Th. Dhanakumar Singh, C. Manikyamba, G. Harshitha, M. Lingadevaru, K. S. V. Subramanyam, Arijit Pahari
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Chondritic Al<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> (9.65–16.38) ratios, superchondritic Gd/Yb<sub>N</sub> (1.3–1.6), depleted high-field-strength elements (HFSEs) (Zr, Hf), enrichment of LREE over HREE and negative Nb–Ta anomalies reflect the generation of parental melts from plume-sourced Al-depleted komatiites with significant crustal contamination during their emplacement. The major, trace element and PGE relationships (FeO vs. MgO, Cu vs. Pd, Ni/Cu vs. Pd/Ir) infer the origin of sulphur undersaturated primary melts through moderate to higher degrees of partial melting followed by crustal assimilation that led to PGE enrichment. These observations suggest their formation from melts derived from greater depths of the upper mantle (> 400 km) at high pressure (> 10 GPa), wherein, the mantle residue retained majorite garnet. The high Ni (avg. 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引用次数: 0
摘要
全球太古宙绿岩带超镁铁质岩是铜镍、铂族元素(PGEs)和金等贵金属矿床的潜在寄主。本文重点研究了印度西达瓦尔克拉通Shimoga绿岩带超镁质岩中Ni-PGE矿化的地球化学证据及其成因。岩石学特征表明岩石为蛇纹石化的泥质岩质,地球化学特征表明岩石与马马岩质有亲缘关系。这些岩石中浸染型硫化物的存在和明显的蛇纹岩化表明,与科马铁矿有关的II型(浸染型硫化物)和IV型(岩浆后蚀变)矿床组合。球粒质Al2O3/TiO2(9.65 ~ 16.38)比值、超球粒质Gd/YbN(1.3 ~ 1.6)、贫化高场强元素(Zr、Hf)、轻稀土(LREE)比三稀土(HREE)富集以及Nb-Ta负异常反映了羽状源贫铝科马岩成位过程中存在明显地壳污染的母熔体。主要元素、微量元素和PGE的关系(FeO vs. MgO, Cu vs. Pd, Ni/Cu vs. Pd/Ir)推断硫不饱和原生熔体的起源是通过中度至较高程度的部分熔融,然后是地壳同化,导致PGE富集。这些观测结果表明,它们的形成是在高压(10 GPa)下来自上地幔更深处(400 km)的熔体,其中地幔残留物保留了大部分榴石。高Kambalda比值([Ni:Cr] × [Cu:Zn] = 5.6)的高Ni(平均Ni = 6511 ppm)和高PGE(平均∑PGE = 3078 ppb)的Ni/Cr比值(> 1),证实了下下绿岩带超镁质岩的富矿性和Ni-PGE成矿潜力。
Serpentinised Dunites of the Neoarchean Shimoga Greenstone Belt, Western Dharwar Craton, India: Insights on Ni-PGE Mineralisation and Genesis
Ultramafic rocks of the Archean greenstone belts worldwide are potential hosts for Cu-Ni, precious metal deposits like platinum group elements (PGEs) and gold. This study highlights the geochemical evidence and genesis of Ni-PGE mineralisation in the ultramafic rocks of Shimoga greenstone belt of the Western Dharwar Craton, India. Petrographically, the studied rocks are identified to be serpentinised dunites, while their geochemical signatures indicate komatiitic affinity. Presence of disseminated sulphides and pronounced serpentinisation in these rocks suggest a combination of Type II (disseminated sulphides) and Type IV (post-magmatic alterations) komatiite-related Ni–Cu-PGE deposits. Chondritic Al2O3/TiO2 (9.65–16.38) ratios, superchondritic Gd/YbN (1.3–1.6), depleted high-field-strength elements (HFSEs) (Zr, Hf), enrichment of LREE over HREE and negative Nb–Ta anomalies reflect the generation of parental melts from plume-sourced Al-depleted komatiites with significant crustal contamination during their emplacement. The major, trace element and PGE relationships (FeO vs. MgO, Cu vs. Pd, Ni/Cu vs. Pd/Ir) infer the origin of sulphur undersaturated primary melts through moderate to higher degrees of partial melting followed by crustal assimilation that led to PGE enrichment. These observations suggest their formation from melts derived from greater depths of the upper mantle (> 400 km) at high pressure (> 10 GPa), wherein, the mantle residue retained majorite garnet. The high Ni (avg. Ni = 6511 ppm) substantiated by high Kambalda ratio ([Ni:Cr] × [Cu:Zn] = 5.6), Ni/Cr ratios (> 1) with high concentration of PGEs (avg. ∑PGE = 3078 ppb) confirm the fertile/mineralised nature of the komatiitic source and potential Ni-PGE mineralization in the ultramafic rocks of the Shimoga greenstone belt.
期刊介绍:
In recent years there has been a growth of specialist journals within geological sciences. Nevertheless, there is an important role for a journal of an interdisciplinary kind. Traditionally, GEOLOGICAL JOURNAL has been such a journal and continues in its aim of promoting interest in all branches of the Geological Sciences, through publication of original research papers and review articles. The journal publishes Special Issues with a common theme or regional coverage e.g. Chinese Dinosaurs; Tectonics of the Eastern Mediterranean, Triassic basins of the Central and North Atlantic Borderlands). These are extensively cited.
The Journal has a particular interest in publishing papers on regional case studies from any global locality which have conclusions of general interest. Such papers may emphasize aspects across the full spectrum of geological sciences.