利用来自蔗渣废料的环保陶瓷膜处理含油废水:利用响应面法进行优化

Nurhayati Jamalludin , Mohd Riduan Jamalludin , Siti Khadijah Hubadillah , Mohd Hafiz Dzarfan Othman , Mohd Azizi Hakim Jamalludin
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摘要

采用环保、低成本的分离技术处理含油废水是一项具有挑战性的工作。本文以甘蔗渣为原料,采用溶胶-凝胶法对其进行改性,成功制备了超亲水-超亲油绿色陶瓷中空纤维膜。随后,本研究旨在利用响应面法(RSM)的中心复合设计(CCD)优化绿色陶瓷膜油废水分离的废水行为(pH、浓度和温度)。分析了油pH值(3-11)、油浓度(10-10000 ppm)、油温(30-100℃)及其综合作用的三个有效参数,获得了高的油通量和优异的油分离效率。通过考察发现,pH、油浓度和温度的最佳值分别为10、10.01 ppm和69.04℃。研究结果表明,油温对合成膜的分离性能有显著影响。拟合模型的R2 = 0.954, R2 = 0.986,与实际油通量和分离效率吻合较好。在优化条件下,油通量和分离效率的平均误差分别为4.71%和0.746%,与预测值和实际值基本一致。本研究的新颖之处在于开发了一种从蔗渣中提取的环保陶瓷膜,为含油废水的处理提供了一种创新和可持续的解决方案。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Oily-wastewater treatment using eco-friendly ceramic membranes derived from sugarcane bagasse waste: Optimization using response surface methodology
Treating oily-wastewater through separation technologies with advanced properties such as environmental-friendly and low cost is a challenging work. Herein, we successfully fabricated superhydrophic-superoleophilic green ceramic hollow fibre membrane prepared from sugarcane bagasse waste and modified through sol-gel method. Later, this study aims to optimize wastewater behaviour (pH, concentration and temperature) for oily-wastewater separation through green ceramic membrane using central composite design (CCD) of response surface methods (RSM). The three effective parameters analyzed were oil pH (3–11), oil concentration (10–10000 ppm), oil temperature (30–100 °C) and its combined effect to obtain high oil flux and excellent oil separation efficiency. Through the investigation it was found that the optimum value of pH, oil concentration and temperature were 10, 10.01 ppm and 69.04 °C. The result of the study has suggested that there are oil temperature has significantly influence the efficiency of the synthesized membrane separation performance. The fitted model was found to agree with the predicted and actual oil flux as well as separation efficiency which indicated by the high values of R2 = 0.954 and R2adj = 0.986. According to the optimized condition, the finding reported 4.71 % and 0.746 % average error for oil flux and separation efficiency which agrees with the forecasted and actual values. The novelty of this study lies in the development of an eco-friendly ceramic membrane derived from sugarcane bagasse waste, offering an innovative and sustainable solution for oily-wastewater treatment.
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