{"title":"废棕榈油加氢转化为生物喷气燃料用钴分散硫酸氧化锆纳米催化剂的合成","authors":"Riska Astin Fitria , Niko Prasetyo , Aldino Javier Saviola , Wega Trisunaryanti , Akhmad Syoufian , Amalia Kurnia Amin , Won-Chun Oh , Karna Wijaya","doi":"10.1016/j.cscee.2024.101052","DOIUrl":null,"url":null,"abstract":"<div><div>In the past decade, rising demand for air travel has resulted in increased carbon emissions, stimulating research into bio-jet fuel as an eco-friendly aviation alternative. This study examines the synthesis and application of cobalt-dispersed sulfated zirconia nanocatalysts for the hydroconversion of used palm cooking oil into bio-jet fuel under atmospheric conditions. The catalysts were synthesized using the wet impregnation method with varying cobalt loadings (1 %, 3 %, and 5 %) and characterized by FTIR, XRD, NH<sub>3</sub>-TPD, SAA, XRF, SEM-EDX Mapping, TEM-SAED, and XPS analyses. Hydroconversion with the Co-3/SZ catalyst yielded a 63.03 wt% liquid product, with 92.28 % bio-jet fuel selectivity and a yield of 58.17 wt%. Reusability tests for six consecutive runs further indicated that this catalyst maintained a bio-jet fuel selectivity of 56.94 % and a yield of 28.43 %, underscoring its potential as a promising candidate for bio-jet fuel production.</div></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"11 ","pages":"Article 101052"},"PeriodicalIF":0.0000,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of cobalt-dispersed sulfated zirconia nanocatalyst for the hydroconversion of used palm cooking oil into bio-jet fuel\",\"authors\":\"Riska Astin Fitria , Niko Prasetyo , Aldino Javier Saviola , Wega Trisunaryanti , Akhmad Syoufian , Amalia Kurnia Amin , Won-Chun Oh , Karna Wijaya\",\"doi\":\"10.1016/j.cscee.2024.101052\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In the past decade, rising demand for air travel has resulted in increased carbon emissions, stimulating research into bio-jet fuel as an eco-friendly aviation alternative. This study examines the synthesis and application of cobalt-dispersed sulfated zirconia nanocatalysts for the hydroconversion of used palm cooking oil into bio-jet fuel under atmospheric conditions. The catalysts were synthesized using the wet impregnation method with varying cobalt loadings (1 %, 3 %, and 5 %) and characterized by FTIR, XRD, NH<sub>3</sub>-TPD, SAA, XRF, SEM-EDX Mapping, TEM-SAED, and XPS analyses. Hydroconversion with the Co-3/SZ catalyst yielded a 63.03 wt% liquid product, with 92.28 % bio-jet fuel selectivity and a yield of 58.17 wt%. Reusability tests for six consecutive runs further indicated that this catalyst maintained a bio-jet fuel selectivity of 56.94 % and a yield of 28.43 %, underscoring its potential as a promising candidate for bio-jet fuel production.</div></div>\",\"PeriodicalId\":34388,\"journal\":{\"name\":\"Case Studies in Chemical and Environmental Engineering\",\"volume\":\"11 \",\"pages\":\"Article 101052\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-12-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Case Studies in Chemical and Environmental Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666016424004468\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Environmental Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Case Studies in Chemical and Environmental Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666016424004468","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Environmental Science","Score":null,"Total":0}
Synthesis of cobalt-dispersed sulfated zirconia nanocatalyst for the hydroconversion of used palm cooking oil into bio-jet fuel
In the past decade, rising demand for air travel has resulted in increased carbon emissions, stimulating research into bio-jet fuel as an eco-friendly aviation alternative. This study examines the synthesis and application of cobalt-dispersed sulfated zirconia nanocatalysts for the hydroconversion of used palm cooking oil into bio-jet fuel under atmospheric conditions. The catalysts were synthesized using the wet impregnation method with varying cobalt loadings (1 %, 3 %, and 5 %) and characterized by FTIR, XRD, NH3-TPD, SAA, XRF, SEM-EDX Mapping, TEM-SAED, and XPS analyses. Hydroconversion with the Co-3/SZ catalyst yielded a 63.03 wt% liquid product, with 92.28 % bio-jet fuel selectivity and a yield of 58.17 wt%. Reusability tests for six consecutive runs further indicated that this catalyst maintained a bio-jet fuel selectivity of 56.94 % and a yield of 28.43 %, underscoring its potential as a promising candidate for bio-jet fuel production.