{"title":"下一代纳米复合材料:优化Al2O3-CuO-ZnO和还原氧化石墨烯以增强性能","authors":"Rahul Sharma , Harish Kumar , Rajni Kumari , Gaman Kumar , Bhawna Swami , Antresh Kumar , Gita Rani , Ramesh Kumar","doi":"10.1016/j.nxnano.2024.100119","DOIUrl":null,"url":null,"abstract":"<div><div>Exceptional reduced graphene oxide-based nanocomposites (NCs) were synthesized using Al<sub>2</sub>O<sub>3</sub>-CuO-ZnO (ACZ) nanoparticles (NPs) through a controlled hydrothermal method. Nanomaterials with improved optical, magnetic, antibacterial, adsorption, anticorrosive, and photocatalytic characteristics were synthesized, showing synergistic behavior. To understand key structural features, the NCs were thoroughly examined using energy-dispersive X-ray analysis, SEM, X-ray diffraction, FTIR, and UV-Vis. spectroscopy. Adding ACZ NPs in the rGO matrix, increased magnetic, anticorrosive, improved antibacterial efficacy against Gram-positive bacteria, and photocatalytic activities. The NCs were exposed to sunlight and UVA and UVB light to degrade methylene blue (MB) dye i.e., 89.21 % in 75 min. The anti-corrosive characteristics (95.9 %) were examined against mild steel using a 1.0 N H<sub>2</sub>SO<sub>4</sub> at room temperature at a very low concentration i.e., 10 ppm. The magnetic behavior of the NCs was examined with the help of Gouy’s balance. The induced current showed a clear relationship to the applied magnetic field strength, indicating that the NCs are paramagnetic. The antibacterial effects of the NCs were evaluated against <em>S. aureus</em> and <em>E. coli</em> at different concentrations. The ACZ@rGO NCs exhibited exceptional versatility, showing great promise for water purification, adsorption, corrosion protection, photocatalytic processes, biomedical technologies, and environmental restoration.</div></div>","PeriodicalId":100959,"journal":{"name":"Next Nanotechnology","volume":"7 ","pages":"Article 100119"},"PeriodicalIF":0.0000,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Next-generation nanocomposites: Optimizing Al2O3-CuO-ZnO and reduced graphene oxide for enhanced performance\",\"authors\":\"Rahul Sharma , Harish Kumar , Rajni Kumari , Gaman Kumar , Bhawna Swami , Antresh Kumar , Gita Rani , Ramesh Kumar\",\"doi\":\"10.1016/j.nxnano.2024.100119\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Exceptional reduced graphene oxide-based nanocomposites (NCs) were synthesized using Al<sub>2</sub>O<sub>3</sub>-CuO-ZnO (ACZ) nanoparticles (NPs) through a controlled hydrothermal method. Nanomaterials with improved optical, magnetic, antibacterial, adsorption, anticorrosive, and photocatalytic characteristics were synthesized, showing synergistic behavior. To understand key structural features, the NCs were thoroughly examined using energy-dispersive X-ray analysis, SEM, X-ray diffraction, FTIR, and UV-Vis. spectroscopy. Adding ACZ NPs in the rGO matrix, increased magnetic, anticorrosive, improved antibacterial efficacy against Gram-positive bacteria, and photocatalytic activities. The NCs were exposed to sunlight and UVA and UVB light to degrade methylene blue (MB) dye i.e., 89.21 % in 75 min. The anti-corrosive characteristics (95.9 %) were examined against mild steel using a 1.0 N H<sub>2</sub>SO<sub>4</sub> at room temperature at a very low concentration i.e., 10 ppm. The magnetic behavior of the NCs was examined with the help of Gouy’s balance. The induced current showed a clear relationship to the applied magnetic field strength, indicating that the NCs are paramagnetic. The antibacterial effects of the NCs were evaluated against <em>S. aureus</em> and <em>E. coli</em> at different concentrations. The ACZ@rGO NCs exhibited exceptional versatility, showing great promise for water purification, adsorption, corrosion protection, photocatalytic processes, biomedical technologies, and environmental restoration.</div></div>\",\"PeriodicalId\":100959,\"journal\":{\"name\":\"Next Nanotechnology\",\"volume\":\"7 \",\"pages\":\"Article 100119\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Next Nanotechnology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2949829524000809\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Next Nanotechnology","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2949829524000809","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
以Al2O3-CuO-ZnO (ACZ)纳米颗粒(NPs)为原料,采用可控水热法制备了特殊还原性氧化石墨烯基纳米复合材料(NCs)。合成的纳米材料具有更好的光学、磁性、抗菌、吸附、防腐和光催化特性,并表现出协同作用。为了了解主要的结构特征,研究人员利用能量色散x射线分析、扫描电镜、x射线衍射、红外光谱和紫外-可见光谱对NCs进行了全面的研究。光谱学。在还原氧化石墨烯基体中添加ACZ NPs,增强了磁性、耐腐蚀性,提高了对革兰氏阳性菌的抗菌效果和光催化活性。NCs分别暴露在阳光和UVA和UVB光下,在75 min内降解亚甲基蓝(MB)染料89.21 %。用1.0 N H2SO4在室温下以极低的浓度(10 ppm)对低碳钢进行了防腐性能(95.9% %)测试。利用古伊天平对纳米碳的磁性行为进行了研究。感应电流与外加磁场强度有明显的关系,表明nc是顺磁性的。研究了不同浓度NCs对金黄色葡萄球菌和大肠杆菌的抑菌效果。ACZ@rGO纳米材料表现出卓越的多功能性,在水净化、吸附、防腐、光催化过程、生物医学技术和环境恢复方面显示出巨大的前景。
Next-generation nanocomposites: Optimizing Al2O3-CuO-ZnO and reduced graphene oxide for enhanced performance
Exceptional reduced graphene oxide-based nanocomposites (NCs) were synthesized using Al2O3-CuO-ZnO (ACZ) nanoparticles (NPs) through a controlled hydrothermal method. Nanomaterials with improved optical, magnetic, antibacterial, adsorption, anticorrosive, and photocatalytic characteristics were synthesized, showing synergistic behavior. To understand key structural features, the NCs were thoroughly examined using energy-dispersive X-ray analysis, SEM, X-ray diffraction, FTIR, and UV-Vis. spectroscopy. Adding ACZ NPs in the rGO matrix, increased magnetic, anticorrosive, improved antibacterial efficacy against Gram-positive bacteria, and photocatalytic activities. The NCs were exposed to sunlight and UVA and UVB light to degrade methylene blue (MB) dye i.e., 89.21 % in 75 min. The anti-corrosive characteristics (95.9 %) were examined against mild steel using a 1.0 N H2SO4 at room temperature at a very low concentration i.e., 10 ppm. The magnetic behavior of the NCs was examined with the help of Gouy’s balance. The induced current showed a clear relationship to the applied magnetic field strength, indicating that the NCs are paramagnetic. The antibacterial effects of the NCs were evaluated against S. aureus and E. coli at different concentrations. The ACZ@rGO NCs exhibited exceptional versatility, showing great promise for water purification, adsorption, corrosion protection, photocatalytic processes, biomedical technologies, and environmental restoration.