烯基磺酸盐与S8和h -膦酸盐的可见光诱导磷酸化硫代作用

IF 3.6 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2025-02-04 DOI:10.1021/acs.joc.4c02642

Li-Hua Yang, Ni-Dan Meng, Li Tang, Lin Chen, Shan-Shan Tang, Long-Yong Xie

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引用次数: 0

摘要

通过可见光诱导的烯基磺酸盐、S8和h -膦酸盐的三组分反应，证明了一种高效实用的合成乙烯基硫代磷酸酯的方法。该方法有利于合成具有广泛底物范围和官能团耐受性的各种乙烯基硫代酸酯。初步的机理研究表明，该反应涉及到一个由硫代磷酸酯自由基引发的过程。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Visible-Light-Induced Phosphorothioation of Alkenyl Sulfonium Salts with S8 and H-Phosphonates

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Visible-Light-Induced Phosphorothioation of Alkenyl Sulfonium Salts with S8 and H-Phosphonates

An efficient and practical method for synthesizing vinyl phosphorothioates has been demonstrated through a visible-light-induced three-component reaction of alkenyl sulfonium salts, S₈, and H-phosphonates. This method facilitates the synthesis of a diverse range of vinyl phosphorothioates with a wide substrate scope and functional group tolerance. Preliminary mechanistic studies suggest that the reaction involves a phosphorothioate radical-triggered process.

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.