寿命终止固体氧化物电池陶瓷组件材料的可扩展回收和表征

Gudaysew Tsegaye Yenesew, Clément Nicollet, Eric Quarez, Annie Le Gal La Salle, Olivier Joubert
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引用次数: 0

摘要

通过回收固体氧化物电池(soc)的报废材料,可以减少对环境的影响,材料的闭环生命周期可以帮助保护自然资源,创造一个可持续的循环系统。本研究提出了一种从SOC报废产品中回收NiO, LaxSr1-xCoO3 (LSC)和Zr1-xYxO2-x/2 (YSZ)组件的技术。首先,整个电池组件,包括电解液、燃料和空气电极被粉碎、球磨和用硝酸浸出。在阳离子最大溶解后,离心除去未浸出的YSZ作为沉积物。用二甲基乙肟(C4H8N2O2 DMG)处理富含镍、钴、锶和镧离子的浸出液,Ni优先沉淀为C8H14N4NiO4。对C8H14N4NiO4离心过滤后的废液进行热处理,回收LSC。约90% wt%的陶瓷成分被成功回收。回收材料的组成显示出商业级的纯度,即NiO约为99 at%, LSC为96 at%, YSZ为97 at%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Scalable recycling and characterization of end-of-life solid oxide cell ceramic component materials
By recycling solid oxide cells (SOCs) end-life materials, the environmental impact can be reduced, and the materials' closed-loop life cycle can help preserve natural resources and create a sustainable and circular system. This study presents a technique for recovering NiO, LaxSr1-xCoO3 (LSC) and Zr1-xYxO2-x/2 (YSZ) components from SOC end-of-life products. First, the entire cell components, including the electrolyte, fuel and air electrodes were crushed, ball-milled, and leached with nitric acid. Following the maximum dissolution of cations, centrifugation was used to remove the non-leached YSZ as a sediment. The leached solution, which is rich in nickel, cobalt, strontium, and lanthanum ions was treated with dimethylglyoxime (C4H8N2O2 DMG) and Ni is preferentially precipitated as C8H14N4NiO4. LSC is then recovered from thermal treatment of solution leftover from C8H14N4NiO4 centrifugation and filtration. About 90 wt% of the ceramic components were successfully recovered. The compositions of recovered materials show a commercial-grade purity i.e about 99 at% for NiO, 96 at% for LSC and 97 at% for YSZ.
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