{"title":"基于响应面法优化的低成本活性炭基三元复合材料及其电化学性能","authors":"Vikas Kumar Pandey , Sanjeev Verma , Bhawna Verma","doi":"10.1016/j.synthmet.2025.117844","DOIUrl":null,"url":null,"abstract":"<div><div>Nowadays, energy storage technologies have attracted much interest because there is a massive demand for electronic gadgets, electric automobiles, and automotive applications. Supercapacitors are gaining prominence as electrochemical energy storage applications because of their exceptional properties like fast charging, high power density, and outstanding cyclic stability. They are designed to fill the performance barrier between traditional capacitors and conventional batteries. This paper reports detailed optimization studies for low-cost ternary composite materials for supercapacitive applications with the help of Response Surface Methodology (RSM). The optimum composition was 4:1.03:2.66 (polyaniline: activated carbon: cobalt ferrite) for best electrochemical performance. The specific capacitance of the optimized composite material was 687.9 F/g. The optimized ternary composite material also demonstrated the 47.5 Wh/kg highest energy density and extraordinarily high capacitance retention of 76.1 % after completing 5000 cycles.</div></div>","PeriodicalId":22245,"journal":{"name":"Synthetic Metals","volume":"311 ","pages":"Article 117844"},"PeriodicalIF":4.0000,"publicationDate":"2025-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Response Surface Methodology optimization approach to architect low-cost activated carbon-based ternary composite for supercapacitor application with enhanced electrochemical performance\",\"authors\":\"Vikas Kumar Pandey , Sanjeev Verma , Bhawna Verma\",\"doi\":\"10.1016/j.synthmet.2025.117844\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Nowadays, energy storage technologies have attracted much interest because there is a massive demand for electronic gadgets, electric automobiles, and automotive applications. Supercapacitors are gaining prominence as electrochemical energy storage applications because of their exceptional properties like fast charging, high power density, and outstanding cyclic stability. They are designed to fill the performance barrier between traditional capacitors and conventional batteries. This paper reports detailed optimization studies for low-cost ternary composite materials for supercapacitive applications with the help of Response Surface Methodology (RSM). The optimum composition was 4:1.03:2.66 (polyaniline: activated carbon: cobalt ferrite) for best electrochemical performance. The specific capacitance of the optimized composite material was 687.9 F/g. The optimized ternary composite material also demonstrated the 47.5 Wh/kg highest energy density and extraordinarily high capacitance retention of 76.1 % after completing 5000 cycles.</div></div>\",\"PeriodicalId\":22245,\"journal\":{\"name\":\"Synthetic Metals\",\"volume\":\"311 \",\"pages\":\"Article 117844\"},\"PeriodicalIF\":4.0000,\"publicationDate\":\"2025-01-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthetic Metals\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0379677925000207\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthetic Metals","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0379677925000207","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
A Response Surface Methodology optimization approach to architect low-cost activated carbon-based ternary composite for supercapacitor application with enhanced electrochemical performance
Nowadays, energy storage technologies have attracted much interest because there is a massive demand for electronic gadgets, electric automobiles, and automotive applications. Supercapacitors are gaining prominence as electrochemical energy storage applications because of their exceptional properties like fast charging, high power density, and outstanding cyclic stability. They are designed to fill the performance barrier between traditional capacitors and conventional batteries. This paper reports detailed optimization studies for low-cost ternary composite materials for supercapacitive applications with the help of Response Surface Methodology (RSM). The optimum composition was 4:1.03:2.66 (polyaniline: activated carbon: cobalt ferrite) for best electrochemical performance. The specific capacitance of the optimized composite material was 687.9 F/g. The optimized ternary composite material also demonstrated the 47.5 Wh/kg highest energy density and extraordinarily high capacitance retention of 76.1 % after completing 5000 cycles.
期刊介绍:
This journal is an international medium for the rapid publication of original research papers, short communications and subject reviews dealing with research on and applications of electronic polymers and electronic molecular materials including novel carbon architectures. These functional materials have the properties of metals, semiconductors or magnets and are distinguishable from elemental and alloy/binary metals, semiconductors and magnets.