富马酸铜和琥珀酸铜-单乙醇胺水溶性配合物的合成与结构

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2025-02-09 DOI:10.1134/S1070328424600785

B. I. Petrov, V. V. Semenov, N. M. Lazarev, E. V. Baranov, M. A. Lopatin

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引用次数: 0

摘要

用碳酸羟基铜与丁二酸或富马酸在50℃水溶液中非均相反应制备了新的水溶性二羧酸铜配合物。在配合物中额外引入单乙醇胺（MEA）保证了琥珀酸铜和富马酸盐的高溶解度。用x射线衍射（CCDC号分别为2352578和2352579）研究了配合物[Cu（Suc）·2MEA]·H2O和[Cu（fu）·2MEA]·H2O的结构。这些化合物被发现具有由之字形链组成的聚合物结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis and Structure of Water-Soluble Complexes of Copper Fumarate and Succinate with Monoethanolamine

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Synthesis and Structure of Water-Soluble Complexes of Copper Fumarate and Succinate with Monoethanolamine

New water-soluble copper(II) complexes with dicarboxylic acids were obtained by the heterogeneous reaction of copper hydroxy carbonate with succinic or fumaric acid in water at 50°C. The additional introduction of monoethanolamine (MEA) into the complexes ensured high solubility of copper succinate and fumarate. The structures of the complexes [Cu(Suc)·2MEA]·H₂O and [Cu(Fum)·2MEA]·H₂O were studied by X-ray diffraction (CCDC nos. 2352578 and 2352579, respectively). The compounds were found to have a polymeric structure composed of zigzag chains.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.