微咸地下水反渗透系统中无机结垢的表征及缓解策略

Abdelilah Fatni , Mourad Addich , Abdelilah Essekri , Noureddine EL Baraka , Driss Azdem , Abdelaziz Ait Taleb , Abdellatif EL Hammadi
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引用次数: 0

摘要

由于摩洛哥和全世界的淡水资源短缺,海水淡化已经成为一种更有效和更广泛的处理海水和微咸水的技术。反渗透是一种常用的海水淡化方法。然而,膜污染仍然是该技术面临的严重问题,包括无机、有机、胶体和生物污染。本研究旨在分析Souss Massa农场的反渗透性能,利用饲料的化学和物理性质,渗透和排斥水来解决污染问题,从而表征膜上沉积的污垢。利用扫描电子显微镜、x射线能谱、x射线衍射和傅里叶变换红外光谱等技术对污垢进行了表征。分析表明,Ca2+、Na+、Cl -、HCO3 -和SO42 -是给水中最主要的离子。预测结垢指数和膜表面形成的结垢结构表征结果表明,膜表面主要由碳酸钙和饱和二氧化硅组成。改变阻垢剂和建议的清洗方案可以防止反渗透膜中结垢,并有助于提高TDS的去除率,从94.23 %提高到97.04 %。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Characterization and mitigation strategies for inorganic scaling in reverse osmosis system treating brackish groundwater
Water desalination has become a more effective and widespread technology for treating seawater and brackish water because of a shortage of freshwater resources in Morocco and the world. Reverse osmosis is a commonly used method for water desalination. Nevertheless, membrane fouling remains a serious problem facing this technique, including inorganic, organic, colloidal, and biofouling. This research aims to analyze the performance of reverse osmosis used on Souss Massa farm and solve the fouling issue by using the chemical and physical properties of feed, permeate, and reject water, thus the characterization of fouling deposited on the membrane. The fouling was characterized by several techniques, such as scanning electron microscopy coupled with energy dispersion X-ray spectroscopy, X-ray diffraction, and Fourier transform infrared spectroscopy. The analysis revealed that Ca2+, Na+, Cl, HCO3, and SO42– are the most dominant ions in the feedwater. The predicting scaling indices and the characterization results of the scale structure developed on the membrane surface revealed that it was mainly composed of calcium carbonate and silica saturated. Changing the antiscalant and the proposed cleaning protocol prevent scale formation in reverse osmosis membranes and help increase and improve TDS's rejection rate from 94.23 % to 97.04 %.
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