基于1-乙烯基咪唑的新型氧化石墨烯纳米片固定离子液体的合成、鉴定及应用

Q1 Environmental Science
Masoumeh Mirhasani , Reza Sandaroos , Behrooz Maleki , Sahar Peiman
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引用次数: 0

摘要

在本研究中,合成了一种新型催化剂GO@[PBVIm]HSO4,它是一种负载在氧化石墨烯衬底上的酸性聚合物离子液体。首先,将(3-氨基丙基)三乙氧基硅烷作为连接剂连接到制备的氧化石墨烯上。下一步,利用1-丁基乙烯基咪唑溴在固体载体上合成了预期的聚合物催化剂。该催化剂在合成铬、杂蒽、二氢嘧啶衍生物等多种有机化学反应中具有较高的效率。该方法具有反应时间短、温度适宜、产物收率高、回收催化剂活性好等优点。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis, identification and application of a new ionic liquid based on 1-vinylimidazole, immobilized on graphene oxide nanosheets
In this research, a novel catalyst GO@[PBVIm]HSO4, which is an acidic polymer ionic liquid supported on a graphene oxide substrate, was synthesized. First, (3-aminopropyl) triethoxysilane was attached as a linker to the prepared graphene oxide. In the next step, 1-butyl vinyl imidazolium bromide was used to synthesize the expected polymer catalyst on a solid support. The efficiency of this catalyst was used in various organic chemical reactions such as the synthesis of chromene, xanthene, and dihydropyrimidinone derivatives. Short reaction time, suitable temperature, excellent yield of products, and very good activity of recycled catalyst are among the advantages of this heterogeneous catalyst synthesis.
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来源期刊
Case Studies in Chemical and Environmental Engineering
Case Studies in Chemical and Environmental Engineering Engineering-Engineering (miscellaneous)
CiteScore
9.20
自引率
0.00%
发文量
103
审稿时长
40 days
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