二芳基碘鎓盐的室温活化：n -甲基二芳胺非原位合成的原子经济途径

IF 1.5 4区化学 Q3 CHEMISTRY, ORGANIC

Tetrahedron Letters Pub Date : 2025-01-30 DOI:10.1016/j.tetlet.2024.155436

Dhanashri A. Sable, Anant R. Kapdi

引用次数: 0

摘要

通过使用非原位生成的HNMe2对二氮鎓盐进行室温活化合成n -甲基芳胺的原子经济途径已经公开，并且还进行了放大反应以证明所开发方案的可扩展性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Ambient temperature activation of diaryliodonium salts: Atom-economic route towards the ex-situ metal-free synthesis of N-methyldiarylamine

查看原文本刊更多论文

Ambient temperature activation of diaryliodonium salts: Atom-economic route towards the ex-situ metal-free synthesis of N-methyldiarylamine

An atom economic route for the synthesis of N-methylarylamines via the ambient temperature activation of diaryliodonium salts using an ex-situ generated HNMe₂ has been disclosed and a scale-up reaction was also performed to demonstrate the scalability of the developed protocol.

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来源期刊

Tetrahedron Letters 化学-有机化学

CiteScore

3.50

自引率

5.60%

发文量

521

审稿时长

28 days

期刊介绍： Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.