MoS2厚度对TiO2/MoS2/P3HT电池太阳能转换效率的影响

IF 8 2区 材料科学 Q1 ENERGY & FUELS
Kamila Kollbek, Łukasz Jarosiński, Paweł Dąbczyński, Piotr Jabłoński, Marta Gajewska, Piotr Jeleń, Jakub Rysz, Konrad Szaciłowski, Marek Przybylski
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引用次数: 0

摘要

在全球能源危机的时代,高效的可再生能源收集越来越受到人们的关注。太阳能是被广泛使用的能源之一,但转换能源的设备的效率需要不断提高。其中一个想法是制造太阳能电池,使其受益于二维范德华结构与其他材料(如TiO2和导电聚合物)的结合。这种混合太阳能电池与非复合光伏设备相比,显示出更高的功率转换。在这项工作中,在磁控溅射过程中产生的TiO2/MoS2异质结被P3HT聚合物涂层覆盖。利用TEM、XRD、拉曼光谱和TOF-SIMS等方法研究了复合多层体系的组成、光学性质和太阳能转换潜力。基于量子尺寸效应的MoS2带隙工程成功地改善了多层体系的光伏响应。此外,TiO2/MoS2/P3HT表现出增强的光学性能和改善的电荷输运性能,具有合理的能带排列。混合电池的光伏效率比之前发表的工作翻了一番,达到2.7%。此外,基于TiO2/MoS2/P3HT的太阳能电池的光伏性能比基于TiO2/P3HT或MoS2/P3HT的太阳能电池有改善。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The Influence of MoS2 Thickness on the Efficiency of Solar Energy Conversion in TiO2/MoS2/P3HT Cells

The Influence of MoS2 Thickness on the Efficiency of Solar Energy Conversion in TiO2/MoS2/P3HT Cells

In the era of global energy crisis, more attention is paid to efficient energy harvesting from renewable sources. Solar power is one of those widely utilized, yet the efficiency of devices converting energy needs to be constantly improved. One of the ideas is to create solar cells that benefit from 2D van der Waals structures combined with other materials such as TiO2 and conductive polymers. Such hybrid solar cells show higher power conversion compared to non-composite photovoltaic devices. In this work, a TiO2/MoS2 heterojunction created in the magnetron sputtering process was covered with a P3HT polymer coating. Composite multilayer systems were investigated (TEM, XRD, Raman spectroscopy and TOF-SIMS) to define the composition, optical properties and solar energy conversion potential. The photovoltaic response of the multilayer system was successfully improved by MoS2 band gap engineering based on the quantum size effect. Furthermore, TiO2/MoS2/P3HT revealed enhanced optical properties and improved charge transport performance with reasonable energy band alignment. The photovoltaic efficiency of hybrid cells doubled compared to previously published work and reached 2.7%. Furthermore, the photovoltaic performance of the solar cells based on TiO2/MoS2/P3HT exhibited an improvement compared to that of the solar cell based on TiO2/P3HT or MoS2/P3HT.

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来源期刊
Progress in Photovoltaics
Progress in Photovoltaics 工程技术-能源与燃料
CiteScore
18.10
自引率
7.50%
发文量
130
审稿时长
5.4 months
期刊介绍: Progress in Photovoltaics offers a prestigious forum for reporting advances in this rapidly developing technology, aiming to reach all interested professionals, researchers and energy policy-makers. The key criterion is that all papers submitted should report substantial “progress” in photovoltaics. Papers are encouraged that report substantial “progress” such as gains in independently certified solar cell efficiency, eligible for a new entry in the journal''s widely referenced Solar Cell Efficiency Tables. Examples of papers that will not be considered for publication are those that report development in materials without relation to data on cell performance, routine analysis, characterisation or modelling of cells or processing sequences, routine reports of system performance, improvements in electronic hardware design, or country programs, although invited papers may occasionally be solicited in these areas to capture accumulated “progress”.
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