5-溴同形金刚烷-4-烯羧酰胺衍生物的还原环化和功能化：同形金刚烷环杂环的合成途径

IF 1.5 4区化学 Q3 CHEMISTRY, ORGANIC

Tetrahedron Letters Pub Date : 2025-01-30 DOI:10.1016/j.tetlet.2024.155431

Alexander N. Reznikov, Svetlana Yu. Vostruhina, Yury N. Klimochkin

引用次数: 0

摘要

钯催化的5-溴同形金刚烷-4-烯羧酰胺分子内还原Heck反应和Heck/氰化多米诺序列是一种方便的合成途径，可获得具有5,6-二氢吡啶-2(1H)- 1和1,5-二氢- 2h -吡啶-2- 1核的多环环状同形金刚烷衍生物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Reductive heck cyclization and functionalyzation of 5-bromohomoadamant-4-ene carboxamide derivatives: The route to homoadamantene annulated heterocycles

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Reductive heck cyclization and functionalyzation of 5-bromohomoadamant-4-ene carboxamide derivatives: The route to homoadamantene annulated heterocycles

Palladium catalyzed intramolecular reductive Heck reaction and Heck/cyanation domino sequence of 5-bromohomoadamant-4-ene carboxamides are a convenient synthetic pathway that provides access to polycyclic annulated homoadamanthene derivatives with 5,6-dihydropyridin-2(1H)-one and 1,5-dihydro-2H-pyrrol-2-one cores.

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来源期刊

Tetrahedron Letters 化学-有机化学

CiteScore

3.50

自引率

5.60%

发文量

521

审稿时长

28 days

期刊介绍： Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.