, industry, and policymakers, the conference underscored the critical role of CCU in achieving India’s ambitious net-zero emissions target by 2070. The major themes of the conference were Carbon Capture and Carbon Utilization (Figure 1). The ICCCU-24 convenor, Sebastian C Peter (JNCASR), pointed out in the opening session that “CCU is an important research activity as it can help reduce emissions and contribute to global decarbonization efforts. The cross-disciplinary training through the ICCCU-2024 will develop a deep understanding and problem-oriented approach in next-generation researchers working in different dimensions of CCU”. Figure 1. Overall themes of ICCCU-24. The first approach focused on theoretical studies, providing a fundamental background for CCU chemistry. Biswarup Pathak (IIT Indore), Ali Haider (IIT Delhi), and Vidya Avasare (Ashoka University) extensively discussed their computational explorations of CO2 behavior through various pathways. (2,3) Soujanya Yarasi (CSIR-IICT) highlighted how quantum mechanical (QM) methods integrated with AI/ML techniques can predict the adsorption and interaction behaviors of amine solvents and solid adsorbent materials, enabling the optimization of CO2 capture processes. (4) Vikram Vishal (IIT Bombay) and Rajnish Kumar (IIT Madras) discussed strategies for mitigating risks in CO2-enhanced petroleum recovery and gas hydrates for capture and sequestration, respectively. (5,6) K. V. Agrawal (EPFL) explored membrane-based CO2 capture, focusing on unit-cell-thick MOF membranes precisely tuned with Å-scale pore sizes. (7) These membranes enable a highly scalable and uniform CO2 capture process. Raju Kumar Gupta (IIT Kanpur) emphasized the importance of solid sorbents, particularly nanostructured solid adsorbents for CO2 capture. (8) His research aims to develop low-cost, low-temperature adsorbents, reducing energy and cost requirements. Additionally, he highlighted CO2 conversion using Bismuth oxyhalide (BiOX) materials. Ranga Rao (IIT Madras) presented an innovative approach to CO2 capture using waste biomass materials, such as coco-peat and chitosan, as sustainable sources for synthesizing activated porous carbons. (9) Coco-peat-derived carbon demonstrated CO2 adsorption of up to 4.8 mmol g–1 at 25 °C and 1 bar. He also discussed ultramicroporous carbons derived from chitosan hydrogels, which enable effective CO2 capture and catalytic conversion using materials like Cu2O films, mixed phases of BaTiO3/BaTi5O11, and POM-based systems. (10) C.M. Nagaraja (IIT Ropar) highlighted the strategic design, synthesis, and catalytic performance of CO2-philic framework materials. These materials integrate catalytic sites for efficient carbon capture and conversion directly from the air. (11) By facilitating simultaneous CO2 fixation into high-value chemicals under mild conditions, these smart materials offer sustainable and practical solutions for carbon management and utilization. Carbon utilization was classified into three categories: electrochemical, thermochemical and photochemical. A more sustainable electro-synthetic route for graphitic carbon nitride quantum dots (g-C3N4 QDs) with size-tuned properties for enhanced electrochemical activity was proposed by Vijayamohanan K. Pillai (IISER Tirupati). (12) Addressing cathodic flooding, a major issue in electrochemical CO2 reduction (eCO2RR), Brian Seger (Technical University of Denmark) introduced a unique approach to study this phenomenon using synchrotron-based small-angle and wide-angle X-ray scattering and X-ray fluorescence techniques. He also highlighted the advantages of CO electroreduction for enhanced stability and the use of Ni anodes, which avoid anodic corrosion of IrO2 anodes and their deposition on the cathode, ultimately boosting hydrogen generation. (13,14) Peter Strasser (TU Berlin) discussed the challenges of direct air or flue gas CO2 capture, emphasizing its necessity for atmospheric CO2 reduction. He presented the electrochemically mediated amine regeneration (EMAR) technique to capture CO2 via complexation and release it with proper mechanistic insights gained through operando mass spectrometry. (15) Prashanth W. Menezes (TU Berlin and Helmholtz-Zentrum Berlin) elaborated on the efficient design of catalysts and the tailored development of (pre)catalysts that dictate the formation of active catalysts under reaction conditions. He also explored strategies to reduce the overall full-cell potential of eCO2RR, replacing the oxygen evolution reaction (OER) at the anode with organic oxidation reactions (OOR). (16) Abhishek Dey (IACS) addressed the challenges posed by proton and oxygen reductions leading to hydrogen evolution reaction (HER) and oxygen reduction reaction (ORR), which significantly diminish eCO2RR. He presented exploratory research on iron porphyrin bioinspired artificial mimics for highly selective eCO2RR, explaining how spin states, hydrogen bonding, and heterogenization influence the rate and selectivity of CO2RR products such as CO, HCOOH, CH3OH, CH4, or C2H4. (17) Praveen Kumar (IACS) proposed an innovative approach to reduce HER and enhance CO2 availability near the electrode surface by coating Bi 2D flakes with organic polyaniline (PANI). The amine groups in PANI attract acidic CO2 molecules, reducing overpotential and improving the faradaic efficiency for formate production. (18) Chinmoy Ranjan (IISc Bangalore) introduced the use of solid oxide electrodes in eCO2RR, elucidating their science through in situ Raman spectroscopy and in situ mass spectrometry techniques. (19) Pravin P. Ingole (IIT Delhi) discussed the exclusive design of nanocatalysts for efficient CO2 capture and electro-reduction, along with probing the photoelectrochemical photocurrent polarity switching effect by tuning electrochemical interfaces. (20) These groundbreaking contributions highlight the multidisciplinary efforts to tackle challenges in CO2 capture and utilization through advanced theoretical, experimental, and material design approaches. The photoconversion of CO2 is a promising green approach for CO2 mitigation. However, challenges related to efficiency and the limited availability of suitable materials were key topics addressed during the conference. Arnab Dutta (IIT Bombay) discussed an Mn-based molecular photocatalyst, [Mn(apap)2Br2], designed with a bulky multifunctional ligand to achieve efficient and selective CO2 reduction under visible light. (21) Tapas Kumar Maji (JNCASR) highlighted MOF-based systems with tuned electronic and optical properties for delivering C2 products. (22) Ujjal Gautam and Tokeer Ahmed (Jamia Millia Islamia) presented strategies for designing advanced catalytic systems for decarbonization and CO2 conversion, including MBenes, TMPs, MOFs, POPs, particularly COFs, and oxide-based heterostructured nanocatalysts. (23,24) Prashant V. Kamat (University of Notre Dame) addressed the unresolved chemistry and challenges of photochemical and electrochemical methods. He discussed the next-generation fabrication of photoelectrodes for designing more efficient photoelectrochemical devices, offering promising advancements in CO2 photoconversion technologies. (25,26) Thermocatalytic CO2 utilization is one of the most explored approaches; however, it is hindered by high energy demands due to the need for elevated temperatures and pressures, as well as the requirement for hydrogen. Kamal Kishore Pant (IIT Roorkee) presented his extensive research on thermochemical CO2 hydrogenation to produce syngas, sustainable aviation fuel (SAF), and bio-oil, including methodologies designed for low-temperature and ambient conditions. (27) Majd Al-Naji (BasCat, TU Berlin) introduced biorefinery processes utilizing the cellulosic fraction and lignin. (28) Sudhanshu Sharma (IIT Gandhinagar) discussed methane production from CO2 using geopolymer-supported Ru nanoparticles. (29) Subarna Maiti (CSIR-CSMCRI) highlighted the successful utilization of toxic agro-residues from cotton farming, unsuitable as fodder, for CO2 applications. (30) Manirul Islam (Kalyani University) showcased nearly 99% selectivity in forming cyclic carbonates via cycloaddition of CO2 with epoxides. (31,32) Joyanta Choudhury (IISER Bhopal) explored the hydride-transfer mechanism for CO2 hydrogenation to fuels in depth, (33) while Abhijit Shrotri (Hokkaido University) emphasized the role of O-vacancy dynamics in oxides for CO2 activation and selective methanol production. (34) Komal Tripathi (IIT Roorkee) provided insights into the challenges of CO2 reduction to value-added products using experimental and theoretical (AI/ML) tools. Addressing the issue of metal dependency in catalysis, Swadhin Mandal (IISER Kolkata) presented affordable metal-free catalysts to achieve exceptional S-formylation of thiols using CO2. (35) The adoption of CCU technologies in any country is intrinsically tied to public and governmental policies. The conference emphasized this critical aspect by including discussions from experts on policy frameworks and strategic implementations. Ajay Phatak (Ecological Society and Terre Policy Centre) provided a comprehensive overview of CCU in the context of industrial decarbonization, highlighting policy-driven opportunities and the nexus between renewable energy, hydrogen, and CCU. Swaminathan Sivaram (INSA Senior Scientist, IISER Pune) stressed the urgency of CCUS for India to achieve net-zero emissions by 2070. He underscored the need for low-carbon strategies, energy-efficient CO2 mitigation methods, and innovative life-cycle assessments. R. R. Sonde (Professor Emeritus, BITS Group of Institutions) advocated for prioritizing renewable energy and energy efficiency in technological advancements. He projected that India would need Carbon Capture, Utilization and Storage (CCUS) technologies capable of handling 1500 million tons of CO2 annually by 2030 and removing approximately 80000 million tons of CO2 from the atmosphere by 2070 for carbon dioxide removal (CDR). Sukumar Devotta (Anna University) emphasized integrating green hydrogen from water electrolysis with CO2 hydrogenation for enhanced sustainability. (36) Neelima Alam (CEST, DST) highlighted her extensive involvement in fostering global best practices through bilateral and multilateral collaborations, leveraging platforms such as Mission Innovation (MI) 1.0, Accelerating CCUS Technologies (ACT), CDR Mission MI 2.0, and the Clean Energy Transition Partnership (CETP). These insights underscore the importance of robust policy frameworks and international collaboration in advancing CCU technologies to combat climate change effectively. The event featured a panel discussion on CCU, moderated by Kannan Srinivasan (Director, CSIR-Central Salt and Marine Research Institute, Bhavnagar), which brought together experts to assess the current status, challenges, and future potential of CCU technologies in India. This engaging dialogue underscored CCU as a cornerstone of India’s climate strategy, emphasizing its pivotal role in reducing emissions and fostering sustainability. The conference also served as a platform for technology transfer and collaboration. V. K. Saraswat (Member, NITI Aayog) inaugurated the commissioning of a 500 kg/day CO2-to-methanol plant at the Singareni Thermal Power Plant in Telangana, funded by CMPDI/CIL. This groundbreaking technology, developed by JNCASR and commissioned by Breathe, a JNCASR spin-off, represents a significant milestone in CCU innovation. Two collaborative projects were also inaugurated: CO2-to-ethanol and ethylene, developed jointly by JNCASR and HPCL. CO2-to-syngas, a collaboration between JNCASR and Tata Steel. Further, a memorandum of understanding was signed between Breathe, Mitocn, and Sadguru Sugars for the development of a 20 TPD CO2-to-methanol plant. V. K. Saraswat emphasized the importance of raising awareness about CCU technologies and fostering robust partnerships between academic institutions and industries. By accelerating innovation and collaboration, he highlighted the transformative potential of CCU in addressing climate challenges effectively and advancing India’s sustainability goals. ICCCU-24 showcased the power of collective action in addressing one of the most urgent global challenges─climate change. It highlighted how international cooperation, fueled by shared objectives, can drive meaningful advancements. The conference not only propelled CCU technologies forward but also reinforced the global commitment to combating climate change through innovation, collaboration, and shared responsibility. As the world strives for a sustainable future, ICCCU-24 stands as a beacon of how academic and industrial engagements can inspire real-world solutions, paving the way for a greener planet. The event successfully bridged the gap between seasoned experts and emerging researchers, fostering a dynamic ecosystem for advancing sustainability goals. During the closing session, it was announced that ICCCU-25 will be held from December 7–12, 2025, at the same location. The upcoming event aims to attract an even larger global audience from academia and industry, building on the success of its predecessor. ICCCU-25 will continue to strengthen international networks in CCU research and applications, focusing on driving sustainability and achieving Net Zero objectives. Financial support from the Department of Science and Technology (DST) (Grant Number: DST/TMDEWO/CCUS/CoE/2020/JNCASR(C)), is acknowledged. S.C.P. thanks DST for the Swarna Jayanti Fellowship (Grant DST/SJF/CSA-02/2017-18) Sheikh Saud Laboratory for Career Fellowship. The organizers of the event thank various sponsors including DST, Anusandhan National Research Foundation (ANRF), Tata Steel, Trilok Corporation, Partek, Texol Engineering, American Chemical Society, Royal Society of Chemistry, Breathe Applied Sciences, Spirare Energy, Mitcon, AdiChem technology and Smart Labtek. This article references 36 other publications. This article has not yet been cited by other publications.
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来源期刊
ACS Energy Letters
ACS Energy Letters Energy-Renewable Energy, Sustainability and the Environment
CiteScore
31.20
自引率
5.00%
发文量
469
审稿时长
1 months
期刊介绍: ACS Energy Letters is a monthly journal that publishes papers reporting new scientific advances in energy research. The journal focuses on topics that are of interest to scientists working in the fundamental and applied sciences. Rapid publication is a central criterion for acceptance, and the journal is known for its quick publication times, with an average of 4-6 weeks from submission to web publication in As Soon As Publishable format. ACS Energy Letters is ranked as the number one journal in the Web of Science Electrochemistry category. It also ranks within the top 10 journals for Physical Chemistry, Energy & Fuels, and Nanoscience & Nanotechnology. The journal offers several types of articles, including Letters, Energy Express, Perspectives, Reviews, Editorials, Viewpoints and Energy Focus. Additionally, authors have the option to submit videos that summarize or support the information presented in a Perspective or Review article, which can be highlighted on the journal's website. ACS Energy Letters is abstracted and indexed in Chemical Abstracts Service/SciFinder, EBSCO-summon, PubMed, Web of Science, Scopus and Portico.
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