前言：β-和γ-环环酮的全合成

IF 16.9 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Angewandte Chemie International Edition Pub Date : 2025-02-05 DOI:10.1002/anie.202580662

Prof. Dr. Yoshio Ando, Taiju Hoshino, Nozomi Tanaka, Dr. Mark M. Maturi, Yusuke Nakazawa, Dr. Takumi Fukazawa, Prof. Dr. Ken Ohmori, Prof. Dr. Keisuke Suzuki

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引用次数: 0

摘要

据Yoshio Ando等人在他们的通讯（e202415108）中报道，经过半个世纪的分离，β-和γ-萘环clinone （pyranonaphtho醌异二聚体）的首次全合成已经完成。这些天然红色色素是由在喀麦隆一个火山口收集的土壤细菌产生的。这张照片展示了火山，它们的家园，以及利用铑（Rh）和硫(S)构建双环结构的关键反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Frontispiece: Total Syntheses of β- and γ-Naphthocyclinones

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Frontispiece: Total Syntheses of β- and γ-Naphthocyclinones

After half a century from their isolation, the first total syntheses of β- and γ-naphthocyclinones, the pyranonaphthoquinone hetero-dimers, have been accomplished, as reported by Yoshio Ando et al. in their Communication (e202415108). These natural red pigments are produced by soil bacteria collected at a volcano crater in Cameroon. This image illustrates a volcano, their home ground, and the key reactions for constructing the bicyclic structure by employing rhodium (Rh) and sulfur (S).

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来源期刊

Angewandte Chemie International Edition 化学-化学综合

CiteScore

26.60

自引率

6.60%

发文量

3549

审稿时长

1.5 months

期刊介绍： Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.