纳米二氧化硅分散改善水泥基复合材料性能及机理研究

IF 6.5 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY
Tonghuan Zhang , Zhenjun Wang , Wei Wang , Gang Li , Haoyan Guo , Haibao Zhang
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引用次数: 0

摘要

纳米二氧化硅(NS)在提高水泥材料性能方面表现出巨大的潜力。然而,其改善水泥基材料性能的有效性受到了NS在水泥基体中分散不良的阻碍。本文通过减水剂(FDN-C萘减水剂和PCE-11聚羧酸高效减水剂)和机械分散方法(超声和磁力搅拌)改善了NS在水泥溶液中的分散性,并通过紫外可见分光光度法和zeta电位测试考察了它们的协同效应。研究分析了NS分散性对NS改性水泥浆体(NS- c)微观结构和性能的影响及其机理。结果表明,与萘减水剂相比,聚羧酸型高效减水剂在NS颗粒表面具有更强的吸附能力,有效提高了NS在水泥溶液中的分散稳定性。超声波比磁力搅拌能保证NS更好的分散。1.0 %聚羧酸减水剂与1 h超声作用的协同作用增强了NS骨料的分散,从而促进水泥水化反应,细化孔隙结构。此外,这种协同作用提高了NS-C的和易性和抗压强度。热重(TG)和工业计算机断层扫描(ICT)结果表明,与1 %聚羧酸型高效减水剂和1 h超声作用协同分散的NS-C中C-S-H凝胶含量的增加和大于10 mm3的大孔隙体积的减小是其抗压强度提高的主要原因。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Property enhancement and mechanism of cement-based composites from the perspective of nano-silica dispersion improvement
Nano-silica (NS) exhibits significant potential for enhancing the properties of cement materials. However, its effectiveness in improving the properties of cement-based materials is hindered by the poor dispersion of NS within the cement matrix. In this work, the dispersibility of NS in cement solutions was improved by water reducers (FDN-C naphthalene water reducer and PCE-11 polycarboxylate superplasticizer) and mechanical dispersion methods (ultrasonication and magnetic stirrer), and their synergistic effects were investigated by ultraviolet visible spectrophotometry and zeta potential tests. Effects and mechanism of NS dispersibility on microstructure and properties of NS modified cement pastes (NS-C) were also investigated and analyzed. Results indicate that polycarboxylate superplasticizers have stronger adsorption on the surface of NS particles compared with naphthalene water reducers, which effectively improved the dispersion stability of NS in cement solutions. Furthermore, ultrasonication can ensure better dispersion of NS than magnetic stirrer. The synergistic effects of 1.0 % polycarboxylate superplasticizers and 1 h of ultrasonication enhances the dispersion of NS aggregates, thereby promoting the hydration reaction of cement and refining the pore structure. Additionally, this synergistic effect improves the workability and the compressive strength of NS-C. Thermogravimetric (TG) and industrial computed tomography (ICT) results indicated that the increase in C-S-H gel and the reduction in the volume of large pores (greater than 10 mm3) in NS-C dispersed synergistically with 1 % polycarboxylate superplasticizers and 1 h of ultrasonication are the mainly reasons for the improvement in compressive strength.
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来源期刊
CiteScore
7.60
自引率
19.40%
发文量
842
审稿时长
63 days
期刊介绍: Case Studies in Construction Materials provides a forum for the rapid publication of short, structured Case Studies on construction materials. In addition, the journal also publishes related Short Communications, Full length research article and Comprehensive review papers (by invitation). The journal will provide an essential compendium of case studies for practicing engineers, designers, researchers and other practitioners who are interested in all aspects construction materials. The journal will publish new and novel case studies, but will also provide a forum for the publication of high quality descriptions of classic construction material problems and solutions.
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